Dolomite formation within microbial mats in the coastal sabkha of Abu Dhabi (United Arab Emirates)

Microbial mediation is the only demonstrated mechanism to precipitate dolomite under Earth surface conditions. A link between microbial activity and dolomite formation in the sabkha of Abu Dhabi has, until now, not been evaluated, even though this environment is cited frequently as the type analogue for many ancient evaporitic sequences. Such an evaluation is the purpose of this study, which is based on a geochemical and petrographic investigation of three sites located on the coastal sabkha of Abu Dhabi, along a transect from the intertidal to the supratidal zone. This investigation revealed a close association between microbial mats and dolomite, suggesting that microbes are involved in the mineralization process. Observations using scanning electron microscopy equipped with a cryotransfer system indicate that authigenic dolomite precipitates within the exopolymeric substances constituting the microbial mats. In current models, microbial dolomite precipitation is linked to an active microbial activity that sustains high pH and alkalinity and decreased sulphate concentrations in pore waters. Such models can be applied to the sabkha environment to explain dolomite formation within microbial mats present at the surface of the intertidal zone. By contrast, these models cannot be applied to the supratidal zone, where abundant dolomite is present within buried mats that no longer show signs of intensive microbial activity. As no abiotic mechanism is known to form dolomite at Earth surface conditions, two different hypotheses can reconcile this result. In a first scenario, all of the dolomite present in the supratidal zone formed in the past, when the mats were active at the surface. In a second scenario, dolomite formation continues within the buried and inactive mats. In order to explain dolomite formation in the absence of active microbial metabolisms, a revised microbial model is proposed in which the mineral‐template properties of exopolymeric substances play a crucial role.     

The action of wind and water in a mid‐Cretaceous subtropical erg‐margin system close to the Variscan Iberian Massif,Spain

Aeolian processes and ephemeral water influx from the Variscan Iberian Massif to the mid‐Cretaceous outer back‐erg margin system in eastern Iberia led to deposition and erosion of aeolian dunes and the formation of desert pavements. Remains of aeolian dunes encased in ephemeral fluvial deposits (aeolian pods) demonstrate intense erosion of windblown deposits by sudden water fluxes. The alternating activity of wind and water led to a variety of facies associations such as deflation lags, desert pavements, aeolian dunes, pebbles scattered throughout dune strata, aeolian sandsheets, aeolian deposits with bimodal grain‐size distributions, mud playa, ephemeral floodplain, pebble‐sand and cobble‐sand bedload stream, pebble–cobble‐sand sheet flood, sand bedload stream, debris flow and hyperconcentrated flow deposits. Sediment in this desert system underwent transport by wind and water and reworking in a variety of sub‐environments. The nearby Variscan Iberian Massif supplied quartzite pebbles as part of mass flows. Pebbles and cobbles were concentrated in deflation lags, eroded and polished by wind‐driven sands (facets and ventifacts) and incorporated by rolling into the toesets of aeolian dunes. The back‐erg depositional system comprises an outer back‐erg close to the Variscan highlands, and an inner back‐erg close to the central‐erg area. The inner back‐erg developed on a structural high and is characterized by mud playa deposits interbedded with aeolian and ephemeral channel deposits. In the inner back‐erg area ephemeral wadis, desiccated after occasional floods, were mud cracked and overrun episodically by aeolian dunes. Subsequent floods eroded the aeolian dunes and mud‐cracked surfaces, resulting in largely structureless sandstones with boulder‐size mudstone intraclasts. Floods spread over the margins of ephemeral channels and eroded surrounding aeolian dunes. The remaining dunes were colonized occasionally by plants and their roots penetrated into the flooded aeolian sands. Upon desiccation, deflation resulted in lags of coarser‐grained sediments. A renewed windblown supply led to aeolian sandsheet accumulation in topographic wadi depressions. Synsedimentary tectonics caused the outer back‐erg system to experience enhanced generation of accommodation space allowing the accumulation of aeolian dune sands. Ephemeral water flow to the outer back‐erg area supplied pebbles, eroded aeolian dunes, and produced hyperconcentrated flow deposits. Fluidization and liquefaction generated gravel pockets and recumbent folds. Dune damming after sporadic rains (the case of the Namib Desert), monsoonal water discharge (Thar Desert) and meltwater fluxes from glaciated mountains (Taklamakan Desert) are three potential, non‐exclusive analogues for the ephemeral water influx and the generation of hyperconcentrated flows in the Cretaceous desert margin system. An increase in relief driven by the Aptian anti‐clockwise rotation of Iberia, led to an altitude sufficient for the development of orographic rains and snowfall which fed (melt)water fluxes to the desert margin system. Quartzite conglomerates and sands, dominantly consisting of quartz and well‐preserved feldspar grains which are also observed in older Cretaceous strata, indicate an arid climate and the mechanical weathering of Precambrian and Palaeozoic metamorphic sediments and felsic igneous rocks. Unroofing of much of the cover of sedimentary rocks in the Variscan Iberian Massif must therefore have taken place in pre‐Cretaceous times.     

