Transition from shoshonitic to adakitic magmatism in the eastern Pontides,NE Turkey: Implications for slab window melting

The formation of the eastern Pontides orogenic belt has been widely assigned to a northward subduction of the Neotethyan oceanic slab during the late Mesozoic–Cenozoic. Here we provide an alternate model based on new geological, geochemical and isotopic data. The magmatic activity in the far south of the belt started in the early Campanian with shoshonitic trachyandesites and associated pyroclastics. This sequence is covered by the late Campanian–early Maastrichtian reefal limestones and another stage of high-K volcanism represented by analcimized leucite-rich ultrapotassic rocks of the Maastrichtian–early Paleocene (?) ages. The shoshonitic and ultrapotassic rocks, with K₂O contents ranging from 0.26 to 6.95 wt.%, display broadly similar rare earth and multi-element distribution patterns. Both rock types are enriched in LILE and LREE and depleted in HFSE (Nb, Ta and Ti), suggesting a subduction-enriched mantle source for the magma generation. Subsequently, during the late Paleocene, a stage of acidic magmatism (SiO₂ of 53.25–73.61 wt.%) that shows adakitic geochemical characteristics including high Sr/Y (46–416) and La/Yb (11–51) and low Y (2.6–12.2 ppm), is documented characterized by melting of a mafic source such as the MORB crust with garnet in the residue. The adakitic magmatism began at ~ 56 Ma and migrated toward the north through time, culminating with porphyritic andesites (~ 47 Ma) that were emplaced in the Gumushane–Bayburt line and its vicinity. North of this line, coeval magmas show typical calc-alkaline nature and continued to develop toward further north until the middle to late Eocene. Based on the spatial and temporal variations in the magmas generated in the eastern Pontides orogenic belt, we propose a new geodynamic model to explain the tectonomagmatic evolution of these rocks and correlate the adakitic magmatism to ridge subduction and slab window process within a south-dipping subduction zone. Our model is in contrast to the previous proposals which envisage partial melting or delamination of thickened lower continental crust due to the collision in the south during the Paleocene–Eocene.     

2016年中资海外矿产能源投资报告

尽管全球经济复苏乏力,需求不振,2016年矿业实体经济仍旧处于低迷状态;但是经历了连续5年的下滑之后,2016年矿产品价格和矿业资本市场已经发生了巨大的变化,矿产品价格出现了难见的普涨趋势.10年来,中资海外矿产能源投资步伐逐年加快,现在很多矿业投资者已经在矿业低谷启动逆周期投资,特别是在“一带一路”战略引领下,中资企业纷纷“走出去”,希望能在全球矿产资源配置中占有先机.很多中资矿企在海外矿业投资中取得了丰硕的成果.根据统计,2016年宣布和完成的中资海外矿产能源投资项目有103项,宣布和完成投资总额达394.93亿美元;其中,2016年完成投资项目58宗,完成投资金额达158.96亿美元,其中固体矿产投资金额达89.32亿美元.     

基于河口潮间带底栖微藻群落水平的环境质量状态评价

The feasibility of community-based bioassessment of environmental quality status was studied using microphytobenthos(MPB) in estuarine intertidal ecosystems.The sediment samples of MPB were collected monthly during a 1-year cycle(September 2006–August 2007) at four sampling stations in the Nakdong River Estuary,Korea.Environmental variables,such as salinity,radiation,grain size of sediment,Si(OH)_4(Si),nitrate(NO_3~–),nitrite(NO_2~–),ammonium(NH_4~+) and phosphates(PO_4~(3–)),were measured synchronously for comparison with biotic parameters.The statistical analyses were carried out for assessment the relationship between biotic and environmental parameters.The results showed that:(1) the MPB community structures were significant differences among four sampling stations;(2) spatial variation in the MPB communities were significantly correlated with environmental variables,especially the nutrient NH_4+ in combination with salinity and grain size;(3) three species(Navicula lacustris,Pleurosigma anglulatum and Fragilaria sp.1) were significantly correlated with nutrients and/or Si;and(4) the species richness and diversity were significantly correlated with the grain size.It is suggested that MPB communities may be used as a potentially robust bioindicator for assessing environmental quality status in estuarine intertidal ecosystems.     

THE CONSTITUTION OF COAL

In regard to the knowledge of the constitutions of coal we are still inthe Dark Ages. To the man in the street, coal is merely a dirty mass ofcombustible matter; to the engineer it is generally thought of in termsof its contents in carbon, velatile matter, moisture, ash and sulphur;     

The Lhasa Terrane: Record of a microcontinent and its histories of drift and growth

The Lhasa Terrane in southern Tibet has long been accepted as the last geological block accreted to Eurasia before its collision with the northward drifting Indian continent in the Cenozoic, but its lithospheric architecture, drift and growth histories and the nature of its northern suture with Eurasia via the Qiangtang Terrane remain enigmatic. Using zircon in situ U–Pb and Lu–Hf isotopic and bulk-rock geochemical data of Mesozoic–Early Tertiary magmatic rocks sampled along four north–south traverses across the Lhasa Terrane, we show that the Lhasa Terrane has ancient basement rocks of Proterozoic and Archean ages (up to 2870 Ma) in its centre with younger and juvenile crust (Phanerozoic) accreted towards its both northern and southern edges. This finding proves that the central Lhasa subterrane was once a microcontinent. This continent has survived from its long journey across the Paleo-Tethyan Ocean basins and has grown at the edges through magmatism resulting from oceanic lithosphere subduction towards beneath it during its journey and subsequent collisions with the Qiangtang Terrane to the north and with the Indian continent to the south. Zircon Hf isotope data indicate significant mantle source contributions to the generation of these granitoid rocks (e.g., ~ 50–90%, 0–70%, and 30–100% to the Mesozoic magmatism in the southern, central, and northern Lhasa subterranes, respectively). We suggest that much of the Mesozoic magmatism in the Lhasa Terrane may be associated with the southward Bangong–Nujiang Tethyan seafloor subduction beneath the Lhasa Terrane, which likely began in the Middle Permian (or earlier) and ceased in the late Early Cretaceous, and that the significant changes of zircon ε_Hf(t) at ~ 113 and ~ 52 Ma record tectonomagmatic activities as a result of slab break-off and related mantle melting events following the Qiangtang–Lhasa amalgamation and India–Lhasa amalgamation, respectively. These results manifest the efficacy of zircons as a chronometer (U–Pb dating) and a geochemical tracer (Hf isotopes) in understanding the origin and histories of lithospheric plates and in revealing the tectonic evolution of old orogenies in the context of plate tectonics.     

