Contrasting stable isotope behavior between calcite and dolomite marbles,Lone Mountain,Nevada

 Late Proterozoic to Cambrian carbonate rocks from Lone Mountain, west central Nevada, record multiple post-depositional events including: (1) diagenesis, (2) Mesozoic regional metamorphism, (3) Late Cretaceous contact metamorphism, related to the emplacement of the Lone Mountain granitic pluton and (4) Tertiary hydrothermal alteration associated with extension, uplift and intrusion of silicic porphyry and lamprophyre dikes. Essentially pure calcite and dolomite marbles have stable isotopic compositions that can be divided into two groups, one with positive δ¹³C values from+3.1 to +1.4 ‰ (PDB) and high δ¹⁸O values from +21.5 to +15.8 ‰ (SMOW), and the other with negative δ¹³C values from –3.3 to –3.6‰ and low δ¹⁸O values from +16.9 to +11.1‰. Marbles also contain minor amounts of quartz, muscovite and phlogopite. Brown and blue luminescent, clear, smooth textured quartz grains from orange luminescent calcite marbles have high δ¹⁸O values from +23.9 to +18.1‰, while brown luminescent, opaque, rough textured quartz grains from red luminescent dolomite marbles typically have low δ¹⁸O values from +2.0 to +9.3‰. The δ¹⁸O values of muscovite and phlogopite from marbles are typical of micas in metamorphic rocks, with values between +10.4 and +14.4‰, whereas mica δD values are very depleted, varying from −102 to −156‰. No significant lowering of the δ¹⁸O values of Lone Mountain carbonates is inferred to have occurred during metamorphism as a result of devolatilization reactions because of the essentially pure nature of the marbles. Bright luminescence along the edges of fractures, quartz cements and quartz overgrowths in dolomite marbles, low δD values of micas, negative δ¹³C values and low δ¹⁸O values of calcite and dolomite, and depleted δ¹⁸O values of quartz from dolomite marbles all indicate that meteoric fluids interacted with Lone Mountain marbles during the Tertiary. Partial oxygen isotopic exchange between calcite and low ¹⁸O meteoric fluids lowered the δ¹⁸O values of calcite, resulting in uniform quartz-calcite fractionations that define an apparent pseudoisotherm. These quartz-calcite fractionations significantly underestimate both the temperature of metamorphism and the temperature of post-metamorphic alteration. Partial oxygen isotopic exchange between quartz and meteoric fluids also resulted in ¹⁸O depletion of quartz from dolomite marbles. This partial exchange was facilitated by an increase in the surface area of the quartz as a result of its dissolution by meteoric fluids. The negative δ¹³C values in carbonates result from the oxidation of organic material by meteoric fluids following metamorphism. Stable isotopic data from Lone Mountain marbles are consistent with the extensive circulation of meteoric hydrothermal fluids throughout western Nevada in Tertiary time. Received: 1 February 1994/Accepted: 12 September 1995     

Vapour transport of rare earth elements (REE) in volcanic gas: Evidence from encrustations at Oldoinyo Lengai

Fumarolic encrustations and natrocarbonatite lava from the active crater of Oldoinyo Lengai volcano, Tanzania, were sampled and analysed. Two types of encrustation were distinguished on the basis of their REE content, enriched (~ 2800–5600 × [REE_chondrite]) and depleted (~ 100–200 × [REE_chondrite]) relative to natrocarbonatite (1700–1900 × [REE_chondrite]. REE-enriched encrustations line the walls of actively degassing fumaroles, whereas REE-depleted encrustations occur mainly along cracks in and as crusts on cooling natrocarbonatite lava flows; one of the low REE encrustation samples was a stalactite from the wall of a possible fumarole. The encrustations are interpreted to have different origins, the former precipitating from volcanic gas and the latter from meteoric/ground water converted to steam by the heat of the overlying lava flow(s). REE-profiles of encrustations and natrocarbonatite are parallel, suggesting that there was no preferential mobilization of specific REE by either volcanic vapour or meteoric water vapour. The elevated REE-content of the first group of encrustations suggests that direct REE-transport from natrocarbonatite to volcanic vapour is possible. The REE trends observed in samples precipitating directly from the volcanic vapour cannot be explained by dry volatility based on the available data as there is no evidence in the encrustation compositions of the greatly enhanced volatility predicted for Yb and Eu. The observed extreme REE-fractionation with steep La/Sm slopes parallel to those of the natrocarbonatite reflects solvation and complexation reactions in the vapour phase that did not discriminate amongst the different REE or similar transport of REE in both the natrocarbonatite magma and its exsolving vapour. The low concentrations of REE in the encrustations produced by meteoric vapour suggest that the temperature was too low or that this vapour did not contain the ligands necessary to permit significant mobilization of the REE.     

