Spectroscopic evolution of nova LW serpentis 1978 during its early decline

Optical spectroscopic data are presented on nova LW Serpentis 1978, obtained during its decline fromV 9.0 to ≃10.2 (compared to a value of ∼ 8.0 at recorded maximum). The spectrum and its evolution compare well with a typical nova, though the principal absorption (∼ −750 km s^−l) was very weak in comparison with the diffuse-enhanced absorption (∼ −1300 km s⁻¹). The principal absorption could be identified only in the lines of O I λλ7774, 8446, and in moderate-resolution observations of Hα. The salient features of spectral evolution follow: The near-infrared triplet of Ca n continuously weakened. O I λ8446 was always brighter than O I λ 7774, indicating continued importance of Lyman Β fluorescence. The lines due to [O I], [N II] and N n brightened considerably near the end of our observations (37 days from maximum). The Hα emission line was asymmetric all through with more emission towards the red. Its emission profile showed considerable structure. Based on the individual peaks in the Hα line profile, a kinematical model is proposed for the shell of LW Ser. The model consists of an equatorial ring, and a polar cone on the side away from the earth. The nearer polar cone did not show significant emission of Hα during our observations. The polar axis of the shell is inclined at a small angle (∼ 15‡) to the line of sight.     

Mineralogy and major-element geochemistry of the lower Permian Greta Seam,Sydney Basin,Australia

The mineralogy of the high-volatile bituminous coals and associated strata from the Greta seam, Sydney Basin, Australia, has been evaluated in this study. Although the seam is not immediately overlain by marine strata, percolation of marine water into the original peat bed is indicated by the petrological, mineralogical and geochemical characteristics, which resemble those of coals with marine roof strata. The upper and lower sections of the seam have contrasting mineralogy. Pyrite typically comprises 40 to 56 wt% of the mineral assemblage in the marine-influenced upper part of the seam section. The lower part contains much less pyrite (typically <5 wt%, organic-free basis), and also relatively abundant dawsonite (up to 14 wt%, organic-free basis). The minerals within most coal plies are largely of authigenic origin. These include pyrite, siderite, clay minerals (mainly kaolinite and Na-rich mixed-layer illite/smectite), and quartz, most of which have a relatively early, syngenetic origin. Minor Ti-bearing minerals, anatase or rutile, and phosphate minerals, fluorapatite and goyazite, were probably also formed during early diagenesis. Other minerals have features that indicate late-stage precipitation. These include abundant cleat- and fracture-filling dawsonite, which may be the result of reactions between earlier-precipitated kaolinite and Na₂CO₃- or NaHCO₃-bearing fluids. Minor albite may also be epigenetic, possibly precipitated from the same Ca–Al bearing fluids that formed the dawsonite. The most abundant detrital minerals in the Greta coals are quartz, poorly ordered kaolinite, illite and mixed-layer illite/smectite (I/S). These occur mainly in the floor, roof and other epiclastic horizons of the seam, reflecting periods of greater clastic influx into those parts of the original peat-forming environment. Detrital minerals are rare in the coals away from the epiclastic horizons, probably owing to almost complete sediment bypassing in the depositional system. Alternatively, any detrital minerals that were originally present may have been leached from the peat bed by diagenetic or post-diagenetic processes.     

Geochemical characteristics and evaluation of minor and trace elements pollution in groundwater of Tuticorin city,Tamil Nadu,India using geospatial techniques

In this work the major and trace elements pollution levels in groundwater of Tuticorin city of Tamil Nadu was investigated. This coastal city with numerous large and small scale industries has increasingly affected the water quality by dumping effluents. The mean major and trace elements levels in groundwater in descending order: Si > Sr > Zn > Fe > Rb > Se > Al > Mn > Cu > As > Cr > Ba > V > Ni > Pb > Mo > Co > Sb > Cd > Ag. The concentrations of As, Se, Pb, Ba, Al, Fe and V (0.084, 0.150, 0.057, 0.837, 0.357 and 0.052) in some of the groundwater samples exceed the standard value of world health organization (WHO, 2004). Interrelationship between the elements was done by correlation matrix and factor analysis which indicates the contribution from industrial and irrigation fields. Spatial interpolation of inverse distance method (IDW) maps of all the elements suggested that discharge of effluents from chemical factory (STERLITE, TAC, SPIC, HEAVY WATER PLANT, NILA SEA FOODS), municipal wastewater, fertilizers were added to the natural sources. Results of this research suggests that proper measures should be taken to protect the vital groundwater resources in the Tuticorin city.     

Highly ordered monoclinic K-feldspars from Haut Boréon anatexites,Argentera Massif,Maritime Alps

Summary In microperthitic alkali feldspars from the Haut Boréon anatexites in the Argentera Massif, Maritime Alps, the dominant K-rich phases are devoid of grid twinning but usually show weak uneven extinction. They consist of monoclinic forms characterized by (a) highly ordered Si,Al distributions in theT-sites, (b) weak but systematic residual strain due to coherency with the exsolved Na-rich phase, and (c) not very pure compositions ranging from 0.85 to 0.88 mole fraction KAlSi₃O₈. Weak triclinic peaks in X-ray powder patterns and the evidence of incipient formation of M-twinning and the diagonal association in single-crystal X-ray photographs indicate that the dominant monoclinic K-rich phases have undergone a partial transformation into triclinic material. The microperthites investigated appear to be the expression of a relatively rapid thermal history which started and terminated at temperatures higher than those experienced by the microperthites from the Mt. Pélago anatexites, which are exposed to the West of the Haut Boréon anatexites.

