Cryogenesis as a factor of methane distribution in layers of permafrost

The gas seeps in Kolyma lowland are associated with methane inclusions in permafrost. These inclusions are formed by methane squeezed by epigenetic freezing of methane saturated deposits. This is proved by the biological genesis of the methane, by the isotopic data and the lower radiocarbon age of the methane from the gas seep in comparison with the radiocarbon age of the host deposits. The experimental data and observations of methane distribution in permafrost indicate that the methane distribution in the stratum of frozen deposits is a result of methane migration during cryolithogenesis. The regularities of methane distribution in the deposits and formation of methane inclusions may change the idea of the character and volumes of emission of greenhouse gases into the atmosphere upon degradation of permafrost.     

Asymmetrically zoned reaction rims: assessment of grain boundary diffusivities and growth rates related to natural diffusion-controlled mineral reactions

This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ～20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe²⁺, Fe³⁺ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe²⁺ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ～10³–10⁴ years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 10⁵–10⁶ and 10⁶–10⁷ years respectively.     

X-ray Raman scattering for structural investigation of silica/silicate minerals

We have performed X-ray Raman scattering (XRS) measurements on the oxygen K and silicon L absorption edges of four silica minerals: α-quartz, α-cristobalite, coesite, and stishovite. We have also calculated the partial electron densities of states (DOSs) and compared these with the XRS spectra. This study demonstrates that the short-range structure around the atom of interest strongly influences the XRS spectral features. Importantly, the oxygen K-edge XRS spectra are found to reflect the p-orbital DOS while the silicon L-edge spectra reflect the s- and d-orbital DOSs, even when a product of a momentum transfer and a mean radius of a electron orbit (1s for oxygen and 2p for silicon), Qr, is close to or larger than unity. Building on this, calculations of the partial DOSs for other silica phases are presented, including ultra-high-pressure phases, which provide a good reference for further XRS study of silica and silicate minerals. XRS measurements should be performed on not only either of oxygen or silicon but also on many kinds of constituent elements to reveal the structural change of glasses/melts of silicates under extreme conditions.     

BOWDITCH TRAVERSE ADJUSTMENT AND A MODIFICATION: NOTES

Abstract

In the second part of the paper on this subject in the last issue (30, 483) the references to the relative angular and linear closures are rather misleading. Mr Clendinning points out that the probable angular error at a station must be considered; the mean error is clearly different.     

Mapping of benthic enrichment patterns in Narragansett Bay,Rhode Island

A synoptic reconnaissance survey was performed over a five-day period in August 1988 to assess benthic habitat quality throughout Narragansett Bay, Rhode Island, using REMOTS^® sediment-profile photography and analysis in combination with measurements of the levels ofClostridium perfringens spores (a fecal indicator) in sediments. Three main areas of degraded benthic habitat quality related to either excessive organic enrichment or physical disturbance were identified based solely on the REMOTS^® analysis: the Providence River Reach, Greenwich Bay and its associated coves and harbors, and an area located along the southwest side of Prudence Island. Sediments at many stations in these areas exhibited shallow apparent redox-potential discontinuity (RPD) depths, high apparent oxygen demand, and low-order benthic successional stages. ElevatedClostridium perfringens spore counts in surface sediments were attributed to inputs from wastewater treatment facilities. The highest spore counts occurred at the head of the bay, where wastewater treatment discharges and associated combined sewer overflows are numerous. Using data from the REMOTS^® analysis and the sediment inventory ofC. perfringens spores, a distinction was made between organic enrichment of the bottom from sewage, versus nonsewage enrichment or physical disturbance. The combination of techniques employed in this investigation could be used to design more efficient monitoring programs to assess eutrophication effects in estuaries and determine the effectiveness of regulatory or management initiatives to reduce organic overenrichment of benthic habitats.     

Changing population concentration in India: a macro-regional scenario

There are great spatial variations in the distribution of the fast growing populations of India. About 70% of the 1981 population is concentrated in only 40% of the geographical area. Such a pattern of population concentration, with its spatio-temporal dimension, can be understood better if examined at the macro-regional level considering the physico-climatic and socio-economic diversity of the country. This is done by way of analyzing district level data for India as a whole and also for its various macro-regions. The study reveals that the Great Plains and Coastal Plains and Islands have a homogenous distribution and a higher population increase. The Deccan Plateau shows the most homogenous dispersion of population. The population is declining in the Northern Mountains and the Great Plains but accentuating in the Coastal Plains and Islands and the Deccan Plateau. The north and south of India are showing opposite trends in population concentration.     

Anisotropy of ionospheric irregularities determined from the amplitude of satellite signals at a single receiver

A new method of determining the anisotropy parameters of small-scale irregularities in the ionospheric F region is presented and experimental results are shown. The method is based on observations of amplitude fluctuations of radio waves transmitted by satellites flying above the F region. In practice, Russian navigational satellites are used and both the amplitude and the phase of the signal is measured on the ground level. The method determines both the field-aligned anisotropy and the field-perpendicular anisotropy and orientation of the spatial spectrum of the irregularities, assuming that the contours of constant power have an elliptic shape. A possibility of applying the method to amplitude tomography is also discussed. Using a chain of receivers on the ground level, one could locate the regions of small-scale irregularities as well as determine their relative intensities. Then the large-scale background structures could be mapped simultaneously by means of ordinary ray tomography using the phase observations, and therefore the relations of small-scale and large-scale structures could be investigated.     

Understanding and modeling basin hydrology: interpreting the hydrogeological signature

Basin landscapes possess an identifiable spatial structure, fashioned by climate, geology and land use, that affects their hydrologic response. This structure defines a basin's hydrogeological signature and corresponding patterns of runoff and stream chemistry. Interpreting this signature expresses a fundamental understanding of basin hydrology in terms of the dominant hydrologic components: surface, interflow and groundwater runoff. Using spatial analysis techniques, spatially distributed watershed characteristics and measurements of rainfall and runoff, we present an approach for modelling basin hydrology that integrates hydrogeological interpretation and hydrologic response unit concepts, applicable to both new and existing rainfall‐runoff models. The benefits of our modelling approach are a clearly defined distribution of dominant runoff form and behaviour, which is useful for interpreting functions of runoff in the recruitment and transport of sediment and other contaminants, and limited over‐parameterization. Our methods are illustrated in a case study focused on four watersheds (24 to 50 km²) draining the southern coast of California for the period October 1988 though to September 2002. Based on our hydrogeological interpretation, we present a new rainfall‐runoff model developed to simulate both surface and subsurface runoff, where surface runoff is from either urban or rural surfaces and subsurface runoff is either interflow from steep shallow soils or groundwater from bedrock and coarse‐textured fan deposits. Our assertions and model results are supported using streamflow data from seven US Geological Survey stream gauges and measured stream silica concentrations from two Santa Barbara Channel–Long Term Ecological Research Project sampling sites. Copyright © 2004 John Wiley & Sons, Ltd.     

ON THE OCCURRENCE OF LYSTROSAURUS IN SINKIANG~1

The presence of Dicynodontia in Sinkiang was first made manifest by the beautiful skull described in the same number of the Bulletin, (see above 563) as Dicynodon sinkianensis sp. nov. Recently, a second skull also collected by