NEW 10BE COSMOGENIC AGES FROM THE VIMMERBY MORAINE CONFIRM THE TIMING OF SCANDINAVIAN ICE SHEET DEGLACIATION IN SOUTHERN SWEDEN

The overall pattern of deglaciation of the southern part of the Scandinavian Ice Sheet has been considered established, although details of the chronology and ice sheet dynamics are less well known. Even less is known for the south Swedish Upland because the area was deglaciated mostly by stagnation. Within this area lies the conspicuous Vimmerby moraine, for which we have used the terrestrial cosmogenic nuclide (¹⁰Be) exposure dating technique to derive the exposure age of six glacially transported boulders. The six ¹⁰Be cosmogenic ages are internally consistent, ranging from 14.9 ± 1.5 to 12.4 ± 1.3 ka with a mean of 13.6 ±0.9 ka. Adjusting for the effects of surface erosion, snow burial and glacio-isostatic rebound causes the mean age to increase only by c. 6% to c. 14.4± 0.9 ka. The ¹⁰Be derived age for the Vimmerby moraine is in agreement with previous estimates forthe timing of deglaciation based on radiocarbon dating and varve chronology. This result shows promise for further terrestrial cosmogenic nuclide exposure studies in southern Sweden.     

<Emphasis Type="Italic">Phragmites australis</Emphasis> (Common Reed) Invasion in the Rhode River Subestuary of the Chesapeake Bay: Disentangling the Effects of Foliar Nutrients,Genetic Diversity,Patch Size,and Seed Viability

The invasion and expansion of the introduced haplotype of Phragmites australis across North America is of growing concern. Previous studies in the Chesapeake Bay region found that Phragmites was more abundant, had higher foliar nitrogen, and produced more viable seeds in brackish wetland subestuaries with more anthropogenic development of the watershed. Here, we focus on a different scale and address issues related to the invasion of Phragmites within a single subestuary, the Rhode River. We evaluated patterns in seed viability, foliar nutrient concentrations, patch size, and genetic variation in ten Phragmites patches in wetlands that occur in the side of the subestuary that is surrounded by forest and 10 patches in wetlands that are in the side of the subestuary that has extensive anthropogenic development. Seed viability varied from 0–60% among the 20 patches but did not differ significantly between patches on the developed vs. forested sides of the Rhode River. Foliar nutrients also did not differ between patches on the two sides of the Rhode River. Seed viability, however, was negatively related to foliar nutrients. Most Phragmites patches consisted of >1 genotype. Larger patches had multiple genotypes, and patches with more genotypes produced more viable seeds. Our study indicates that the Rhode River subestuary behaves as one system with no differences in the measured Phragmites variables between the forested vs. developed sides of the watershed. Our findings also suggest a cyclical process by which Phragmites can spread: larger patches contain more genetic diversity, which increases the chances for cross-fertilization. The subsequent increased production of viable seeds can increase local levels of genetic diversity, which can further facilitate the spread of Phragmites by seed.     

Evaluating Groundwater Interbasin Flow Using Multiple Models and Multiple Types of Data

The groundwater interbasin flow, Q_y, from the north of Yucca Flat into Yucca Flat simulated using the Death Valley Regional Flow System (DVRFS) model greatly exceeds assessments obtained using other approaches. This study aimed to understand the reasons for the overestimation and to examine whether the Q_y estimate can be reduced. The two problems were tackled from the angle of model uncertainty by considering six models revised from the DVRFS model with different recharge components and hydrogeological frameworks. The two problems were also tackled from the angle of parametric uncertainty for each model by first conducting Morris sensitivity analysis to identify important parameters and then conducting Monte Carlo simulations for the important parameters. The uncertainty analysis is general and suitable for tackling similar problems; the Morris sensitivity analysis has been utilized to date in only a limited number of regional groundwater modeling. The simulated Q_y values were evaluated by using three kinds of calibration data (i.e., hydraulic head observations, discharge estimates, and constant‐head boundary flow estimates). The evaluation results indicate that, within the current DVRFS modeling framework, the Q_y estimate can only be reduced to about half of the original estimate without severely deteriorating the goodness‐of‐fit to the calibration data. The evaluation results also indicate that it is necessary to develop a new hydrogeological framework to produce new flow patterns in the DVRFS model. The issues of hydrogeology and boundary flow are being addressed in a new version of the DVRFS model planned for release by the U.S. Geological Survey.     

