碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞

建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。     

柴达木盆地北缘侏罗系不同沉积环境烃源岩生物标志物特征及其应用

柴达木盆地北缘地区侏罗系(中下侏罗统)的优质烃源岩主要发育于湖相与三角洲相环境。研究了不同时代、不同沉积环境中烃源岩的生物标志物组成特征,结果发现,有3类化合物的分布与组成差异显著,包括三环萜烷(C19、C20、C21)的分布型式、重排藿烷的丰度以及规则甾烷的相对组成。其中,不同时代的差异主要体现在规则甾烷组成上;而不同沉积环境的差异主要体现为三环萜烷(C19、C20、C21)的分布型式及重排藿烷的丰度。分析认为,这些差异与烃源岩的沉积环境及其生源组成有密切关系。据此,初步将这些参数应用于两方面研究,一是为划分地层沉积环境提供“生物标志物相标志”,二是研究油源对比,取得良好效果。因此,本文研究结果具有重要实用价值与参考意义。     

对松辽盆地钱家店凹陷铀成矿作用的重新认认识

钱家店凹陷中的含矿层位主要为上白垩统姚家组,前人认为其中的红色砂岩为原生成因,但大量的证据证实砂岩原生应以灰色为主,红色砂岩为后生氧化蚀变造成,并控制着钱家店铀矿床铀矿化的产出.在此基础上建立该矿床的后生蚀变分带,依次为红色蚀变带、黄色蚀变带、灰白色蚀变带、过渡带、原生带,红色蚀变带为主要的氧化带,铀矿化主要集中在过渡带.平面上铀矿化主要分布于层间氧化带前锋线附近的位置,并在氧化舌状体的前端和两个氧化舌状体之间存在铀的富集.文章最后还建立了该矿床的成矿模式,并对区域上层间氧化带的展布进行了讨论.     

Zircon U–Pb ages, Hf and O isotopes constrain the crustal architecture of the ultrahigh-pressure Dabie orogen in China

The crustal structure of the Dabie orogen was reconstructed by a combined study of U–Pb ages, Hf and O isotope compositions of zircons from granitic gneiss from North Dabie, the largest lithotectonic unit in the orogen. The results were deciphered from metamorphic history to protolith origin with respect to continental subduction and exhumation. Zircon U–Pb dating provides consistent ages of 751 ± 7 Ma for protolith crystallization, and two group ages of 213 ± 4 to 245 ± 17 Ma and 126 ± 4 to 131 ± 36 Ma for regional metamorphism. Majority of zircon Hf isotope analyses displays negative ε_Hf(t) values of − 5.1 to − 2.9 with crust Hf model ages of 1.84 to 1.99 Ga, indicating protolith origin from reworking of middle Paleoproterozoic crust. The remaining analyses exhibit positive ε_Hf(t) values of 5.3 to 14.5 with mantle Hf model ages of 0.74 to 1.11 Ga, suggesting prompt reworking of Late Mesoproterozoic to Early Neoproterozoic juvenile crust. Zircon O isotope analyses yield δ¹⁸O values of − 3.26 to 2.79‰, indicating differential involvement of meteoric water in protolith magma by remelting of hydrothermally altered low δ¹⁸O rocks. North Dabie shares the same age of Neoproterozoic low δ¹⁸O protolith with Central Dabie experiencing the Triassic UHP metamorphism, but it was significantly reworked at Early Cretaceous in association with contemporaneous magma emplacement. The Rodinia breakup at about 750 Ma would lead to not only the reworking of juvenile crust in an active rift zone for bimodal protolith of Central Dabie, but also reworking of ancient crust in an arc-continent collision zone for the North Dabie protolith. The spatial difference in the metamorphic age (Triassic vs. Cretaceous) between the northern and southern parts of North Dabie suggests intra-crustal detachment during the continental subduction. Furthermore, the Dabie orogen would have a three-layer structure prior to the Early Cretaceous magmatism: Central Dabie in the upper, North Dabie in the middle, and the source region of Cretaceous magmas in the lower.     

Case history of controlling a landslide at Panluo open-pit mine in China

Controlling of landsides safely and economically is a great challenge to mine operators because landslides are major geological problems especially in open-pit mines. In this paper, a case history at Panluo open-pit mine is presented in detail to share the experiences and lessons with mine operators. Panluo open-pit mine is located in the southwestern Fujian province of China. It is the largest open-pit iron mine in the Fujian province and was planned in 1965 and is in full operation from 1978. In July 1990, an earthquake of magnitude 5.3 in Taiwan Strait and big rainstorms impacted the mine slope, causing tension cracks and rather large-scale failures, and forming a U-shaped landslide. Total potential volume was estimated to be up to 1.0 × 10⁶ m³. This directly threatened the mine production. In order to protect the mine production and the dwellers’ safety around, a dynamic comprehensive method was implemented including geotechnical investigations, in-situ testing and monitoring, stability analysis, and many mitigation and preventive measures. These measures slowed down the development and further occurrence of the landslide. The results showed that the landslides were still active, it was slowed with the control measures and moved rapidly with rainfall and mining down. However, no catastrophic accidents occurred and the pit mining was continued till it was closed at the elevation of 887 m in 2000. As a successful case of landslide control at an open-pit mine for 10 years, this paper reports the controlling measures in details. These experiences of landslide control may be beneficial to other similar mines for landslide control.     

