基于20a卫星高度计数据的黑潮变异特征

黑潮作为一支典型的西边界流,其路径变化特征及其相关的物理现象对于渔业和航海有着不可忽视的影响。本文基于改进的特征线方法,利用1992~2012年的高度计绝对动力地形数据提取了整个黑潮流区逐月的黑潮主轴和边界位置,并对沿轴速度、主流宽度、表层水体输运以及路径标准差等黑潮特征量进行了分析研究。结果表明,黑潮整体的沿轴速度在夏秋季较大,最大值可达0.95 m/s,而在冬季的速度较小;黑潮主流宽度在10、11月份达到最大值;黑潮表层水体输运在夏季最大,春秋两季次之,冬季最小。沿黑潮流路分区域对黑潮特征进行分析,结果表明,越往黑潮下游,其沿轴速度、主流宽度和表层水体输运越大,同时沿轴速度和表层水体输运量最大值出现的时间也越晚,黑潮主轴位置相对于其多年平均的偏离程度越大,且随时间波动也越强烈。     

A multiobjective steepest descent method with applications to optimal well control

Multiobjective optimization deals with mathematical optimization problems where two or more objective functions (cost functions) are to be optimized (maximized or minimized) simultaneously. In most cases of interest, the objective functions are in conflict, i.e., there does not exist a decision (design) vector (vector of optimization variables) at which every objective function takes on its optimal value. The solution of a multiobjective problem is commonly defined as a Pareto front, and any decision vector which maps to a point on the Pareto front is said to be Pareto optimal. We present an original derivation of an analytical expression for the steepest descent direction for multiobjective optimization for the case of two objectives. This leads to an algorithm which can be applied to obtain Pareto optimal points or, equivalently, points on the Pareto front when the problem is the minimization of two conflicting objectives. The method is in effect a generalization of the steepest descent algorithm for minimizing a single objective function. The steepest-descent multiobjective optimization algorithm is applied to obtain optimal well controls for two example problems where the two conflicting objectives are the maximization of the life-cycle (long-term) net-present-value (NPV) and the maximization of the short-term NPV. The results strongly suggest the multiobjective steepest-descent (MOSD) algorithm is more efficient than competing multiobjective optimization algorithms.     

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

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Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

经略21世纪海上丝路:重要航线、节点及港口特征

为了更好地认识21世纪海上丝绸之路(简称"海上丝路"),文章对"海上丝路"涉及的重要航线、节点及港口的地理位置、气候状况、水文特征、商业价值、人文背景等进行梳理。重要航线、节点及港口的使用与管理作为"海上丝路"建设的基础要素,是与造船能力并列的核心资源,三者之间环环相扣,构成"海上丝路"健康运营的完整体系。与沿"海上丝路"国家稳步推进航线、节点及港口的管理、开发与维护,打造坚实的战略支撑点、现代之"海上驿站",是成功实现我国资源多样化、产业走出去、贸易全球化的最佳路径之一,以此为契机,融入现有国际海洋法公约并在践行过程中制定利我的海上政策体制,助力"海之梦"、"中国梦"。     

江苏省沿海海域影像地图集的编制与研究

2013年,江苏省成为国家3个海域无人机(UAV)基地建设省份之一。按照国家海域无人机基地建设的有关要求,江苏省海域动态监视监测中心先后购置了海域无人机和应急指挥监控车,并沿着江苏近千千米的海岸带开展了大量的无人机航拍。为将已有的无人机航拍数据给更多的海域管理者和社会公众提供服务,着手编制《江苏省沿海海域影像地图集》。文章简述了江苏沿海开发概况,介绍了图集的编制过程和技术创新点,对其他影像地图集的编制具有一定的参考价值。     

海洋生态文明建设对海域使用论证工作的具体指导

海洋生态文明建设是我国生态文明建设的重要组成部分。海域使用论证作为各类用海项目用海可行性分析的技术性分析工作,在论证工作中引导用海项目贯彻海洋生态文明建设理念,落实海洋生态文明建设具体方案,极具现实意义。文章按照海域使用论证工作流程,依据海洋生态文明建设具体方案,按阶段分析了海域使用论证工作的具体工作内容,以求通过海域使用论证工作落实海洋生态文明建设对用海项目的具体指导。     

锈蚀钢筋在疲劳荷载作用下压磁场分布研究

针对锈蚀钢筋的疲劳损伤与寿命评估中的难度大、精度低等问题,引入压磁检测技术,对锈蚀钢筋疲劳过程中的压磁场分布进行检测,从宏观与微观相结合的角度分析压磁场分布与疲劳损伤之间的联系。试验结果表明,锈蚀钢筋的压磁场分布能够反映疲劳损伤的演变规律,疲劳后期非线性特征加剧,锈蚀率及应力幅越大则变化越为明显,磁感强度值、磁场分布梯度、"反转"现象等均有助于进行疲劳损伤评价与寿命预测。研究结果可为压磁无损检测技术在钢筋混凝土结构中的应用提供依据。     

Length of stay in urban areas of circular migrants from the mountainous areas in China

Currently, there is limited literature dealing with the length of stay of circular migrants in urban areas (LSCMU), although many studies have discussed the phenomenon of migration and the determinants of migration. This study attempts to fill that gap using survey data from the mountainous areas of Chongqing, Southwest China. From a comparative perspective, this study divided workers into two groups (a young group aged between 16 and 35 years and an old group aged between 36 and 65 years). The average LSCMU values for the young and old groups were 225 days and 174 days, respectively. Two multi-regression models were used to estimate the determinants of LSCMU in the two groups. The results showed that LSCMU was closely related to individual factors in both groups, including gender, age and job training. Family and community factors, including household size, arable land per capita and the distance from market, had much weaker effects on the dependent variable, especially in the older group. It was noticeable that job training had significant positive effects on LSCMU in both groups; these findings have special implications for the urbanization process in China.