The natural latitudinal distribution of atmospheric CO2

Although poorly understood, the north–south distribution of the natural component of atmospheric CO₂ offers information essential to improving our understanding of the exchange of CO₂ between the atmosphere, oceans, and biosphere. The natural or unperturbed component is equivalent to that part of the atmospheric CO₂ distribution which is controlled by non-anthropogenic CO₂ fluxes from the ocean and terrestrial biosphere. Models should be able to reproduce the true north–south gradient in CO₂ due to the natural component before they can reliably estimate present-day CO₂ sources and sinks and predict future atmospheric CO₂. We have estimated the natural latitudinal distribution of atmospheric CO₂, relative to the South Pole, using measurements of atmospheric CO₂ during 1959–1991 and corresponding estimates of anthropogenic CO₂ emissions to the atmosphere. Key features of the natural latitudinal distribution include: (1) CO₂ concentrations in the northern hemisphere that are lower than those in the southern hemisphere; (2) CO₂ concentration differences that are higher in the tropics (associated with outgassing of the oceans) than those currently measured; and (3) CO₂ concentrations over the southern ocean that are relatively uniform. This natural latitudinal distribution and its sensitivity to increasing fossil fuel emissions both indicate that near-surface concentrations of atmospheric CO₂ in the northern hemisphere are naturally lower than those in the southern hemisphere. Models that find the contrary will also mismatch present-day CO₂ in the northern hemisphere and incorrectly ascribe that region as a large sink of anthropogenic CO₂.     

The morphodynamics of fluvial sand dunes in the River Rhine, near Mainz, Germany. I. Sedimentology and morphology

The dynamics of large isolated sand dunes moving across a gravel lag layer were studied in a supply‐limited reach of the River Rhine, Germany. Bed sediments, dune geometry, bedform migration rates and the internal structure of dunes are considered in this paper. Hydrodynamic and sediment transport data are considered in a companion paper. The pebbles and cobbles (D₅₀ of 10 mm) of the flat lag layer are rarely entrained. Dunes consist of well‐sorted medium to coarse sand (D₅₀ of 0·9 mm). Small pebbles move over the dunes by ‘overpassing’, but there is a degree of size and shape selectivity. Populations of ripples in sand (D₅₀ < 0·6 mm), and small and large dunes are separated by distinct breaks in the bedform length data in the regions of 0·7–1 m and 5–10 m. Ripples and small dunes may have sinuous crestlines but primarily exhibit two‐dimensional planforms. In contrast, large dunes are primarily three‐dimensional barchanoid forms. Ripples on the backs of small dunes rarely develop to maximum steepness. Small dunes may achieve an equilibrium geometry, either on the gravel bed or as secondary dunes within the boundary layer on the stoss side of large dunes. Secondary dunes frequently develop a humpback profile as they migrate across the upper stoss slope of large dunes, diminishing in height but increasing in length as they traverse the crestal region. However, secondary dunes more than 5 m in length are rare. The dearth of equilibrium ripples and long secondary dunes is probably related to the limited excursion length available for bedform development on the parent bedforms. Large dunes with lengths between 20 m and 100 m do not approach an equilibrium geometry. A depth limitation rather than a sediment supply limitation is the primary control on dune height; dunes rarely exceed 1 m high in water depths of ≈4 m. Dune celerity increases as a function of the mean flow velocity squared, but this general relationship obscures more subtle morphodynamics. During rising river stage, dunes tend to grow in height owing to crestal accumulation, which slows downstream progression and steepens the dune form. During steady or falling stage, an extended crestal platform develops in association with a rapid downstream migration of the lee side and a reduction in dune height. These diminishing dunes actually increase in unit volume by a process of increased leeside accumulation fed by secondary dunes moving past a stalled stoss toe. A six‐stage model of dune growth and diminution is proposed to explain variations in observed morphology. The model demonstrates how the development of an internal boundary layer and the interaction of the water surface with the crests of these bedload‐dominated dunes can result in dunes characterized by gentle lee sides with weak flow separation. This finding is significant, as other studies of dunes in large rivers have attributed this morphological response to a predominance of suspended load transport.     

