SO4^2-改性铁铝复合层柱粘土的制备及其催化性能研究

由共聚法制得的铁铝复合交联剂交换钠基蒙脱石层间的水合钠离子,再经SO42-改性处理制备了铁铝复合层柱粘土固体超强酸催化剂.利用xRD、FT-IR和BET法对催化剂的结构进行了表征.以乙酸正丁酯的合成反应为探针反应对催化剂的活性进行了测试.通过正交实验确定了铁铝复合交联粘土SO42-改性最佳工艺条件.研究了催化剂对探针反应的选择性及重复使用情况.结果表明:在由实验确定的最佳改性工艺条件下,乙酸的转化率达92.2%,反应中无副产物产生,催化剂具有较好的重复使用性能.     

藏北羌塘地区侏罗系中、基性火山岩的发现及意义

经2003-2006年度西藏1∶25万加措、丁固幅区域地质调查,在冈玛错断裂带内首次发现了一套侏罗系喷发-喷溢相中、基性火山岩与石炭系及二叠系呈角度不整合;岩石地球化学特征显示为海相大陆板内向火山弧转换机制下形成的岩浆岩.为进一步研究羌塘地区侏罗纪岩相古地理和中生代构造演化提供了重要资料.     

黔东北地区钒矿物质组分研究

钒矿石的主要化学成份为SiO2和Al2O3,有机质总量一般为3.24%~10%,其次为TFe1.85%~3.25%,绝大部分V2O5含量均在1%左右,少部分大于2%;伴生元素以Mo、Ag、Cu、TiO2、P2O5、Ni、Co为主。     

中国辽宁-浙江沿海地区川蔓草分布现状、生态特征及其主要威胁

川蔓草(Ruppia)是一种广泛分布在咸水、半咸水生境中的广义海草, 其形成的川蔓草床具有重要的生态学价值。然而, 对于其在中国境内的分布情况尚缺乏大范围的调查。基于此, 本研究于2016—2019年对中国辽宁-浙江沿海区域的川蔓草分布情况进行了初步调查, 探究了调查区域内川蔓草的生境分布类型, 及生态特征, 分析了川蔓草床的主要威胁, 并提出了对川蔓草床科学管理的建议。结果表明: 川蔓草在中国浙江省、江苏省、山东省、天津市、河北省、辽宁省均有分布; 分布面积超过2 100 ha; 该区域内分布的川蔓草物种均为中国川蔓草, 主要分布生境包括咸水养殖池塘、咸水沟渠(池塘)、盐场、瀉湖(湖泊)、潮间带(围堰)5类; 人类活动影响(人工清捞、施药、河道工程等)与极端气候事件(极端干旱事件)都会导致川蔓草床退化, 但大部分川蔓草床可以依靠沉积物中的种子库在环境适宜时进行种群恢复; 不同生境中的川蔓草种群特征差异较大, 因此, 对不同生境中的川蔓草应制定差异性管理措施。     

Effect of Cyclic Loading Frequency on Undrained Behaviors of Undisturbed Marine Clay

Based on a series of cyclic triaxial tests, the effect of cyclic frequency on the undrained behaviors of undisturbed marine clay is investigated. For a given dynamic stress ratio, the accumulated pore water pressure and dynamic strain increase with the number of cycles. There exists a threshold value for beth the accumulated pore water pressure and dynamic strain, below which the effect of cyclic frequency is very small, but above which the accumulated pore water pressure and dynamic strain increase intensely with the decrease of cyclic frequency for a given number of cycles. The dynamic strength increases with the increase of cyclic frequency, whereas the effect of cyclic frequency on it gradually diminishes to zero when the number of cycles is large enough, and the dynamic strengths at different frequencies tend to the same limiting minimum dynamic strength. The test results demonstrate that the reasons for the frequency effect on the undrained soil behaviors are beth the creep effect induced by the loading rate and the decrease of sample effective confining pressure caused by the accumulated pore water pressure.     