Cretaceous crustal thinning in North Africa: Implications for magmatic and thermal events in the Eastern Tunisian margin and the Pelagic Sea

The integrated use of geological, geophysical, and geochemical data from Eastern Tunisia onshore and offshore samples indicate a crustal thinning induced from the Tethyan rifting. This is responsible for the subsequent evolution of the North African passive margin during the Late Cretaceous, and the creation of the fold–thrust belt and associated foreland deformations. This thinned crust was an area of mantle upwelling that favoured the increase of isotherms, the uprise of basalt magma, and the circulation of hydrothermal fluids. The Cretaceous magmatism generated a major hydrothermal event characterised by the circulation of hot fluids along faults and a relatively high heat flow in the basin. Temperature elevation and hydrothermal conditions led to alteration of basalts and generated a new mineral equilibrium around the enclosing sedimentary deposits.     

Three-dimensional MHD simulation of interplanetary magnetic field changes at 1 AU as a consequence of simulated solar flares

A fully three-dimensional (3D), time-dependent, MHD interplanetary global model (3D IGM) has been used, for the first time, to study the relationship between different forms of solar activity and transient variations of the north-south component, B_z, of the interplanetary magnetic field (IMF) at 1 AU. One form of solar activity, the flare, is simulated by using a pressure pulse at different locations near the solar surface and observing the simulated IMF evolution of B (=-B_z) at 1 AU. Results show that, for a given pressure pulse, the orientation of the corresponding transient variation of B_z has a strong relationship to the location of the pressure pulse and the initial conditions of the IMF. Two initial IMF conditions are considered: a unipolar Archimedean spiral with outward polarity and a flat heliospheric current sheet (HCS) with outward polarity in the northern hemisphere and which gradually reverses polarity in the solar equatorial plane to inward polarity in the southern heliospheric hemisphere. The wave guide effect of the HCS is also demonstrated.     

Cosmogenic-nuclide ages for New England coastal moraines, Martha's Vineyard and Cape Cod, Massachusetts, USA

Cosmogenic-nuclide exposure ages for 13 glacially transported boulders atop the Martha's Vineyard moraine, MA, USA, indicate that the southeastern margin of the Laurentide ice sheet reached its maximum extent during the last glaciation 23,200±500 yr ago. Another 10 age determinations from the younger Buzzards Bay moraine near Woods Hole, MA, indicate that this moraine complex was formed 18,800±400 yr ago. These ages correlate approximately with the terminations of cooling cycles recorded in Greenland ice cores and coeval ice-rafting events, suggesting that the marginal position of this sector of the ice sheet was tightly coupled to North Atlantic climate during the last glacial maximum.     

Geophysical applications of heat and mass transfer in turbulent pipe flow

The theory of heat and mass transfer in turbulent pipe flow is applied to a semi-infinite moist-walled cylindrical pipe to determine the longitudinal distributions of both temperature and moisture content as functions of external conditions, pipe radius and wall temperature, and flow velocity. Since many cave and mine passages approximate this model, the results are directly applicable to cave microclimate studies and mine ventilation problems. The results are found to agree well with previously published microclimate observations. The theory is also applicable to water flow in free-flow karst aquifers; specifically to the study of temperature variations and of solution kinetics under turbulent flow conditions.     

Stratified unbounded flow past of obstacles

We studied the surface perturbations of a two-layer ideal fluid induced by a flow past a submerged obstacle (simulated by a point dipole) in the vicinity of the density-jump layer. It is shown that the formation of two different types of surface waves is possible behind the flowed past obstacle in the real conditions of the open sea. The comparison of the amplitudes of the surface perturbations induced by the obstacle located above and below the density jump revealed their significant differences, which seems to be important for the use of this effect in practical problems.     

Unstable plasma irregular structures in the topside ionosphere and spread-<Emphasis Type="Italic">F</Emphasis>

The results of the Cosmos-900 satellite observ ations of plasma density inhomogeneities in the geomagnetic equator region and the longitudinal distributions of the equatorial spread-F, according to the Intercosmos-19 satellite data are presented. It is show n that the dependence of radiosignal propagation in the ionosphere on geophysical parameters is related to development of the electrostatic instability of the inhomo-geneous ionospheric plasma. The longitudinal dependence of the spread-F, can reflect the influence of the energetic sources, located outside the ionospheric layer that scatters a radio pulse, on the ionosphere. The manifestation of the longitudinal effect in the equatorial spread-F, in the Atlantic region can be explained by the influence of the cone instability on the plasma electrodynamics in the South Atlantic geomagnetic anomaly.