Discovery of cryptotephra at Middle–Upper Paleolithic sites Arma Veirana and Riparo Bombrini,Italy: a new link for broader geographic correlations

Chemical characterization of cryptotephra is critical for temporally linking archaeological sites. Here, we describe cryptotephra investigations of two Middle–Upper Paleolithic sites from north-west Italy, Arma Veirana and Riparo Bombrini. Cryptotephra are present as small (<100 µm) rhyolitic glass shards at both sites, with geochemical signatures rare for volcanoes in the Mediterranean region. Two chemically distinct shard populations are present at Arma Veirana (P1 and P2). P1 is a high silica rhyolite (>75 wt.%) with low FeO (<1 wt.%) and a K₂O/Na₂O > 1 and P2 is also a high silica rhyolite (>75 wt.%) but with higher FeO (2.33–2.65 wt.%). Shards at Riparo Bombrini (P3) are of the same composition as P1 shards at Arma Veirana, providing a distinct link between deposits at both sites. Geochemical characteristics suggest three possible sources for P1 and P3: eruptions from Lipari Island (56–37.7 ka) in Italy, the Acigöl volcanic field (200–20 ka) in Turkey and the Miocene Kirka-Phrigian caldera (18 Ma) in Turkey. Eruptions from Lipari Island are the most likely source for P1,3 cryptotephra. This study highlights how cryptotephra can benefit archaeology, by providing a direct link between Arma Veirana and Riparo Bombrini as well as other deposits throughout the Mediterranean.     

The monsoon imprint during the ‘atypical’ MIS 13 as seen through north and equatorial Indian Ocean records

Previous studies have suggested that Marine Isotope Stage (MIS) 13, recognized as atypical in many paleoclimate records, is marked by the development of anomalously strong summer monsoons in the northern tropical areas. To test this hypothesis, we performed a multi-proxy study on three marine records from the tropical Indian Ocean in order to reconstruct and analyse changes in the summer Indian monsoon winds and precipitations during MIS 13. Our data confirm the existence of a low-salinity event during MIS 13 in the equatorial Indian Ocean but we argue that this event should not be considered as “atypical”. Taking only into account a smaller precession does not make it possible to explain such precipitation episode. However, when considering also the larger obliquity in a more complete orbitally driven monsoon “model,” one can successfully explain this event. In addition, our data suggest that intense summer monsoon winds, although not atypical in strength, prevailed during MIS 13 in the western Arabian Sea. These strong monsoon winds, transporting important moisture, together with the effect of insolation and Eurasian ice sheet, are likely one of the factors responsible for the intense monsoon precipitation signal recorded in China loess, as suggested by model simulations.     

Magnetotelluric response of a uniformly stratified earth containing a magnetized layer

Summary The magnetotelluric (MT) response is studied of a uniformly stratified earth which contains a magnetized layer. The impedance as a function of the layer parameters (resistivity, ρ permeability, μ and thickness h ) is discussed. The MT response from a layer (μ, ρ, h ) is equivalent to that from a layer (μ/μ_r=μ₀, μ_rρ, μ_r h ) where μ_r is the relative permeability of the layer. Thus the effect of a magnetized layer is to make it apppear μ_r times more resistive and μ_r times thicker than an unmagnetized equivalent layer. Master curves of apparent resistivity and phase are computed for three-layer models with varying permeability associated with varying resistivity in each layer. An example of MT field data is presented in which the most reasonable interpretation is that a magnetized layer exists beneath the observatory site.     