Fluorine in basalts from Iceland

The fluorine content of Icelandic tholeiitic and alkaline basalts matches values found in similar rocks from other areas. Covariation between fluorine and incompatible minor elements such as potassium or phosphorus is found in evolved tholeiites and alkali basalts. Lack of such covariation in primitive olivine tholeiites indicates that fluorine and other incompatible minor and trace elements are not controlled by minerals such as amphibole, mica or apatite in the mantle residue, and that the covariation between these elements in the evolved basalts cannot be inherited from the mantle. Model calculations on rocks from the Langjökull area show that olivine tholeiite suites are, if derived by simple fractional crystallization, enriched in incompatible elements much in excess of the increase due to crystal removal. These observations are taken to indicate that the well documented covariation between fluorine and other incompatible elements is not established until evolution of the basaltic magma has started in crustal holding chambers. The constancy of element ratios and enrichment in excess of what can be accounted for by crystal fractionation or incremental addition of new batches of primitive magmas does indicate (1) mineral control involving amphibole, mica or apatite and (2) addition of fluorine, potassium and phosphorous from an external source. It is argued that this source is the crustal envelope of the holding chamber.     

Morphotectonics of the Iberian Peninsula

A morphotectonic interpretation of the relief of the Iberian Peninsula (IP) is presented based on an analysis of its gross forms. Several geological–geophysical and geomorphological methods were used in order to build up a morphostructural sketch. Three main categories were established using the approach of Rantsman (1979): Territorial Units (1-megablock, 9-macroblocks, 34-mesoblocks, 1.374-blocks and 2.523-microblocks); Morphostructural Alignments (2-first, 8-second, 20-third and 1-fourth rank; and 43 knots between Morphostructural Alignments (second-fourth rank). The main seismic activity is concentrated on the first- and second-rank lineaments, and some important epicenters are located near the lineament intersections. The origin of the earthquakes in the vicinity of such knots can be explained by the forcing/pushing of macroblocks westwards. The existence of earthquakes along the lineaments may be explained by tension. From the present study it appears that earthquake occurrence in the IP is due principally to stress concentrations around morphotectonic zones. A seismotectonic interpretation of the IP is also presented. On this map three zones are distinguished (A, B, C), each of them with a different active level and dimensions.Received: 25 November 2000     

Energy-intensive manufacturing sectors in China: policy priorities for achieving climate mitigation and energy conservation targets

In this study, a long-range energy alternative planning (LEAP) model was built to evaluate the relative priority of three kinds of policies expected to be implemented for the energy-intensive manufacturing sectors (EIMS) in China to achieve CO₂ mitigation and energy conservation targets. These policies encourage (1) the use of more electricity instead of coal; (2) the continuous improvement of energy efficiency; and (3) a shift to other less energy-demanding sectors. The results indicate that the policy of shifting economic activity from the EIMS to other sectors is most helpful for China to achieve its targets of mitigating CO₂ emissions and conserving energy. Encouraging the EIMS to use more electricity can help China to achieve a higher proportion of non-fossil-fuel based energy in its overall primary energy consumption. No single policy will allow China to achieve all the targets, emphasizing the need for an integrated policy design that combines all types of policies.

Key policy insights

• The policy of encouraging a shift to less energy intensive industries should receive the highest priority in aiming to peak China's energy-related CO₂ emissions as early as possible, and lower overall CO₂ emissions, coal consumption and primary energy consumption in the long run.

• Encouraging a shift to electricity should go hand-in-hand with greater energy efficiency, otherwise such a policy cannot help China significantly reduce energy-related CO₂ emissions.

• Encouraging the EIMS to use more electricity should receive the highest priority in helping China achieve a higher proportion of non-fossil-fuel based energy in its overall primary energy consumption.

     

Maximum extent and readvance dynamics of the Irish Sea Ice Stream and Irish Sea Glacier since the Last Glacial Maximum

The BRITICE-CHRONO Project has generated a suite of recently published radiocarbon ages from deglacial sequences offshore in the Celtic and Irish seas and terrestrial cosmogenic nuclide and optically stimulated luminescence ages from adjacent onshore sites. All published data are integrated here with new geochronological data from Wales in a revised Bayesian analysis that enables reconstruction of ice retreat dynamics across the basin. Patterns and changes in the pace of deglaciation are conditioned more by topographic constraints and internal ice dynamics than by external controls. The data indicate a major but rapid and very short-lived extensive thin ice advance of the Irish Sea Ice Stream (ISIS) more than 300 km south of St George's Channel to a marine calving margin at the shelf break at 25.5 ka; this may have been preceded by extensive ice accumulation plugging the constriction of St George's Channel. The release event between 25 and 26 ka is interpreted to have stimulated fast ice streaming and diverted ice to the west in the northern Irish Sea into the main axis of the marine ISIS away from terrestrial ice terminating in the English Midlands, a process initiating ice stagnation and the formation of an extensive dead ice landscape in the Midlands.     