天然气水合物开发安全检测技术应用研究

中国近年来先后在南海北部和祁连山南缘青海省天峻县永久冻土带中发现天然气水合物,这是一种新能源,它将对中国能源结构的调整和能源紧张的缓解起到非常重要的作用。但是,天然气水合物开采安全是个大问题,已经引起了国际上专家们的极大关注。俄罗斯南方国立技术大学地球物理、探矿工程和石油钻采教研室开发出来的天然气水合物开发安全检测技术和方法,可以准确确定出射孔部位的位置、检查射孔部位是否阻塞和如何解阻等关键技术,对天然气水合物开采安全提供了技术支撑,对此应该进行研究。     

Coexisting alkali feldspars in felsic members of the Cauro-Bastelica ring complex,Corsica

The granodioritic and gneissic Hercynian basement in Corsica was intruded, in the Triassic, by non-orogenic ring complexes in which the association early rhyolite-hypersolvus granite-granophyre-late subsolvus granite is clearly developed. The association of low albite and maximum microcline in mesoperthites cannot be attributed to Alpine low-grade metamorphism, restricted to fault zones. On a number of lines of evidence, the development of ordered, almost pure K-feldspar in this rapidly cooled complex appears related to an episode of mild reheating attending emplacement of late subsolvus granites, rocks formed from melts enriched, perhaps even saturated in aqueous fluids.     

Ambient pressure thermal desorption spectroscopy (AP-TDS) of NiO/SiO2 catalysts

The Sabatier reaction is a key process in the “power-to-gas” application which is considered to contribute to future chemical energy storage systems. In this contribution we focus on the catalytic active sites of a NiO catalyst supported on SiO₂ (NiO/SiO₂) which is commonly used in the Sabatier reaction. A novel technique for the characterization of the active sites is presented and discussed using thermal desorption spectroscopy at ambient pressure. This analytical tool is operated under reaction conditions and allows element specific measurements during the catalytic process of CO₂ reforming towards methane. Beside the desorption experiments, XPS and XAS measurements of pristine and catalytically used samples are performed to determine the influence of the Sabatier reaction conditions on the surface structure of the catalyst.     

Environmental isotopic and hydrochemical study of groundwater in the Ejina Basin,northwest China

The study investigates the groundwater evolution and its residence time in the Ejina Basin, northwest China according to isotope and hydrochemical analyses results. The groundwater chemistry is mainly controlled by the dissolution of halite, Glauber’s salt, gypsum, dolomite and calcite, also influenced by other processes such as evaporation, ion exchange, and deposition. Based on tritium content in atmospheric precipitation and by adopting a model with exponential time distribution function, the mean residence time of the unconfined aquifer groundwater with fairly high tritium activities (21–49 TU) is evaluated. The results show that these groundwaters have low residence time (5–120 years) and are renewable. In contrast, the deep confined groundwaters are tritium-free and radiocarbon values range from 18.3 to 26.7 pmc. According to the most commonly used ¹⁴C correction models, the radiocarbon groundwater ages were calculated which yield ages of approximately 4,087–9,364 years BP. Isotopic signatures indicate formation of deep confined groundwaters in a colder and wetter climate during the late Pleistocene and Holocene. It is suggested that long-term, rational water usage guide should be set up for the Heihe River Basin as a whole to permit a considerable discharge to the Ejina Basin.     

An assessment of an oil spill in Gladstone, Australia - impacts on intertidal areas at one month post-spill

In January 2006, 25 tonnes of heavy fuel oil spilled into the Port of Gladstone in Queensland, Australia, from the breached hull of a bulk carrier ship. Over the following days, approximately 18 tonnes of the oil was recovered, however a certain amount of oil was deposited in the intertidal areas of Port Curtis leaving a highly visible, viscous residue. The objectives of this research were to assess the immediate impacts on the intertidal habitat and to gain baseline information for future comparative assessments. Sediment PAH and metal concentrations, mangrove communities and intertidal macroinvertebrates were assessed within one month post-spill at oil-impacted sites; adjacent sites which were not visibly impacted; and reference sites which were located outside the recorded distribution of the oil spill. Highest PAH concentrations were found at the impacted sites, with concentrations of some PAHs exceeding Australian and New Zealand Sediment Quality Guidelines (ANZECC/ARMCANZ, 2000). These sites contained very few or no crab holes in the high intertidal area, indicating a low crab density in comparison to reference sites. Little immediate impact was evident on the mangrove and macrobenthic communities, however future surveys may show evidence of longer-term impacts on these communities.     

Detection and temporal coherence of p‐modes below 1.4 mHz

Data collected recently by the helioseismic experiments aboard the SOHO spacecraft have allowed the detection of low degree p‐modes with increasingly lower order n. In particular, the GOLF experiment is currently able to unambiguously identify low degree modes with frequencies as low as 1.3 mHz. The detection of p‐modes with very low frequency (i.e., low n), is difficult due to the low signal‐to‐noise ratio in this spectral region and its contamination by solar signals that are not of acoustic origin. To address this problem without using any theoretical a priory, we propose a methodology that relies only on the inversion of observed values to define a spectral window for the expected locations of these low frequency modes. The application of this method to 2920‐day‐long GOLF observations is presented and its results discussed. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)