Correlations between ground observations of Pi 2 geomagnetic pulsations and satellite plasma density observations

Ground observations of Pi 2 geomagnetic pulsations are correlated with satellite measurements of plasma density for three time intervals. The pulsations were recorded using the IGS network of magnetometer stations and the plasma density measurements were made on board GEOS-1 and ISEE-1. Using the technique of complex demodulation, the amplitude, phase and polarisation characteristics of the Pi 2 pulsations are observed along two meridional profiles; one from Eidar, Iceland (L = 6.7) to Cambridge, U.K. (L = 2.5) and the other from Tromso, Norway (tL = 6.2) to Nurmijarvi, Finland (L = 3.3). The observed characteristics of the Pi 2 pulsations are then compared with the plasma density measurements. Close relationships between the plasmapause position and the position of an ellipticity reversal and a variation in H component phase are observed. A small, secondary amplitude maximum is observed on the U.K./Iceland meridian well inside the position of the projection of the equatorial plasmapause. The primary maxima on the two meridians, in general occur close to the estimated position of the equatorward edge of a westward electrojet. Using the plasma density measurements, the periods of surface waves at the plasmapause for two intervals are estimated and found to be in good agreement with the dominant spectral peaks observed at the ground stations near the plasmapause latitude and within the plasmasphere. The polarisation reversal, together with phase characteristics, spectral evidence and the agreement between the theoretical and observed periods leads to the suggestion that on occasions a surface wave is excited on the plasmapause as an intermediate stage in the propagation of Pi 2 pulsations from the auroral zone to lower latitudes.     

Characteristics of Stable Flows over Southern Greenland

The main characteristic features of stable atmospheric flows over a large mountain plateau are summarised and then compared with mesoscale and synoptic scale numerical simulation, meteorological analysis, satellite imagery, and surface observations for the cases of flows over Southern Greenland for four wind directions. The detailed features are identified using the concepts and scaling of stably stratified flow over large mountains with variations in surface roughness, elevation, and heating. For westerly and easterly winds detached jets form at the southern tip, where coastal jets converge, which propagate large distances across the ocean. Near coasts katabatic winds can combine with barrier jets and wake flows generated by synoptic winds. Note how the approach flow rises/falls over southern Greenland for easterly/westerly winds, leading in both cases to more cloud on the western side. Some conclusions are drawn about the large-scale influences of these flows; detached jets in the atmosphere; air-sea interaction; formation of low pressure systems. For accurate simulations of these flows, mesoscale models are necessary with resolutions of order of 20 km or less.     

Recent radar measurements of turbulence and microphysical parameters in marine boundary layer clouds

We present a collection of research related to radar measurements of turbulence and microphysical properties in clouds. The radars used in these studies operate at frequencies ranging from 404 MHz to 34.6 GHz. We discuss the relative contributions made by the two primary radar scattering mechanisms to the measured values of radar reflectivity at the different frequencies. The desired turbulence and microphysical information is obtained from the radar reflectivity and other elements of the Doppler velocity spectra. Methods and examples are given with emphasis on liquid water clouds associated with the marine boundary layer.     

Uptake and elimination of lindane and a phthalate ester in tropical corals and mussels

Phthalate esters and γ-hexachlorocyclohexane are among the organic xenobiotics which are most abundant in the atmospheric fallout over Bermuda. It was therefore of interest to study the uptake and elimination of these synthetic components in the most important reef building coral. Diploria strigosa and the mussel Arca zebra, from Bermudian waters. Radioactive labelled components (¹⁴C-γ-hexachlorocyclohexane, diisononyl [carboxyl-¹⁴C] phthalate) were used in the study and the samples were analyzed by liquid scintillation counting.The highest concentrations of radioactivity were found in hepatopancreas and more phthalate ester than lindane was taken up. In gill, muscle and coral tissues the uptake of lindane was higher than that of the phthalate ester. In all tissues analyzed the elimination rate of lindane was higher than that of the phthalate ester.The acute effects of phthalate esters on corals are probably less than those of lindane, due to the low uptake and low toxicity. However, the poor elimination of phthalate esters may lead to long-term effects.