某电厂氯化物在地下水中迁移规律研究

为了研究污染物在地下水中的迁移规律,本文以某电厂地下水中氯化物作为预测因子进行数值模拟。对研究区含水层物质组成、边界条件、初始条件及源汇项等做简化,采用GMS软件建立水文地质模型,在简化的水文地质模型的基础上开展地下水中污染物迁移规律研究。研究结果表明：在污染物排放规律简化为连续恒定排放的点源工况下,（1）污染物平面迁移范围以泄漏点为中心呈椭圆形扩散,污染晕长轴为地下水流动方向;（2）污染物最大迁移距离及污染影响范围均随时间不断增加,但是变化速率不断降低;（3）距离污染源较近的位置,污染物浓度随时间不断增加,但是浓度变化速率逐渐降低;距离污染源较远的位置,污染物浓度随时间不断增加,初期浓度变化速率随时间不断增加,后期浓度变化速率随时间逐渐降低。     

中国碳减排目标的地区分解方法研究述评

碳减排目标的区域分配是中国当前控制CO2排放的紧迫问题。通过文献研究,评述了国际上针对国家之间的碳排放权的区域分解方案以及中国碳减排目标的国内区域分解方案,提出了要想真正公平、公正、可行以及可持续地进行碳减排目标的地区分解,必须明确以下几个方面的关键和核心问题:分配对象、分配原则、分配方案必须考虑的因素、分配标准、分配方法、分配模型以及分配结果的可靠性和合理性。     

海南省城乡关系演化及驱动机制研究

推进城乡一体化协调发展是事关海南自由贸易港建设成效的重点任务之一,新的发展环境及政策框架正促使海南省城乡关系快速转型。采用变异系数法、耦合协调度模型、回归模型,从城乡空间、经济和社会等维度,分析了建省办特区以来海南省城乡关系演化特征及驱动机制。结果表明：①建省办特区以来,海南省城乡协调综合指数呈现明显的先降后升态势,由1988年的0.319 9到1993年的0.153 9,2019年达0.851 9;②海南省城乡各子系统耦合度和耦合协调度均呈波动上升态势,耦合度主要处于磨合和高水平耦合阶段,耦合协调度由轻度失调转变为初级协调,最后达到中级协调,城乡各子系统间相互作用增强;③海南省城乡关系演化经历城乡二元加剧、城乡二元固化、城乡关系趋缓和城乡一体化初期四个阶段,低水平城乡均衡发展是重要特征,高质量推进城乡一体化协调发展是关键;④经济发展对城乡协调发展影响最为明显,但呈负相关,其次为市场消费、产业结构、乡村发展、交通通达性、城镇发展和政府行为,对外开放对城乡关系演化影响相对较弱;⑤制度创新、对外合作、产业优化、城镇建设和乡村振兴是推进城乡融合发展的重要路径。     

The complex nonlinear systems with fractal as well as chaotic dynamics of annual runoff processes in the three headwaters of the Tarim River

This paper attempted to identify fractal and chaotic characteristics of the annual runoff processes in headwaters of the Tarim River. Methods of fractal analyses were used to explore several aspects of the temporal changes from 1957 to 2002. The main findings are as follows: (1) The annual runoff processes of the three headwaters of the Tarim River are complex nonlinear systems with fractal as well as chaotic dynamics. (2) The correlation dimensions of attractor derived from the time series of the annual runoff for the Hotan, Yarkand and Aksu rivers are all greater than 3.0 and non-integral, implying that all three rivers are chaotic dynamical systems that are sensitive to initial conditions, and the dynamic modeling of their annual runoff process requires at least four independent variables. (3) The time series of annual runoff in each river presents a long-term correlation characteristic. The Hurst exponent for the period of 1989 to 2002 suggests that we may expect to see an increasing trend in the annual runoff of the Aksu and Yarkand rivers in the years after 2002, but a decreasing tendency for the Hotan River in the same period.     

无线射频识别双向认证协议及性能分析

针对姚华桢等人提出的射频识别认证协议易遭受读写器ID揭露,中间人攻击和假冒攻击等安全脆弱性,提出一种基于NTRU公钥密码算法的改进双向认证协议,并用GNY逻辑进行了形式化分析.协议不仅具有一次一密的特点,而且在实现双向认证的同时也完成了会话密钥的交换,并将主要的计算放在读写器上,有效降低了服务器的压力;解决了当前协议中存在的位置跟踪,前向安全性等隐私泄漏问题.分析结果表明,该协议不仅能够可抵抗重传,假冒,拒绝服务等多种恶意攻击,而且具有计算复杂度低,通信量小,效率高等特点,适合在低成本标签实现.     

Effect of copper on the growth of shrimps Litopenaeus vannamei: water parameters and copper budget in a recirculating system

