Oxygen and Hydrogen Isotopic Signatures of Large Atmospheric Ice Conglomerations

Specific studies about the stable isotope composition (¹⁸O/¹⁶O and D/H) of atmospheric icy conglomerations are still scarce. The present work offers, for the first time, a very detailed analysis of oxygen and hydrogen isotopic signatures of unusually large ice conglomerations, or “megacryometeors”, that fell to the ground in Spain during January 2000. The hydrochemical analysis is based on the bulk isotopic composition and systematic selective sampling (deuterium isotopic mapping) of eleven selected specimens. δ¹⁸O and δD (V-SMOW) of all samples fall into the Meteoric Water Line matching well with typical tropospheric values. The distribution of the samples on Craig's line suggests either a variation in condensation temperature and/or different residual fractions of water vapour (Rayleigh processes). Three of the largest megacryometeors exhibited unequivocally distinctive negative values (δ¹⁸O = −17.2%₀ and δD = −127 %₀ V-SMOW), (δ¹⁸O = −15.6%₀ and δD = −112%₀ V-SMOW) and (δ¹⁸O = −14.4%₀ and δD = −100%₀ V-SMOW), suggesting an atmospheric origin typical of the upper troposphere. Theoretical calculations indicate that the vertical trajectory of growth was lower than 3.2 km. During the period in which the fall of megacryometeors occurred, anomalous atmospheric conditions were observed to exist: a substantial lowering of the tropopause with a deep layer of saturated air below, ozone depression and strong wind shear. Moreover, these large ice conglomerations occurred during non-thunderstorm conditions, suggesting an alternative process of ice growth was responsible for their formation.     

Internal anatomy of a mixed siliciclastic–carbonate platform: the Late Cenomanian–Mid Turonian at the southern margin of the Spanish Central System

The Late Cenomanian–Mid Turonian succession in central Spain is composed of siliciclastic and carbonate rocks deposited in a variety of coastal and marine shelf environments (alluvial plain–estuarine, lagoon, shoreface, offshore‐hemipelagic and carbonate ramp). Three depositional sequences (third order) are recognized: the Atienza, Patones and El Molar sequences. The Patones sequence contains five fourth‐order parasequence sets, while a single parasequence set is recognized in the Atienza and El Molar sequences. Systems tracts can be recognized both in the sequences and parasequence sets. The lowstand systems tracts (only recognized for Atienza and Patones sequences) are related to erosion and sequence boundary formation. Transgressive systems tracts are related to marine transgression and shoreface retreat. The highstand systems tracts are related to shoreface extension and progradation, and to carbonate production and ramp progradation. Sequences are bounded by erosion or emergence surfaces, whose locations are supported by mineralogical analyses and suggest source area reactivation probably due to a fall in relative sea‐level. Transgressive surfaces are subordinate erosion and/or omission surfaces with a landward facies shift, interpreted as parasequence set boundaries. The co‐existence of siliciclastic and carbonate sediments and environments occurred as facies mixing or as distinct facies belts along the basin. Mixed facies of coastal areas are composed of detrital quartz and clays derived from the hinterland, and dolomite probably derived from bioclastic material. Siliciclastic flux to coastal areas is highly variable, the maximum flux postdates relative sea‐level falls. Carbonate production in these areas may be constant, but the final content is a function of changing inputs in terrigenous sediments and carbonate content diminishes through a dilution effect. Carbonate ramps were detached from the coastal system and separated by a fringe of offshore, fine‐grained muds and silts as distinct facies belts. The growth of carbonate ramp deposits was related to the highstand systems tracts of the fourth‐order parasequence sets. During the growth of these ramps, some sediment starvation occurred basinwards. Progradation and retrogradation of the different belts occur simultaneously, suggesting a sea‐level control on sedimentation. In the study area, the co‐existence of carbonate and siliciclastic facies belts depended on the superimposition of different orders of relative sea‐level cycles, and occurred mainly when the second‐order, third‐order and fourth‐order cycles showed highstand conditions.     

New Views on the Early Evolution of Oxygen in the Galaxy

We discuss results on the oxygen abundance in a sample of 23 metal-poor (?3.0≤ [Fe/H] ≤ ?0.3) unevolved stars and one giant. High resolutionspectroscopy of OH lines in the near UV allowed us to trace the early evolution of oxygenversus metallicity. Contrary to previous expectations, we find that oxygen abundances derived from these low excitation lines agree well withthose derived from the high excitation lines of the OI IR triplet and from the [OI] λ 6300 Å line. Our new oxygen abundances show a smooth extension of previouslyknown trends of [O/Fe] versus [Fe/H] in disk stars to much lower metallicities, with a slope of ?0.31± 0.11. The [O/Fe] ratio increasesfrom 0.6 to 1 between [Fe/H] =?1.5 and ?3.0. Comparison with oxygen abundances in giant stars of the same metallicity imply that the lattermay have suffered a process of oxygen depletion. We briefly discussthe impact of these results on the yields of Type II SNe in the early Galaxy and on the age of globular clusters.     

