Coulometric TCO2 analyses for marine studies; an introduction

Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO₂) in marine waters is described. An extractor—stripper removes CO₂ that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH^? ions for the titration of the acid formed by the reaction of CO₂ and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO₂ determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO₃ into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l^?1 was found for 17 samples of Bermuda coastal waters having a mean TCO₂ of 2007.2 μmol l^?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO₂.     

Source flow expansion of monatomic gas into vacuum under external field of forces

The steady flow expansions of monatomic gases consisting of Maxwellia molecules into a vacuum moving under external forces with a source of spherical symmetry are investigated. The analysis is based on the B-G-K model of the Boltzmann equation with the approximation in hypersonic limit. The kinetic equation is solved by using the moment method. Analytical forms for the density and temperature are obtained for small and large distances from the source. The results show that the temperature in free expansion is less than that in the case of the expansion under the influence of external field of forces.     

Spatial and temporal variations of solar coronal loops

Skylab EUV observations of an active region near the solar limb were analyzed. Both cool (T < 10⁶ K) and hot (T > 10⁶ K) loops were observed in this region. For the hot loops the observed intensity variations were small, typically a few percent over a period of 30 min. The cool loops exhibited stronger variations, sometimes appearing and disappearing in 5 to 10 min. Most of the cool material observed in the loops appeared to be caused by the downward flow of coronal rain and by the upward ejection of chromospheric material in surges. The frequent EUV brightenings observed near the loop footpoints appear to have been produced by both in situ transient energy releases (e.g. subflares) and the infall/impact of coronal rain. The physical conditions in the loops (temperatures, densities, radiative and conducting cooling rates, cooling times) were determined. The mean energy required to balance the radiative and conductive cooling of the hot loops is approximately 3 × 10^–3 erg cm^–3 s^–1. One coronal heating mechanism that can account for the observed behavior of the EUV emission from McMath region 12634 is heating by the dissipation of fast mode MHD waves.     

A Unified Model for Black Hole X-Ray Binary Jets?

We have recently put forward a ‘unified’ semi-empirical model for the coupling between accretion and jet production in galactic black hole X-ray binaries. In this paper, we summarise this model and briefly discuss relevant considerations that have arisen since its publication.     

一种基于Ohta-Okamoto签名的门限群签名方案

在修改的Ohta_Okamoto数字签名方案基础上,设计出了一个新的(t,n)门限签名方案。该方案具有可验证性和防止内部成员合谋攻击;而且验证者在验证群签名的有效性计算的复杂性与一般个人签名方案一样。该方案的安全性是基于大整数的因式分解,因此在计算上是安全的。     

Arsenic incorporation in a salt marsh ecosystem

Replicate portions of a Delaware salt marsh were enclosed in cylindrical microcosms and exposed to elevated levels of inorganic arsenic (arsenate). All biotic and abiotic components in dosed cylinders rapidly incorporated arsenic. Spartina blades showed the greatest arsenic enrichment, with dosed plants incorporating arsenic concentrations an order of magnitude higher than controls. Spartina detritus and sediments also exhibited greatly elevated arsenic concentrations. Virtually all of the arsenic was incorporated into plant tissue or strongly sorbed to cell surfaces. Thus, elevated arsenic concentrations in estuarine waters will be reflected in living and non-living components of a salt marsh ecosystem, implying that increased arsenic will be available to organisms within the marsh ecosystem.     

Yields of Nucleosynthesis from massive and intermediate mass stars and constraints on their final evolution

Nucleosynthetic yields and production rates of helium and heavy elements are derived using new initial mass functions which take into account the recent revisions in O star counts and the stellar models of Maeder (1981a, b) which incorporate the effects of massloss on evolution. The current production rates are significantly higher than the earlier results due to Chiosi & Caimmi (1979) and Chiosi (1979), and a near-uniform birthrate operating over the history of the galactic disc explains the currently observed abundances. However, the yields are incompatibly high, and to obtain agreement it is necessary to assume that stars above a certain mass do not explode but proceed to total collapse. Further confirmation of this idea comes from the consideration of the specific yields and production rates of oxygen, carbon and iron and the constraints imposed by the observational enrichment history in the disc as discussed by Twarog & Wheeler (1982). Substantial amounts of⁴He and¹⁴C, amongst the primary synthesis species, are contributed by the intermediate mass stars in their wind phases. If substantial numbers of them exploded as Type I SN, their contribution to the yields of¹²C and⁵⁶Fe would be far in excess of the requirements of galactic nucleosynthesis. Either efficient massloss precludes such catastrophic ends for these stars, or the current stellar models are sufficiently in error to leave room for substantial revisions in the specific yields. The proposed upward revision of the¹²C (α,γ)¹⁶O rate may produce the necessary changes in stellar yields to provide a solution to this problem. Stars that produce most of the metals in the Galaxy are the same ones that contribute most to the observed supernova rate.