Shrimps( Litopenaeus vannamei) were intensively cultured in a recirculating aquaculture system for 98 days to investigate effects of 0.3 mg/L Cu on its performance, Cu budget, and Cu distribution. Shrimps in Cu-treated systems had greater mean final weight(11.10 vs 10.50 g), body length(107.23 vs 106.42 mm), survival rate(67.80% vs 66.40%), and yield(6.42 vs 5.99 kg/m 3), and lower feed conversion ratio(1.20 vs 1.29) than those in control systems but the differences were not significant. Vibrio numbers remained stable(10 4 –10 6 colony forming units/mL) in the rearing tanks of both control and treated systems. Total ammonium-N, nitrite-N, nitrate-N, pH, chemical oxygen demand, 5-day carbonaceous biochemical oxygen demand, and total suspended solids were similar in controls and treatments. Dissolved Cu concentration in the treated systems decreased from 0.284 to 0.089 mg/L while in the control systems it increased from 0.006 2 to 0.018 mg/L. The main sources of Cu in the treated systems were the artificially added component(75.7% of total input), shrimp feed(21.0%), water(2.06%), and shrimp biomass(1.22%). The major outputs of Cu occurred via the mechanical filter(41.7%), water renewal(15.6%), and draining of the sediment trap(15.1%). The foam fractionator removed only 0.69% of total Cu input. Harvested shrimp biomass accounted for 11.68% of Cu input. The Cu concentration of shrimps in the Cu-treated systems(30.70 mg/kg wet weight) was significantly higher than that in control systems(22.02 mg/kg). Both were below the maximum permissible concentration(50 mg/kg) for Cu in seafood for human consumption in China. Therefore, recirculating systems can be used for commercial on-growing of Litopenaeus vannamei without loss of shrimp quality, even in water polluted by 0.30 mg/L Cu. The mechanical filter is the main route for Cu removal.     

Researches on the Internal Molecular Weight Uniformity of Chitosan Biomaterials

Uniform molecular weight(Mw)chitosan(CS)is highly demanded in medical biomaterial industry.This present article described heterogeneous degradation of CS in aqueous HCl/ethanol solution,in which progress uniform Mw CS was successfully prepared.The Mw distribution of CS was measured by gel permeation chromatography(GPC)analysis.Moreover,the structure and properties of degraded CS were characterized by Fourier transform infrared spectroscopy(FT-IR),nuclear magnetic resonance spectroscopy(^1H NMR),X-ray diffraction(XRD)and thermogravimetric(TG)analysis.In addition,the biocompatibility of degraded CS was also assessed by hemolysis rate(HR)measurement.The Mw of CS dramatically decreased from 246 KDa to 76 k Da at the initial 30 min,and stabilized at 18 kDa after 24 h.GPC analysis results showed that the degraded CS molecular become homogenization.FT-IR and 1 H NMR analysis confirmed the basic structure of CS molecular backbone was not destroyed during this progress.Besides,the water solubility of CS was not significantly influenced by this reaction.Moreover,the XRD analysis revealed that crystallinity of degraded CS increased from 70.32% to 99.25%with time.The TG analysis showed improved thermal stability of degraded CS.HR measurement demonstrated the degraded CS possessed excellent biocompatibility.This simple and efficient heterogeneous degradation would open up a new route to produce uniform Mw CS.     

黄河流域县域交通供给格局及其空间适配性

分析黄河流域交通供给水平特征及其与经济社会发展的空间适配性,对交通资源优化配置、提升交通供需适配性具有重要参考。论文基于黄河流域现状综合交通运输与经济社会基础数据,分析了黄河流域县域交通优势度分异特征,并探讨了交通与县域发展质量的空间适配性。结果表明：黄河流域县域交通优势度有待提升,在人口与GDP方面呈现一定错配特征;高优势度县域集中分布在济南—郑州—西安—兰州通道沿线。黄河流域交通供给均衡性水平高于经济社会差异;样带交通优势度呈现陇海—兰新“一”字型样带>“几”字湾样带>南北纵向“1”字型样带的分布态势,固定资产投资、产业结构、城镇化、经济基础是影响黄河流域县域交通优势度的主要因素。“几”字湾样带和南北纵向“1”字型样带还受到高程、坡度等自然因素的制约;流域40.05%的县域处于初级适配状态,38.78%的县域为交通劣势型,集中在青藏高原、黄土高原沟壑区和内蒙古中西部地区,亟需提升交通设施对该类县域经济社会发展的支撑与保障能力。     

成都“2008.9.24”暴雨的中尺度数值模拟

为了更好的研究四川成都地区2008年9月23日～25日强降水天气的物理机制,利用中尺度天气预报模式(Weather Research Forecast,WRF)模拟了此次过程,并结合FY-2号C星云图资料,对过程的发生、发展过程进行分析后发现,此次暴雨过程为低层弱低压辐合,同时台风"黑格比"登陆后带来大量水汽,并借助西伸的西太平洋副高源源不断的向四川盆地输送,另外存在来自南方孟加拉湾水汽的持续供应,对流云团形成于地面低压与西伸副高的交界处,并沿着副高边缘由西南向东北移动,雨带分布在副高边缘气压梯度大的地方,模拟结果与观测事实基本相符。利用WRF模式模拟暴雨产生的环流形势,配合卫星云图,能进一步揭示暴雨产生的物理机制,可作为深化暴雨研究的有效手段。     

基于GWR模型的中国城市雾霾污染影响因素的空间异质性研究

基于全国城市的PM_2.5监测数据,识别PM_2.5的时空分布特征,并着重利用地理加权回归模型分析自然和社会经济因素对PM_2.5影响的空间异质性。结果显示：2015年全国PM_2.5的年均浓度为50.3 μg/m3,浓度变化呈现冬高夏低,春秋居中的“U型”特征;PM_2.5的空间集聚状态明显,其中京津冀城市群是全国PM_2.5的污染重心。地理加权回归结果显示：影响因素除高程外,其余指标均呈现正负两种效应,且影响程度具有显著的空间差异性特征。从回归系数的贡献均值来看,自然因素对城市PM_2.5浓度影响强度由高到低依次是高程、相对湿度、温度、降雨量、风速、植被覆盖指数;各类社会经济指标对城市PM_2.5浓度影响强度排名依次是人口密度、研发经费、建设用地比例、产业结构、外商直接投资、人均GDP。由于各指标对城市PM_2.5浓度变化的影响程度存在着空间异质性,因此在制定大气治理对策时可以考虑不同指标影响程度的空间差异,从而使得治霾对策更具针对性。