Puerto Lápice eucrite fall: Strewn field,physical description,probable fireball trajectory,and orbit

Abstract— The fall of the Puerto Lápice eucrite occurred on May 10, 2007, at 17 h 57 m 30 ± 30 s UTC. Its daylight fireball was witnessed by hundreds of people from Spain, and produced a meteorite fall associated with a large strewn field of fragments. There were no direct pictures of the fireball, but several pictures of the fireball's train were taken from different locations in Spain. Additional theodolite calibrations of visual records were made in order to find the most probable fireball trajectory based on the available data. The shape of the meteorite strewn field was considered as well. Although the orbit of the Puerto Lápice meteoroid could not be computed due to the absence of velocity data, we assumed a likely range of geocentric velocities and computed a range of possible orbits. All solutions show that the body was in an Apollo‐type orbit, with low inclination and perihelion distance just below 1 astronomical unit (AU). This is the first case that an orbit can be discussed for an HED meteorite fall.     

Downslope‐migrating sandwaves and platform‐margin clinoforms in a current‐dominated,distally steepened temperate‐carbonate ramp (Guadix Basin,Southern Spain)

During the Late Tortonian, platform‐margin‐prograding clinoforms developed at the south‐western margin of the Guadix Basin. Large‐scale wedge‐shaped deposits here comprise 26 rhythms of mixed carbonate–siliciclastic bedset packages and marl beds. These sediments were deposited on a shallow‐water, temperate‐carbonate distally steepened ramp. A downslope‐migrating sandwave field developed in this ramp, with sandwaves moving progressively down the ramp to the ramp‐slope, where they destabilized, folded and occasionally collapsed. Downslope sandwave migration was induced by currents flowing basinwards. During the Late Tortonian, the Guadix Basin was open north to the Atlantic Ocean via the Dehesas de Guadix Strait and connected east to the Mediterranean Sea through the Almanzora Corridor. According to the proposed current circulation model for the Guadix Basin for this time, surface marine currents from the Atlantic entered the basin from the northern seaway. These currents moved counter‐clockwise and shifted the sediment on the ramp, forming sandwaves that migrated downslope. The development of platform‐margin prograding clinoforms by the basinward sediment‐transport mechanisms inferred here is known relatively poorly in the ancient sedimentary record. Moreover, these wedge‐shaped geometries are similar to those found in some shelves in the Western Mediterranean Sea and could represent an outcrop analogue to (sub)‐recent, platform‐margin clinoforms revealed by high‐resolution seismic studies.     

The action of wind and water in a mid‐Cretaceous subtropical erg‐margin system close to the Variscan Iberian Massif,Spain

Aeolian processes and ephemeral water influx from the Variscan Iberian Massif to the mid‐Cretaceous outer back‐erg margin system in eastern Iberia led to deposition and erosion of aeolian dunes and the formation of desert pavements. Remains of aeolian dunes encased in ephemeral fluvial deposits (aeolian pods) demonstrate intense erosion of windblown deposits by sudden water fluxes. The alternating activity of wind and water led to a variety of facies associations such as deflation lags, desert pavements, aeolian dunes, pebbles scattered throughout dune strata, aeolian sandsheets, aeolian deposits with bimodal grain‐size distributions, mud playa, ephemeral floodplain, pebble‐sand and cobble‐sand bedload stream, pebble–cobble‐sand sheet flood, sand bedload stream, debris flow and hyperconcentrated flow deposits. Sediment in this desert system underwent transport by wind and water and reworking in a variety of sub‐environments. The nearby Variscan Iberian Massif supplied quartzite pebbles as part of mass flows. Pebbles and cobbles were concentrated in deflation lags, eroded and polished by wind‐driven sands (facets and ventifacts) and incorporated by rolling into the toesets of aeolian dunes. The back‐erg depositional system comprises an outer back‐erg close to the Variscan highlands, and an inner back‐erg close to the central‐erg area. The inner back‐erg developed on a structural high and is characterized by mud playa deposits interbedded with aeolian and ephemeral channel deposits. In the inner back‐erg area ephemeral wadis, desiccated after occasional floods, were mud cracked and overrun episodically by aeolian dunes. Subsequent floods eroded the aeolian dunes and mud‐cracked surfaces, resulting in largely structureless sandstones with boulder‐size mudstone intraclasts. Floods spread over the margins of ephemeral channels and eroded surrounding aeolian dunes. The remaining dunes were colonized occasionally by plants and their roots penetrated into the flooded aeolian sands. Upon desiccation, deflation resulted in lags of coarser‐grained sediments. A renewed windblown supply led to aeolian sandsheet accumulation in topographic wadi depressions. Synsedimentary tectonics caused the outer back‐erg system to experience enhanced generation of accommodation space allowing the accumulation of aeolian dune sands. Ephemeral water flow to the outer back‐erg area supplied pebbles, eroded aeolian dunes, and produced hyperconcentrated flow deposits. Fluidization and liquefaction generated gravel pockets and recumbent folds. Dune damming after sporadic rains (the case of the Namib Desert), monsoonal water discharge (Thar Desert) and meltwater fluxes from glaciated mountains (Taklamakan Desert) are three potential, non‐exclusive analogues for the ephemeral water influx and the generation of hyperconcentrated flows in the Cretaceous desert margin system. An increase in relief driven by the Aptian anti‐clockwise rotation of Iberia, led to an altitude sufficient for the development of orographic rains and snowfall which fed (melt)water fluxes to the desert margin system. Quartzite conglomerates and sands, dominantly consisting of quartz and well‐preserved feldspar grains which are also observed in older Cretaceous strata, indicate an arid climate and the mechanical weathering of Precambrian and Palaeozoic metamorphic sediments and felsic igneous rocks. Unroofing of much of the cover of sedimentary rocks in the Variscan Iberian Massif must therefore have taken place in pre‐Cretaceous times.     