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Monokline K-Feldspäte mit hohem Ordnungsgrad aus Anatexiten des Haut Boréon, Argentera Massiv Seealpen

Zusammenfassung In den mikroperthitischen Alkalifeldspäten der Anatexite des Haut Boréon im Argentera Massiv (Seealpen) zeigen die vorherrschenden monoklinen Phasen keine Zwillingsgitterung, aber gewöhnlich schwach unregelmäßige Auslöschung. Sie bestehen aus monoklinem Kali-feldspat, der 1, durch eine weitgehend geordnete Si,Al-Verteilung auf denT-Positionen, 2. durch schwache aber systematische Spannungen, welche durch die Kohärenz mit der entmischten Na-reichen Phase verursacht sind, und 3, durch eine nicht sehr scharfe Zusammensetzung, die von 0,85 bis 0,88 Molenbruch KAlSi₃O₈ schwankt, charakterisiert ist. Schwache trikline Maxima in den Röntgen-Pulverdiagrammen sowie der Hinweis auf beginnende M-Verzwilligung und diagonale Assoziation in Röntgen-Einkristallaufnahmen weisen darauf hin, daß die vorherrschenden monoklinen Phasen partiell in triklines Material umgewandelt wurden. Die untersuchten Mikroperthite scheinen eine relativ rasche thermische Geschichte zu widerspiegeln, die bei höheren Temperaturen begann und endete als jene, welche die westlich des Haut Boréon aufgeschlossenen Anatexite des Mt. Pélago erlitten.

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With 6 Figures     

Elemental Concentrations in Japanese Silicate Rock Standards JA-1, JR-1 and JB-2

Data on three Japanese geochemical reference samples (JR-1, JA-1, and JB-2) are presented. Ten major and thirty-five trace element concentrations were determined using x-ray fluorescence, instrumental thermal neutron activation, thermal neutron capture prompt gamma-ray spectrometry, delayed neutron assay, automated thermal neutron activation analysis, inductively coupled plasma emission, atomic absorption, and ion selective electrode. Good agreement between the various methods and with recent literature values were obtained using error weighted mean concentrations for the samples.     

Spatial factors of differentiation of unemployment in Poland during 1990–2007

An analysis is made of the dynamics of unemployment and of the factors of its spatial differentiation on the territory of Poland. Six stages were identified in the dynamics of employment, which are associated with the character of development of the national economy and its accession to the common European market of manpower. It is stressed that the historical and political-geographical conditions have influence on the character of the spread of unemployment.     

Chemical denudation rates in Kärkevagge, Swedish Lapland

This study examines the spatial and temporal variability of chemical denudation rates in Kärkevagge, northern Sweden. The chemical flux rates within the valley are strongly influenced by the local geology. Chemical denudation rates determined for the study period are more than double those previously reported in the literature for this valley. Rates of greater than 46t km⁻² a⁻¹ were measured at the valley mouth over the course of the melt season. This difference is likely due to differences in measurement technique compared to that used by past researchers. This rate is also much higher than for other arctic and alpine watersheds. Chemical denudation in Kärkevagge is comparable to larger temperate rivers. The rapid chemical denudation in Kärkevagge is likely due to sulfide weathering creating acid solutions.     

HH 111 STIS Observations and their Analysis using Analytical and Numerical Models

The internal structure of stellar jets arising from young stellar objects is characterized by a series of `knots' or condensations which have highly supersonic proper motions. These structures, we believe, are the result of a variable ejection from the source, which leads to the formation of internal working surfaces or small bowshock within the jet beam. In this paper we present a long-slit spectrum of Herbig-Haro object HH 111 obtained with STIS and an interpretation of this observation in terms of an ejection velocity variability model.     

Long term evolution of quasi-circular Trojan orbits

Trojan asteroids undergo very large perturbations because of their resonance with Jupiter. Fortunately the secular evolution of quasi circular orbits remains simple—if we neglect the small short period perturbations. That study is done in the approximation of the three dimensional circular restricted three-body problem, with a small mass ratio μ—that is about 0.001 in the Sun Jupiter case. The Trojan asteroids can be defined as celestial bodies that have a “mean longitude”, M + ω + Ω, always different from that of Jupiter. In the vicinity of any circular Trojan orbit exists a set of “quasi-circular orbits” with the following properties: (A) Orbits of that set remain in that set with an eccentricity that remains of the order of the mass ratio μ. (B) The relative variations of the semi-major axis and the inclination remain of the order of ${\sqrt{\mu}}$ . (C) There exist corresponding “quasi integrals” the main terms of which have long-term relative variations of the order of μ only. For instance the product c(1 – cos i) where c is the modulus of the angular momentum and i the inclination. (D) The large perturbations affect essentially the difference “mean longitude of the Trojan asteroid minus mean longitude of Jupiter”. That difference can have very large perturbations that are characteristics of the “horseshoes orbit”. For small inclinations it is well known that this difference has two stable points near ±60° (Lagange equilibrium points L₄ and L₅) and an unstable point at 180° (L₃). The stable longitude differences are function of the inclination and reach 180° for an inclination of 145°41′. Beyond that inclination only one equilibrium remains: a stable difference at 180°.