Quantitative textural analysis of packings of elongate crystals

The spatial distribution of grains in a solidifying igneous rock controls the physical properties of the crystal mush, and in turn is controlled by the rate of crystal growth and accumulation. A predominant non-spherical habit for igneous minerals brings into question the use of spherical particles in reference packings used for quantification of spatial distribution. Furthermore, variations of crystal clustering/ordering with length scale require spatial statistics which take into account the distribution of particles beyond nearest neighbours. Using random close packings of spherocylinders, we demonstrate the importance of aspect ratio for the aggregation index (usually known as R) and show that packings of spherical particles have more structure than packings of rods. The spatial distribution functions demonstrate that the plagioclase grains in the colonnade from the Holyoke basalt are clustered on a length scale of 0.5 mm. Understanding the controls on grain spatial distribution in igneous rocks will depend on the application of these techniques to well-understood environments.     

Tectonics of the Southern Ocean Passive Margins in the Africa–East Antarctica Region

Geotectonics - Based on geological and geophysical data for the conjugate Africa–East Antarctica margins, the peculiarities of preparation of the breakup of central Gondwana are discussed....     

Sediment type distribution in reservoirs: sediment source versus morphometry

 Bottom sediments were collected from seven Texas reservoirs to assess the spatial distribution of sediment types in reservoirs. The sediment samples were analyzed for water content, organic content, and grain-size distributions. The reservoirs are characterized by distinct water content patterns (referred to in this paper as Types I, II, and III) that reflect the lithologic units comprising their drainage area. The water content, organic content, and percent mud decreases from Type I (shale, marl) through Type II (limestone-marl-sandstone) to Type III (granite-gneiss-schist-sandstone) reservoirs. Reported elemental concentrations in the reservoir sediments are consistent with concentrations in the dominant rocks within their drainage area. While water depth accounts for part of the spatial distribution, sediment source explains the overall distribution of sediment types. Coarse-grained source rocks, multiple source rocks, and multiple tributaries which input sediment at different points contribute to an inconsistent sediment type distribution. Depending on the sediment source, sand and gravel-size sediments are present in the deeper regions of some reservoirs. This disrupts the classical morphometry (water depth, slope) controlled sediment distribution pattern (coarser sediments in shallower regions and finer sediments in deeper regions) of natural lakes. Thus, the location of tributaries and the type of sediments they carry are the dominant factors that control the sediment type distribution in reservoirs. Received: 16 June 1998 · Accepted: 24 August 1998     

Long-Term Geochemical Monitoring of the Source of the Angara River (Runoff from Lake Baikal)

The long-term data (1950–2017) on the chemical composition of the water from the source of the Angara River, which is the only run-off from Lake Baikal, a large and clean fresh water reservoir, are presented. The absence of water contamination despite the anthropogenic influence is shown. The similarity and constancy of the current composition of the waters in the lake and the Angara River are recorded. It is recommended to continue geochemical studies of this unique world heritage site.     

Electron beam analytical instruments and the determination of modes,spatial variations of minerals and textural features of rocks in polished section

Point counts based on X-ray intensities collected with an automated electron beam analytical instrument can be used to estimate the accurate modes required by modern physical-chemical modelling of rock-forming processes. In addition, the spatial distributions of mineral species and mineral compositions can be extracted from the coordinates of the point counting grid. Statistical tests of whether the mineral and porosity distributions are uniform can be performed by comparing the results from subareas of the polished section. The separate and composite contributions of the mineral phases to the texture and structure of the rock can be visually represented with mineral distribution maps. Qualitative differences in grain size can be recognized because the nonzero, finite electron beam diameter can detect grain boundaries. Spots on the minerals are identified by comparing the ranking of X-ray intensities with the ranking of intensities on a set of standards. For example, this method identified more than 88% of the spots on the surface of a polished section of an alkali olivine basalt. A small additional number of spots, approximately 1%, were identified because their spectra were dominated by the X-ray intensities of two characteristic elements. This method was particularly efficient in identifying phases with a small grain size and simple chemistry, e.g. apatite. The modal amounts of an alkali olivine basalt obtained with a microprobe are within approximately one standard deviation of the results obtained by point counting the same areas of the polished section under reflected and transmitted light if the minerals are major constituents and occur only in the groundmass. Accessory and phenocryst phases agree to within approximately three standard deviations.     

Geochemistry constraints of Mesozoic–Cenozoic calc-alkaline magmatism in the South Shetland arc, Antarctica

Geochemical data from basalts, basaltic andesites, and andesites of the Mesozoic–Cenozoic (143–44 Ma) from Livingston, Greenwich, Robert, King George, and Ardley Islands of the South Shetland archipelago, Antarctica, are presented. The rocks have variable SiO₂ of approximately 46–61 wt%, Al₂O₃ of 15–26 wt%, and total alkali (K₂O+Na₂O) of 2–6 wt%. Most samples have low Mg#, Cr, and Ni, which indicates that they have undergone significant fractional crystallization from mantle-derived melts. The presence of olivine cumulatic in the samples from Livingston and Robert Islands explains some high MgO, Ni, and Cr values, whereas low Rb, Zr, and Nb values could be related to undifferentiated magmas. N-MORB-normalized trace element patterns show that South Shetland Islands volcanic rocks have a geochemical pattern similar to that found for other island arcs, with enrichment in LILE relative to HFSE and in LREE relative to HREE. The geochemistry pattern and presence of calcic plagioclase, orthopyroxene, Mg-olivine, and titanomagnetite phenocrysts suggest a source related to the subduction process. The geochemical data also suggest magma evolution from the tholeiitic to the calc-alkaline series; some samples show a transitional pattern. Samples from the South Shetland archipelago show moderate LREE/HREE ratios relative to N-MORB and OIB, depletion in Nb relative to Yb, and high Th/Yb ratios. These patterns probably reflect magma derived from a lithospheric mantle source previously modified by fluids and sediments from a subduction zone.