Lateritized tephric palaeosols from Central Patagonia,Argentina: a southern high‐latitude archive of Palaeogene global greenhouse conditions

Palaeosols of the Koluel‐Kaike Formation, a red colour‐banded, pyroclastic succession from southern Argentina, constitute a proxy for Eocene climate changes. Reticulated and vertically elongated ferric mottles, along with iron and manganese nodules are the most significant climate indicators, which originated by alternating cycles of waterlogging and drying conditions causing Fe‐Mn mobilization and fixation. Clay minerals vary from a kaolinite > smectite suite in the lower and middle sections, to a smectite > kaolinite one in the upper part. High concentrations of iron oxides/hydroxides and kaolinite, lack of exchangeable bases, absence of carbonate cement, presence of ironstone and redness of hue in most of the palaeosols suggest intense chemical weathering related to leaching and lateritization processes. Five pedotypes, ordered in a stratigraphic sense, were identified. Strongly developed, red to orange Chornk (Fragiaquult) and Kápenk (Plinthaquult) pedotypes display argillic horizons, abundant ferric nodules and slickensides; they are dominant in the lower and middle sections, and formed in seasonal humid and megathermic (tropical) conditions with a mean annual precipitation of 1200 to 1300 mm and a mean annual temperature of 15 °C. Weakly developed, less structured Ornek (Vitrand) and Pólnek (Placaquand) pedotypes occur in the middle and upper sections, and originated in sub‐humid and mesic‐megathermic conditions with a mean annual precipitation around 1000 mm and a mean annual temperature around 12 °C. The brownish Soorsh (Argialboll) pedotype exhibits a granular structure and is present at the uppermost part of the unit. It developed in sub‐humid/semi‐arid and mesic conditions, with a mean annual precipitation of 600 to 700 mm and a mean annual temperature around 10 °C. This pedotype succession and clay mineral distribution indicates a decrease in chemical weathering and degree of soil development with time. Koluel‐Kaike palaeosols from Central Patagonia are some of the first continental non‐palaeobiological data linked to the Early Palaeogene global warming in South America; they show an especially close relationship with the Early Eocene Climatic Optimum and the following long‐term cooling and drying initiated by Middle to Late Eocene time.     

Late Pleistocene biota from Pubenza,Colombia; turtles,mammals, birds,invertebrates and plant remains

Pubenza is a remarkable palaeontological site of Colombia, and a place that could hold some of the potentially oldest evidence of humans in northern South America. Previous palaeontological research at this site has mainly focused on the megafauna. Here we describe and establish the systematic palaeontology for the small fauna that inhabited this ancient lacustrine ecosystem, including the first report of birds, tortoises and vipers for the Late Pleistocene in Colombia. Furthermore, exceptionally well preserved fossilised wasp nests are morphologically and elementally characterised, which is the first report of an ichnofossil of this kind in northern South America. In addition, new material of kinosternid turtles, armadillos and rodents is also described. Our results reveal that the Bogotá River Basin, where Pubenza is located, was a rich ecosystem during the Late Pleistocene and a region of great interest for future articulated palaeontological and archaeological studies.