Ambient Changes in Tracer Concentrations from a Multilevel Monitoring System in Basalt

Starting in 2008, a 4‐year tracer study was conducted to evaluate ambient changes in groundwater concentrations of a 1,3,6‐naphthalene trisulfonate tracer that was added to drill water. Samples were collected under open borehole conditions and after installing a multilevel groundwater monitoring system completed with 11 discrete monitoring zones within dense and fractured basalt and sediment layers in the eastern Snake River aquifer. The study was done in cooperation with the U.S. Department of Energy to test whether ambient fracture flow conditions were sufficient to remove the effects of injected drill water prior to sample collection. Results from thief samples indicated that the tracer was present in minor concentrations 28 days after coring, but was not present 6 months after coring or 7 days after reaming the borehole. Results from sampling the multilevel monitoring system indicated that small concentrations of the tracer remained in 5 of 10 zones during some period after installation. All concentrations were several orders of magnitude lower than the initial concentrations in the drill water. The ports that had remnant concentrations of the tracer were either located near sediment layers or were located in dense basalt, which suggests limited groundwater flow near these ports. The ports completed in well‐fractured and vesicular basalt had no detectable concentrations.     

Seasonal variation in di-nitrogen fluxes and associated processes (denitrification, anammox and nitrogen fixation) in sediment subject to shellfish farming influences

Seasonal patterns of di-nitrogen fluxes together with denitrification, anammox, and N-fixation rates were studied in sediment in an area subject to strong human pressure via waste water, tributaries and shellfish farming in the Mediterranean Sea (Carteau Cove, NW area of the Gulf of Lion). Ammonium concentration demonstrated no seasonal variation, however, a large increase in its concentration was observed over a 10 years period due to intense biodeposition of organic matter. In contrast, nitrate concentration demonstrated no seasonal or long-term (10 years) variation. The main processes affecting di-nitrogen flux magnitudes were denitrification and N-fixation. Anammox was only detected occasionally, nevertheless it represented at times up to 39% of the N₂-flux. Nitrate reducing processes were variable and denitrification showed a 20-fold increase over the past 10 years and might actually have reached its potential maximal activity. Rates of N₂ production (denitrification and anammox) were generally higher than those of N-fixation, leading to elimination of nitrogen from the ecosystem.     

Data reporting norms for 40Ar/39Ar geochronology

Data reported in ⁴⁰Ar/³⁹Ar geochronology studies are commonly insufficient to allow computation of ages. This deficiency renders it difficult to compare ages based on different standards or constants, and often hinders critical evaluation of the results. Herein are presented an enumeration of the data that should be reported in all ⁴⁰Ar/³⁹Ar studies, including a discussion in support of these requirements. The minimum required data are identified and distinguished from parameters that are useful but may be derived from them by calculation. Finally, recommendations are made for metadata needed to document age calculations (e.g., from age spectrum or isochron analyses).     

A novel mobile multipole system (MUCEP) for shallow (0–3 m) geoelectrical investigation: the ‘Vol-de-canards’ array

The aim of this paper is to point out the advantages of multipoles for the exploration of the very near subsurface (0–3 m) by continuous profiling. We propose a new geometry with eight poles for a MUltipole Continuous Electrical Profiling (MUCEP) measuring system, where the array has a V-shape and is thus called ‘Vol-de-canards’. A series of criteria including 3D numerical simulations are performed (direct and inverse modelling) to determine the optimal geometry and to compare its performance (in terms of depth of investigation and resolution of the geometry of the targets) with the other arrays (quadrupoles or rectangular-type multipoles). This multipole was built together with a real-time acquisition system. The multidepth maps obtained confirm the characteristics predicted by numerical simulations.     

A proposal for comparing the reliabilities of alternative seismic hazard models

Differences between statistical unertainty and modeling uncertainty are briefly discussed. It is pointed out that, when different models are proposed for the interpretation of reality, the uncertainty cannot be described in terms of mean value and coefficient of variation. The important question is: which of the proposed models is more reliable than the others? The attention, then, is concentrated on the comparison between different models proposed for the estimate of the required quantity, looking for a criterion leading to the selection of the most reliable one. A criterion for comparison of different models is suggested. In the example of application considered in this paper, it proved to be effective, so that the continuation of numerical experiments, exploring different and more complex situations, seems promising.     

Specific features of explosive plasma flows in the near-earth space

The analytical expressions for determining the deceleration region of plasma, produced during large-scale geophysical experiments of explosion type, and taking into account the effect of the rarefied ionosphere and geomagnetic field have been obtained. The possibility of the magnetosphere braking by plasma produced by a powerful explosion is analyzed. The simplified set of equations used to analyze the linear and non-linear stages of flute instability of explosive plasma expanding into the magnetic field has been obtained. The mass overflow between flutes and the viscous force is taken into account. The experimental studies of flute instability during laser plasma expansion into the magnetic field are theoretically substantiated. The mechanism explaining the formation of a jet stream and the main jet inclination of 11° with respect to the axis of symmetry has been proposed.     