Assessment of frozen-ground conditions for engineering geology along the Qinghai–Tibet highway and railway, China

The Qinghai–Tibet Highway and Railway (the Corridor) across the Qinghai–Tibet Plateau traverses 670 km of permafrost and seasonally frozen-ground in the interior of the Plateau, which is sensitive to climatic and anthropogenic environmental changes. The frozen-ground conditions for engineering geology along the Corridor is complicated by the variability in the near-surface lithology, and the mosaic presence of warm permafrost and talik in a periglacial environment. Differential settlement is the major frost-effect problem encountered over permafrost areas. The traditional classification of frozen ground based on the areal distribution of permafrost is too generalized for engineering purposes and a more refined classification is necessary for engineering design and construction. A proposed classification of 51 zones, sub-zones, and sections of frozen ground has been widely adopted for the design and construction of foundations in the portion of the Corridor studied. The mean annual ground temperature (MAGT), near-surface soil types and moisture content, and active faults and topography are most commonly the primary controlling factors in this classification. However, other factors, such as local microreliefs, drainage conditions, and snow and vegetation covers also exert important influences on the features of frozen ground. About 60% of the total length of the Corridor studied possesses reasonably good frozen-ground conditions, which do not need special mitigative measures for frost hazards. However, other sections, such as warm and ice-rich or -saturated permafrost, particularly in the sections in wetlands, ground improvement measures such as elevated land bridges and passive or proactive cooling techniques need to be applied to ensure the long-term stability of thermally unstable, thick permafrost subsoils, and/or refill with non-frost-susceptible soils. Due to the long-history of the construction and management of the Corridor by various government departments, adverse impacts of construction and operation on the permafrost environment have been resulted. It is recommended that an integrated, executable plan for the routing of major construction projects within this transportation corridor be established and long-term monitoring networks installed for evaluating and mitigating the impact from anthropogenic and climatic changes in frozen-ground conditions.     

Soil n-alkane δD vs. altitude gradients along Mount Gongga, China

The altitude effect on the isotopic composition of precipitation and its application to paleoelevation reconstruction using authigenic or pedogenic minerals have been intensively studied. However, there are still no studies on variations in biomarker δD along altitude transects to investigate its potential as a paleoelevation indicator, although it has been observed that δD of higher plant lipid may record changes in precipitation δD (δD_p). Here, we present δD values of higher plant-derived C₂₇, C₂₉, and C₃₁n-alkanes from surface soil along the eastern slope of Mount Gongga, China with great changes in physical variables and vegetation over a range from 1000 to 4000 m above sea level. The weighted-mean δD values of these n-alkanes (δD_wax) show significant linear correlations with predicted δD_p values (R² = 0.76) with an apparent isotopic enrichment (ε_wax-p) of −137 ± 9‰, indicating that soil δD_wax values track overall δD_p variation along the entire altitudinal transect. Leaf δD_wax is also highly correlated with mountain altitude by a significant quadratic relationship (R² = 0.80). Evapotranspiration is found declining with altitude, potentially lowering δD_wax values at higher elevations. However, this evapotranspiration effect is believed to be largely compensated by the opposing effect of vegetation changes, resulting in less varied ε_wax-p values over the slope transect. This study therefore confirms the potential of using leaf δD_wax to infer paleoelevations, and more generally, to infer the δD of precipitation.     

Church-based social capital, networks and geographical scale: Katrina evacuation, relocation, and recovery in a New Orleans Vietnamese American community

This research examines the role of social capital and networks to explain the evacuation, relocation, and recovery experiences of a Vietnamese American community in New Orleans, Louisiana in the aftermath of Hurricane Katrina. As the single largest community institution, the parish church’s complex bonding and bridging social capital and networks proved particularly critical in part because of its historically based ontological security. The process of evacuation, but especially relocation and recovery, was dependent on deploying co-ethnic social capital and networks at a variety of geographical scales. Beyond the local or community scale, extra-local, regional, and national scales of social capital and networks reproduced a spatially redefined Vietnamese American community. Part of the recovery process included constructing discursive place-based collective-action frames to successfully contest a nearby landfill that in turn engendered social capital and networks crossing ethnic boundaries to include the extra-local African American community. Engaging social capital and networks beyond the local geographical scale cultivated a Vietnamese American community with an emergent post-Katrina cultural and political identity.     

含硫化物脉状矿床成矿流体的中阶段 δD亏损：实例与原因

很多含硫化物脉状金银矿床的成矿过程可以大致分为3个阶段,从早到晚分别以形成黄铁矿-石英组合、多金属硫化物和碳酸盐网脉为标志.所谓中阶段δD亏损,是指在成矿流体δ18O逐渐降低(或升高)时,中阶段δD同时低于早阶段和晚阶段的δD.列举了一些矿床的氢氧同位素研究结果,例证了这种现象的存在;根据中阶段伴随大量硫化物沉淀的事实,认为硫化物沉淀时流体中H2S或HS-的H 被金属离子置换出来,H 加入到流体系统后导致了流体的中阶段δD亏损.对不同温度H2O-H2S体系1000In ot值的概算显示,在200-650℃温度范围,H2S或HS-的δD低于H2O的δD约211‰～478%‰,H2S或HS-中H 的少量释放即可导致流体水δD的显著降低.因此建议,成矿流体从早到晚δ18O逐渐降低,中阶段δD亏损的规律,可以作为含硫化物脉状矿床氢氧同位素演化的概念性模型.