Resumo

Dados geoquímicos de basaltos, andesitos basálticos e andesitos mesozóicos–cenozóicos (143–44 Ma) das ilhas Livingston, Greenwich, Robert, King George e Ardley do Arquipélago Shetland do Sul, Antártica são discutidas neste artigo. As rochas tem conteúdos de SiO₂ variando de 46 a 61%, Al₂O₃ de 15 a 26% e álcalis (K₂O+Na₂O) de 2 a 6%. A maior parte das amostras tem conteúdos baixos de Mg#, Cr e Ni, indicando que sofreram significante cristalização fracionada de fusões derivadas do manto. A presença de fases cumuláticas nas amostras das ilhas Livingston e Robert explicaria os elevados valores de MgO, Ni, Cr, enquanto que baixos valores de Rb, Zr e Nb observados nas amostras destas ilhas poderiam estar relacionados a magmas não diferenciados. Os padrões de elementos-traço normalizados pelo N-MORB mostram que as rochas vulcânicas das Ilhas Shetland do Sul têm padrão geoquímico similar àqueles encontrados em outros arcos de ilhas com enriquecimento em LILE em relação aos HFSE e em ETRL em relação aos ETRP. O padrão geoquímico e a ocorrência de fenocristais de plagioclásio cálcico, ortopiroxênio, olivina magnesiana e titanomagnetita sugerem origem relacionada a processos de subducção. Dados geoquímicos obtidos para as amostras do arquipélago Shetland do Sul sugerem um magma evoluindo de toleítico para cálcico-alcalino, observando-se em algumas amostras um padrão transicional. As amostras do arquipélago Shetland do Sul mostram em relação ao N-MORB e OIB, moderadas razões ETRL/ETRP, empobrecimento em Nb relativo a Yb e elevada razão Th/Yb Estes padrões refletem, provavelmente, magma derivado de uma fonte mantélica litosférica, que foi modificada por fluídos e sedimentos da zona de subducção.     

Timings of early crustal activity in southern highlands of Mars:Periods of crustal stretching and shortening

Extensional and compressional structures are globally abundant on Mars. Distribution of these structures and their ages constrain the crustal stress state and tectonic evolution of the planet. Here in this paper, we report on our investigation over the distribution of the tectonic structures and timings of the associated stress fields from the Noachis-Sabaea region. Thereafter, we hypothesize possible origins in relation to the internal/external processes through detailed morphostructural mapping. In doing so, we have extracted the absolute model ages of these linear tectonic structures using crater size-frequency distribution measurements, buffered crater counting in particular. The estimated ages indicate that the tectonic structures are younger than the mega impacts events(especially Hellas) and instead they reveal two dominant phases of interior dynamics prevailing on the southern highlands, firstly the extensional phase terminating around3.8 Ga forming grabens and then compressional phase around 3.5-3.6 Ga producing wrinkle ridges and lobate scarps. These derived absolute model ages of the grabens exhibit the age ca. 100 Ma younger than the previously documented end of the global extensional phase. The following compressional activity corresponds to the peak of global contraction period in Early Hesperian. Therefore, we conclude that the planet wide heat loss mechanism, involving crustal stretching coupled with gravitationally driven relaxation(i.e.,lithospheric mobility) resulted in the extensional structures around Late Noachian(around 3.8 Ga). Lately cooling related global contraction generated compressional stress ensuing shortening of the upper crust of the southern highlands at the Early Hesperian period(around 3.5-3.6 Ga).     

Palaeomagnetism and rock magnetism of the Deccan traps

Extensive work on the palaeomagnetism of the Deccan traps by several workers has revealed only one reversal (normal-reverse-normal) of the geomagnetic field during the period of eruption of these flows. The scatter in the natural remanent magnetic directions of different flows in a sequence of these traps is rather large and it persists even after magnetic cleaning. Generally this large scatter of directions is attributed to the geomagnetic secular variation during formation of the traps. Recent studies of the magnetic properties of the trap samples indicate that the presence of multidomain magnetite in a lava sequence differs from locality to locality in the Deccan trap province and so the stability of their natural remanent magnetization. While these features can be clearly perceived, an understanding of the same seems to be quite difficult. However, it appears that part of the scatter in directions could be due to the alteration of the magnetic minerals in the Deccan traps and hence it would not be proper to relate the entire scatter to the secular variation.     

Phenanthrene biomarkers in the organic matter of Precambrian and Phanerozoic deposits and in the oils of the Siberian Platform

The composition and distribution of phenanthrenes (polyaromatic compounds) have been studied in chloroform extracts from dispersed organic matter (OM) of clayey, siliceous, carbonate, and terrigenous rocks of different ages and facies and from some oils of the Siberian Platform. Phenanthrenes have been analyzed by gas chromatography-mass spectrometry. High contents of 1,7,8-trimethylphenanthrene and 1,1,7,8-tetramethyl-1,2,3,4-tetrahydrophenanthrene are present in the OM of Vendian and Cambrian carbonate-shale deposits and in ancient oils of the Nepa-Botuobiya and Anabar anteclises. The OM of Permian continental deposits and oils of the Vilyui syneclise is dominated by 1-methyl-7-isopropylphenanthrene (retene). A triangular diagram for identification of the types of original OM of rocks and classification of genetically related oils has been constructed based on the assessment of phenanthrene biomarker distribution. Putative pathways of the formation of phenanthrene biomarkers are discussed.