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271.
272.
273.
To study the crystal chemistry of bernalite, Fe(OH)3, and the nature of the octahedral Fe3+ environment, Mössbauer spectra were recorded from 80 to 350 K, optical spectra were recorded at room temperature and a sample was studied using transmission electron microscopy. The Mössbauer spectrum of bernalite consists of a single six-line magnetic spectrum at 80 K. A broadened six-line magnetic spectrum with significantly less intensity is observed at higher temperatures, and is attributed to a small fraction of bernalite occurring as small particles. The variation of hyperfine magnetic field data for bulk bernalite with temperature is well described by the Weiss molecular field model with parameters of H
0 = 55.7±0.3 T and T
N = 427±5K. The centre shift data were fitted to the Debye model with parameters 0=0.482±0.005 mm/s (relative to -Fe) and M=492±30 K. The quadrupole shift is near zero at 300 K, and does not vary significantly with temperature. Absorption spectra in the visible and near infrared range show three crystal field bands of Fe3+ at 11 300, 16000 and 23 200 cm-1, giving a crystal field splitting of 14 570 cm-1 and Racah parameters of B=629 cm-1 and C=3381 cm-1. Infrared reflection spectra show two distinct OH-stretching frequencies, which could correspond to two structurally different types of OH groups. A band was also observed at 2250 cm-1, suggesting the presence of molecular CO2 in the large cation site. Analytical transmission electron microscopy indicates that Si occurs within the bernalite structure as well as along domain boundaries. Electron diffraction and imaging show that bernalite is polysynthetically twinned along {100} planes with twin domains ranging from 3 to 20 nm in thickness. Results are discussed with respect to the nature of the octahedral Fe3+ site, and compared with values for other iron oxides and hydroxides. 相似文献
274.
Use of public participation geographic information systems (PPGIS) studies that collect local knowledge in a spatial format is increasing as a tool in natural resources management. Qualitative PPGIS studies have been conducted as individual interviews, as workshops, and in focus groups. As the number of qualitative PPGIS studies increases, so does the need to understand their quality. Saturation, the point when the researcher determines that the collection of additional data will provide minimal new information as it relates to a particular issue, directly reflects on the validity of the study. While the concept of saturation is well established, it is still inconsistently assessed and reported. Furthermore, how saturation applies to qualitatively collected spatial data has not been addressed. A method is presented to assess spatial saturation of qualitative PPGIS data from 19 focus groups that were conducted to investigate important places for recreation, livelihoods, and the environment in the Florida Panhandle. 相似文献
275.
276.
Impact of Earth radiation pressure on GPS position estimates 总被引:2,自引:8,他引:2
C. J. Rodriguez-Solano U. Hugentobler P. Steigenberger S. Lutz 《Journal of Geodesy》2012,86(5):309-317
GPS satellite orbits available from the International GNSS Service (IGS) show a consistent radial bias of up to several cm
and a particular pattern in the Satellite Laser Ranging (SLR) residuals, which are suggested to be related to radiation pressure
mismodeling. In addition, orbit-related frequencies were identified in geodetic time series such as apparent geocenter motion
and station displacements derived from GPS tracking data. A potential solution to these discrepancies is the inclusion of
Earth radiation pressure (visible and infrared) modeling in the orbit determination process. This is currently not yet considered
by all analysis centers contributing to the IGS final orbits. The acceleration, accounting for Earth radiation and satellite
models, is introduced in this paper in the computation of a global GPS network (around 200 IGS sites) adopting the analysis
strategies from the Center for Orbit Determination in Europe (CODE). Two solutions covering 9 years (2000–2008) with and without
Earth radiation pressure were computed and form the basis for this study. In previous studies, it has been shown that Earth
radiation pressure has a non-negligible effect on the GPS orbits, mainly in the radial component. In this paper, the effect
on the along-track and cross-track components is studied in more detail. Also in this paper, it is shown that Earth radiation
pressure leads to a change in the estimates of GPS ground station positions, which is systematic over large regions of the
Earth. This observed “deformation” of the Earth is towards North–South and with large scale patterns that repeat six times
per GPS draconitic year (350 days), reaching a magnitude of up to 1 mm. The impact of Earth radiation pressure on the geocenter
and length of day estimates was also investigated, but the effect is found to be less significant as compared to the orbits
and position estimates. 相似文献
277.
K. W. Helen Lau Keith E. Louden Sharon Deemer Jeremy Hall John R. Hopper Brian E. Tucholke W. Steven Holbrook Hans Christian Larsen † 《Geophysical Journal International》2006,167(1):157-170
New multichannel seismic reflection data were collected over a 565 km transect covering the non-volcanic rifted margin of the central eastern Grand Banks and the Newfoundland Basin in the northwestern Atlantic. Three major crustal zones are interpreted from west to east over the seaward 350 km of the profile: (1) continental crust; (2) transitional basement and (3) oceanic crust. Continental crust thins over a wide zone (∼160 km) by forming a large rift basin (Carson Basin) and seaward fault block, together with a series of smaller fault blocks eastwards beneath the Salar and Newfoundland basins. Analysis of selected previous reflection profiles (Lithoprobe 85-4, 85-2 and Conrad NB-1) indicates that prominent landward-dipping reflections observed under the continental slope are a regional phenomenon. They define the landward edge of a deep serpentinized mantle layer, which underlies both extended continental crust and transitional basement. The 80-km-wide transitional basement is defined landwards by a basement high that may consist of serpentinized peridotite and seawards by a pair of basement highs of unknown crustal origin. Flat and unreflective transitional basement most likely is exhumed, serpentinized mantle, although our results do not exclude the possibility of anomalously thinned oceanic crust. A Moho reflection below interpreted oceanic crust is first observed landwards of magnetic anomaly M4, 230 km from the shelf break. Extrapolation of ages from chron M0 to the edge of interpreted oceanic crust suggests that the onset of seafloor spreading was ∼138 Ma (Valanginian) in the south (southern Newfoundland Basin) to ∼125 Ma (Barremian–Aptian boundary) in the north (Flemish Cap), comparable to those proposed for the conjugate margins. 相似文献
278.
We present here, for the O and B type stars in the Catalogue of Stellar Ultraviolet Fluxes, an approach which does not require
a precise knowledge of spectral type and luminosity class for derivingE(B-V) colour excesses. The method is based on the use of an UV-visual two-colour diagram; galactic variations in the interstellar
extinction law are analyzed and fully taken into account. Our results have been compared with those derived by using the differences
between observed and intrinsic colours for stars with known spectral classification. The very good agreement in a large number
of cases (94 per cent) demonstrates that our approach permits the derivation of reliable colour excess values for early type
stars even if only a rough spectral classification is available. 相似文献
279.
280.
Three‐dimensional (3D) numerical modelling of fault displacement enables the building of geological models to represent the complex 3D geometry and geological properties of faulted sedimentary basins. Using these models, cross‐fault juxtaposition relationships are predicted in 3D space and through time, based on the geometries of strata that are cut by faults. Forward modelling of fault development allows a 3D prediction of fault‐zone argillaceous smear using a 3D application of the Shale Gouge Ratio. Numerical models of the Artemis Field, Southern North Sea, UK and the Moab Fault, Utah, USA are used to demonstrate the developed techniques and compare them to traditional one‐ and two‐dimensional solutions. These examples demonstrate that a 3D analysis leads to significant improvements in the prediction of fault seal, the analysis of the interaction of the sealing properties of multiple faults, and the interpretation of fault seal within the context of sedimentary basin geometry. 相似文献