Magnetic properties of basalts and geodynamics of the rift zone in the southern Red Sea

Magnetic properties of young rift basalts in the southern Red Sea are studied in detail. It is found that basalt samples dredged in the rift zone are characterized by a large spread in magnetic parameters. The magnetic properties of the basalts are shown to indicate a complex evolution of the Red Sea rift zone. Titanomagnetite grains of the basalts are mostly affected by single-phase oxidation processes and have preserved paleomagnetic information. However, basalts discovered near the rift axis yield evidence of multiphase oxidation of titanomagnetite grains, which is untypical of young oceanic basalts. These basalts have high Curie points and large values of the natural remanent magnetization and Koenigsberger parameter. The corresponding samples were taken in nontransform zones where rocks have experienced the action of significant tectonic forces and, moreover, anomalous geomagnetic field patterns correlate with the position of these zones. Using the magnetic properties of the basalts, the northern segment of the rift axis is relocated.     

The composition of nutrient fluxes from contrasting UK river basins

Accurate estimates of N and P loads were obtained for four contrasting UK river basins over a complete annual cycle. The fractionation of these loads into dissolved and particulate, and inorganic and organic components allowed a detailed examination of the nutrient load composition and of the factors influencing both the relative and absolute magnitude of these components. The particulate phosphorus (TPP) loads account for 26–75% of the annual total phosphorus (TP) transport and are predominantly inorganic. The inorganic (PIP) and organic (POP) fractions of the TPP loads represent 20–47% and 6–28% of the annual TP transport, respectively. In contrast, the particulate nitrogen loads (TPN) represent 8% or less of the annual total nitrogen (TN) loads and are predominately organic. For dissolved P transport, the dissolved inorganic fraction (DIP) is more important, representing 15–70% of the TP loads, whereas the dissolved organic fraction (DOP) represents only 3–9% of the TP loads. The TN loads are dominated by the dissolved component and more particularly the total oxidized fraction (TON), which is composed of nitrate and nitrite and represents 76–82% of the annual TN transport. The remaining dissolved N species, ammonium (NH₄-N) and organic N (DON) account for 0·3–1·2% and 13–16% of the annual TN transport, respectively. The TPN and TPP fluxes closely reflect the suspended sediment dynamics of the study basins, which are in turn controlled by basin size and morphology. The dissolved inorganic nutrient fluxes are influenced by point source inputs to the study basins, especially for P, although the TON flux is primarily influenced by diffuse source contributions and the hydrological connectivity between the river and its catchment area. The dissolved organic fractions are closely related to the dissolved organic carbon (DOC) dynamics, which are in turn influenced by land use and basin size. The magnitude of the NH₄-N fraction was dependent on the proximity of the monitoring station to point source discharges, because of rapid nitrification within the water column. However, during storm events, desorption from suspended sediment may be temporarily important. Both the magnitude and relative contribution of the different nutrient fractions exhibit significant seasonal variability in response to the hydrological regime, sediment mobilization, the degree of dilution of point source inputs and biological processes. © 1998 John Wiley & Sons, Ltd.     

Precise Relative Location of 25-ton Chemical Explosions at Balapan Using IMS Stations

—?We test how well low-magnitude (m _bLg 1.8 to 2.6), 25-ton chemical explosions at Balapan, Kazakhstan, can be located using IMS stations and standard earth models, relying on precisely determined relative arrival times of nearly similar, regional and teleseismic waveforms. Three 1997 Balapan explosions were recorded by a number of currently reporting and surrogate IMS stations. Three regional stations and two teleseismic arrays yielded consistent waveforms appropriate for relative picking. Master-event locations based on the AK135 model and ground-truth information from the first, shallowest and best-recorded explosion, fell under 1 km from known locations, for depths constrained to that of the master event. The resulting 90% confidence ellipses covered 12–13?km² and contained the true locations; however, results for depth constrained to true depth were slightly less satisf actory. From predictions based on ground truth, we found a P _g -coda phase at Makanchi, Kazakhstan to be misidentified and poorly modeled. After accounting for this, 90% ellipses shrank to 2–3?km² and true-depth mislocation vectors became more consistent with confidence-ellipse orientations. These results suggest that a high level of precision could be provided by a tripartite array of calibration shots in cases where models are poorly known. We hope that the successful relocation of these small Balapan shots will support the role of calibration explosions in verification monitoring and special event studies, including on-site inspection.