Spatial Pattern and Order in Sunbelt Retailing: Shopping in Phoenix in the Twenty-First Century

Understanding the complexity of store location in sprawling polycentric cities requires exploitation of new spatial analysis methods that can decipher patterns in georeferenced point data. This article shows how the intrametropolitan location of retailing is best understood as a series of interconnected spatial distributions with varying order-based characteristics. A scattered pattern, which initially appears random or chaotic, is a web of differentiated spatial regimes containing wide-ranging order. A variety of clustering and colocation methods are used to uncover spatial patterns of retailing in Phoenix, Arizona. The analysis simultaneously identifies establishment associations and disassociations within and across sectors. Results show that clothing and motor vehicles are the most likely to cluster next to establishments in the same sector. These sectors also have strong intersectoral relationships across retailing. We find limited evidence that the size of establishments significantly increases with distance from sectoral mean centers. Geospatial technologies are increasingly used by individual retailers to locate and manage their facilities. It is important that scholarly analysis of retailing spatial patterns keeps pace, especially as cities grow and land use and land value patterns become more complex.     

Actualistic taphonomy of barn owl pellet-derived small mammal bone accumulations in arid environments of South America

The avian family of barn owls (Tytonidae, Strigiformes) is the most geographically widespread group of owls in the world and one of the most common accumulators of small mammal bone and tooth remains recovered from archaeological and palaeontological sites. The present study analyses the taphonomic characteristics of modern barn owl pellet-derived small mammal bone and tooth accumulations at three roosting sites from the central Monte Desert, one of the most arid regions of South America. In order to identify the taphonomic signature of this predator in the formation of zooarchaeological and palaeontological accumulations, taxonomic structure, relative abundance of skeletal elements, bone and teeth breakage patterns, and digestion were evaluated. Taphonomic results locate the barn owl in modification category 1 (light modifier). Although the general taphonomic results obtained in the present study were similar to a common barn owl pattern, the three samples showed variability both among them and with other samples previously reported in different regions of the world. Very light digestion was detected on incisors, whereas the proportion of digestion on incisors was close to 20%. Cricetid and murid rodents as well as marsupials were detected. Salinomys delicatus, a scarcely known and endangered cricetid species, was recovered.     

The first description and confirmation of the Vista Alegre impact structure in the Paraná flood basalts of southern Brazil

Abstract– The Vista Alegre structure, centered at 25°57′S and 52°41′W, has been recently proposed as a meteorite impact structure. The 9.5 km‐diameter structure is located in the Paraná state of southern Brazil, within the Paraná Basin, which contains one of the largest and most extensive flood basalt provinces on Earth. The Paraná flood basalts belong to the Serra Geral Formation and are temporally related to the opening of the South Atlantic Ocean, having been dated at about 133–132 Ma. Tholeiitic basalts dominate the western portion of Paraná state, with some minor rhyodacites. Morphologically, Vista Alegre has a prominent circular outline, in the form of an incomplete ring of escarpments, and an inner depression. The presence of a central uplift is not obvious, but it is inferred by the occurrence of deformed sandstone blocks near the center of the structure. These sandstones are possibly related to the Triassic Pirambóia Formation and/or to the Cretaceous Botucatu Formation. These units are normally at stratigraphic depths of about 700–800 m below the present surface in this portion of the Paraná Basin. The structure appears to be in an advanced erosion stage and its interior is occupied by a soil cover several meters thick, extensively used for agriculture. As a result there are limited outcrops in the interior of the structure, all of polymict breccias, some of them melt‐bearing. We report the extensive occurrence of shatter cones, in the form of fine‐grained rock clasts within the polymict breccias. The shatter cone‐bearing breccias occur at different locations within the structure, separated by several kilometers. The nested shatter cones range in size from about 0.5 to 20 cm for individual cones, and up to half a meter for complete assemblages. The shatter cones formed in fine‐grained Parana flood basalt and might be the first examples of shatter cones in such a rock type. In addition, planar deformation features (PDFs) were found in quartz grains within sedimentary rock clasts of the polymict breccia. These findings confirm the impact origin of the Vista Alegre structure.     

Mapping groundwater development costs for the transboundary Western Aquifer Basin, Palestine/Israel

The costs of developing groundwater in the Western Aquifer Basin vary considerably across the West Bank and Israel. One of the main reasons for this variability is the diverse hydrogeological conditions within the aquifer. Using data from recent hydrogeological investigations, an estimate of the variation of both the drilling and pumping costs was calculated and then mapped across the Upper and Lower Aquifers within the Western Aquifer Basin. These groundwater cost maps proved helpful in analyzing the impacts of hydrogeology on water supply, and also in communicating complex hydrogeological information to a broader audience. The maps clearly demonstrate that the most cost-effective area to develop groundwater is along the Green Line—the 1949 armistice boundary between Israel and the Palestinian West Bank. Any migration of this boundary eastwards will affect the cost and feasibility of developing groundwater within Palestine, making abstraction from the Upper Aquifer impracticable, and increasing the cost of developing the Lower Aquifer. Therefore, the separation wall, which is being constructed to the east of the Armistice Line in Palestinian territory, will significantly reduce the ability of the Palestinians to develop groundwater resources.