A petrologic, geochemical and Sr–Nd isotopic study on contact metamorphism and degassing of Devonian evaporites in the Norilsk aureoles, Siberia

Devonian evaporites and associated sedimentary rocks in the Norilsk region were contact metamorphosed during emplacement of mafic sills that form part of the end-Permian (~252 Ma) Siberian Traps. We present mineralogical, geochemical and Sr–Nd isotopic data on sedimentary rocks unaffected by metamorphism, and meta-sedimentary rocks from selected contact aureoles at Norilsk, to examine the mechanisms responsible for magma-evaporite interaction and its relation to the end-Permian environmental crisis. The sedimentary rocks include massive anhydrite, rock salt, dolostone, calcareous siltstones and shale, and the meta-sedimentary rocks comprise calcareous hornfels, siliceous hornfels and minor meta-anhydrite and meta-sandstone. Contact metamorphism took place at low pressure and at maximum temperatures corresponding to the phlogopite-diopside stability field. Calcareous hornfels have high CaO, MgO, CΟ₂, SΟ₃, low SiO₂ and initial Sr isotopic ratios of 0.7079–0.7092, features indicative of calcareous siltstone protoliths. Siliceous hornfels, in contrast, have high SiO₂, Al₂O₃, Na₂O, low in other major element oxides and initial Sr isotopic ratios of 0.7083–0.7152, consistent with pelitic or shaley protoliths. Loss of CO₂ in a subset of calcareous hornfels can be explained by decarbonation reactions during metamorphism, but release of SO₂ from evaporites cannot be accounted for by a similar mechanism. Occurrences of wollastonite and a variety of hydrous minerals in the calcareous hornfels are consistent with equilibration with hydrous fluid, which was capable of leaching large quantities of anhydrite in the presence of dissolved NaCl. In this way, substantial sediment-derived sulfur could have been mobilized, incorporated into the magmatic system and released to the atmosphere. The release of CO₂ and SO₂ from Siberian evaporites added to the variety of toxic gases generated during metamorphism of organic matter, coal and rock salt, contributing to the end-Permian environmental crisis.     

How Central Asian Orogeny Evolves: New Insights from End-Permian to Middle Triassic Magmatic Record along the Solonker Suture Zone

正Objective The modern Earth is characterized by two types of orogens:collisional orogen and accretionary orogen.It is widely accepted that the Central Asian Orogenic Belt(CAOB)is made up of widespread multiple ancient archipelagos.It has been recognized as a non-collisional orogen,contrasting with the archetypical AlpineHimalayan-type collisional orogens.Although the CAOB is     

Provenance of Cored Sediments from Active Margin off Southwestern Taiwan Deduced from Geochemical Constraints

The cored sediments sampled by R/V Marion Dufrense in the active margin off southwestern Taiwan on the east side of the Manila Trench are mostly muds consisting mainly of quartz, feldspar, illite, chlorite ＋ kaolinite with a trace amount of montmorillonite. The cored sediments have higher Fe, Ti, Cr, Cs, Li, Ni, and V but lower Ca, Na, Mn, Hf, Nb, Sr, Ta, U and Zr contents when compared with the upper continental crust（UCC, Taylor and McLennan, 1985）. The Eu/Eu＊ ratios of the sediments averaging 0.69 indicate that the recycling effect on the Eu anomaly may be minor and the contribution of mafic source rock was unimportant, which can also be depicted in the La-Th-Sc plot（Cullers, 1994） showing a ＂mixed origin＂ close to the felsic end member. The chemistry of the cored sediment can be explained by a mixing model designed by Ho and Chen（1996） with four end members i.e., greywacke, shale, quartzite and limestone, which are widely distributed in the Cenozoic formations of southern Taiwan with greywacke as the dominant contributor followed by shale.     

Mesozoic high-Ba–Sr granitoids from North China: geochemical characteristics and geological implications

Abstract Mesozoic magmatism occurred extensively in the North China block (NCB) and the Dabie–Sulu orogen (DSO) post-dating the North–South China collision, resulting in abundant intrusive and volcanic rocks ranging from basic to acidic compositions. The intermediate-acidic intrusive rocks can be grouped into two types, namely high-Ba–Sr granitoids and low-Ba–Sr granitoids that both have distinct geochemical characteristics. The high-Ba–Sr granitoids are similar in most of the incompatible trace element systematics to the associated basic rocks, which probably originated from melting of subcontinental lithospheric mantle, indicating significant mantle contributions to them. Geochemical similarities are observed between the basic rocks from the NCB and DSO, implying a regional-scale magma-generating mechanism and that mantle enrichment beneath the DSO was independent from the Triassic deep continental subduction in the region. We therefore interpret that the Mesozoic magmatism resulted from delamination of the ancient lithospheric mantle beneath the eastern part of North China.