PARTHENOGENESIS AND THE GENETIC PROPERTIES OF PARTHENOSPOROPHYTES OF UNDARIA PINNATIFIDA

Parthenogenesis in Laminaria and Alaria has been observed by Yabu, Nakaharaet al. and Fang et al. After we had made some preliminary progress in the study ofthe haploid phases of Laminaria japonica, similar study was started in 1974 on anotherspecies of brown algae, i. e., Undaria pinnatifida Sur. Some interesting results of such astudy on Undaria are summarized here. I. MATERIAL AND METHODS The material used in the experiments was mature sporophyte of Undaria collectedfrom the lower tide regions at Qingdao. The methods used in collecting Undaria zoo-     

THE DISTRIBUTION OF PLANKTONIC OSTRACODA ALONG THE WESTERN COAST OF TAIWAN STRAITS

The present paper studies the seasonal change, quantitative variation and distributional patterns of planktonic Ostracoda along the western coast of the Taiwan Straits and their relationship with various environmental factors, especially those of the movement, intensification and decay and interaction of different water systems.Except for some study of Ostracqda in the Straits[14], ours is based on the samples of planktonic Ostracoda and field hydrological and chemical data collected during the two comprehensive investigations (Oct. 1961-Sept. 1962 (no data for July, 1962) 23°16′-24°15′ N, 117°16′-118°13′E and March, 1963-Feb. 1964, 24°34′-25°43′ N, 118°46′-119°52′ E).The total amounts of planktonic Ostracoda along the western coast of Taiwan Straits show evident seasonal variations with greater amounts in summer and autumn. The yearly maximum appeared in October and subpeaks in May and August. The quantity of the animal was lowest from January to April.There are all together 17 species     

双斑东方鲀人工繁殖及育苗技术

本文报道了福建省水产研究所 2 0 0 1年双斑东方人工繁殖及育苗过程与结果 .在春季当海水水温达到 1 6℃以上时 ,用DOM、LRH A3或HCG进行催产 ,混和或单一使用 ,剂量视亲鱼性腺成熟度而定 .受精卵在水温 1 8.0～ 2 2 .4℃、盐度 2 2 .1～2 8.6条件下 ,经 1 1 7～ 1 56h孵化 .用 2 0 5万尾开口仔鱼培育出平均全长为 3 7mm ,平均体重为 1 .3 g的鱼苗 52 .3 5万尾 ,成活率 2 5.5%.此外 ,对亲鱼的暂养、催产、受精卵的孵化、仔鱼的前期培育和后期培育等关键环节进行了探讨 .     

亚热带沿海景观的旅游保护性开发及建设探讨--以福建沿海为例

依据地貌学和风景学的角度,福建沿海景观以闽江口和九龙江口为界可分为3个景观亚区,并具有多样性与复杂性、动态性与脆弱性和关联性与分异性等特征.本文运用景观生态的原理研究沿海景观的构成与格局,在沿海景观的分类和特征概括的基础上,探讨福建沿海景观旅游开发与建设的模式.通过维护沿海景观系统的稳定,优化沿海各景观亚区的分布格局,提高沿海景观的整体舒适性和挖掘文化景观的内涵等应对措施以实现福建沿海旅游的科学发展.     

珠江口沉积物酸挥发性硫化物与重金属生物毒性的研究

研究了2003年10月采于珠江口5个站位的沉积物剖面酸挥发性硫化物(AVS)和同时提取的重金属(SEM:Pb,Zn,Cu,Cd,Ni)。其中,站位1、2位于中滩,其沉积物的AVS含量变化范围较小,为0.25—4.06μmol.g-1;站位3、4位于西滩,其沉积物的AVS含量变化范围较大,为0—26.09μmol.g-1。中滩和西滩沉积物的AVS含量均随深度增加。西滩表层沉积物的AVS含量接近于零,这可能与该水域较强的底层流和沉积物的再悬浮作用有关。站位5位于珠江口外侧,其表层沉积物的AVS含量相对较高,且垂向变化较小,可能是还原性沉积物间歇性再悬浮后重新沉积的结果。站位1、2和5沉积物中同时提取的重金属含量大体在0.95±0.2μmol.g-1范围内,随深度增加略呈下降趋势;而西滩沉积物重金属含量相对较高,为1.43—2.42μmol.g-1,且在一定深度范围内随深度增加呈明显下降的趋势,表明珠江口西滩沉积物中的重金属污染有加重的趋势。对AVS/SEM摩尔比值和单个金属的毒性效应研究显示,珠江口内尤其是西滩的表层沉积物存在重金属污染,对其中生活的底栖生物具有潜在的毒性效应。