Mid-Paleocene event at Gabal Nezzazat,Sinai, Egypt: planktonic foraminiferal biostratigraphy,mineralogy and geochemistry

The Qreiya Beds that record the ‘mid-Paleocene event’ at Gabal Nezzazat occur within the Igorina albeari (P3b) Zone and constitute part of a 14-m thick shale succession that ranges in age from Early to Late Paleocene. They are composed of four alternating dark grey and brown shale beds, which are thinly laminated, phosphatic, organic-rich and extremely sulphidic. They are characterized by distinct enrichment and high peak anomalies in chalcophiles (Zn, Co, Ni, Cu and Pb) and organic association elements (V and Cr), especially within the brown organic-rich beds. It is concluded that these elements are incorporated into the phosphatic debris, sulphides and organic matter. In contrast, the grey beds are enriched in clay minerals and quartz. Clay mineral assemblages indicate alternating periods of warm/humid climate (high kaolinite) and dry climate (low kaolinite) during the formation of the grey and brown beds, respectively. The sediments of the Qreiya Beds yield lithological, biotic, geochemical and mineralogical data indicative of suboxic/anoxic marine environments as a result of high productivity and/or upwelling. The top metre of the succession below the Qreiya Beds is characterized by a progressive change from faunas dominated by praemurcurids to faunas dominated by Morozovilids, and by a progressive upward decrease in δ¹³C_carb and δ¹⁸O_carb values. The foraminiferal faunal change may reflect shallowing and warming preceding deposition of the Qreiya Beds. The change in isotopic values is inferred to be the result of surface weathering, fluvial input and diagenesis with no evidence of any primary change that could support presence of a hyperthermal event.     

Pollution Transport in the Southwest Pacific

The impacts of long range transport of pollutants from anthropogenic and natural sources play a major role in atmospheric chemistry and may have an impact on global climate change. Although atmospheric transport in the Northern Hemisphere is recognised as an essential feature on aglohalscale, longrange transport in the Southern Hemisphere may have important regional implications.     

Spatial variation in river runoff into a coastal area — An ecological approach

Carbon and nitrogen stable isotopes were used to investigate spatial variation in terrestrial particulate organic matter (POM) input to a coastal area off the Tagus river estuary. Isotopic variation in higher trophic level organisms was also examined, along the coast. This study was carried out in late summer, after a period of 3 months of low river flow. The overall aim was to determine if under such conditions the coastal area is enriched by the river plume and, particularly, if lower secondary productivity should be expected in some areas. Spatial variation was detected as a gradient of decreasing terrestrial input with increasing distance from the river. It was concluded that terrestrial carbon input was also incorporated into higher trophic levels and that organisms with lower mobility are more sensitive to the gradient in terrestrial input. Even in low flow conditions the whole fishing area remained under the influence of the river plume, which still accounted for 24% of the total POM 30 km from the river mouth. Additionally, δ¹⁵N values indicated pollution input from the river Tagus.     

A software tool for monitoring legal minimum length of landings: Case study of a fishery in southern Spain

The regulation of minimum legal size (MLS) of catches is a tool widely applied in the management of fisheries resources, although the MLS does not always coincide with the length at first maturity (LFM). The optimization of this management tool requires a series of quality control in fish markets and transportation. A software application has been developed to make the control of the landings of several target species easier and faster. In order to test and make this tool operational, six species of commercial interest were selected: four species of fish and two species of bivalves. It is proposed to estimate the proportion of illegal specimens in the studied lot from the proportion of illegal individuals found in the samples taken from this lot. The input data for the application are the minimum legal size (MLS) of the species and the total length (TL) of each specimen sampled. The output data is a statistical summary of the percentage of specimens of size less than the legal minimum (TL≤MLS) within different confidence intervals (90%, 95% and 99%). The software developed will serve as a fast, efficient and easy to manage tool that allows inspectors to determine the degree of compliance on MLS control and to make a decision supported by statistical proof on fishing goods.     

Effect of wave amplitude on turbulent flow in a wavy channel by direct numerical simulation

The present study numerically investigates the characteristics of three-dimensional turbulent flow in a wavy channel. For the purpose of a careful observation of the effect of the wave amplitude on the turbulent flow, numerical simulations are performed at a various range of the wave amplitude to wavelength ratio (0.01?α/λ?0.05), where the wavelength is fixed with the same value of the mean channel height (H). The immersed boundary method is used to handle the wavy surface in a rectangular grid system, using the finite volume method. The Reynolds number (Re=U_bH/ν) based on the bulk velocity (U_b) is fixed at 6760. The present computational results for a wavy surface are well compared with those of references. When α/λ=0.02, the small recirculating flow occurs near the trough at the instant, but the mean reverse flow is not observed. In the mean flow field, the reverse flow appears from α/λ=0.03 among the wave amplitude considered in this study. The domain of the mean reverse flow defined by the locations of separation and reattachment depends strongly on the wave amplitude. The pressure drag coefficient augments with increasing the wave amplitude. The friction drag coefficient shows the increase and decrease behavior according to the wave amplitude. The quantitative information about the flow variables such as the distribution of pressure and shear stress on the wavy surface is highlighted.     

The estimation of acid dissociation constants in seawater media from potentionmetric titrations with strong base. I. The ionic product of water — Kw

The various assumptions implicit in the calculation of acid dissociation constants (based on ionic medium standard states) from potentiometric titrations using a cell with liquid junction (i.e. a pH measuring cell) have been examined. It was concluded that results can be obtained having an accuracy commensurate with the experimental precision. It has been shown that although the precise composition of the medium is a function of the hydrogen ion concentration (because of the protolytic nature of some of the ions in the media, e.g., sulphate and fluoride), the effect of such variations in the medium composition can be compensated for when defining the activity of hydrogen ion on an ionic medium standard state by defining the concentration of hydrogen ion as:

where β_HSO4 and β_HF are the relevant association constants and S_T and F_T are the total concentrations of sulphate and fluoride, respectively.This approach was used to obtain values for the ionic product of water (K_W) in artificial seawater media at various temperatures and ionic strengths. These were fitted to give the equation (molal concentration units):

$\text{pK}{}_{\mathrm{w}}\text{=}\text{3441.0}\text{T}\text{+2.256-0.7091}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(}\text{rms deviation 0.01}\text{)}$

where I is the formal ionic strength of the artificial seawater medium and T is the absolute temperature. The values obtained are in reasonable agreement with those found by previous workers.     

Agglutinated abyssal foraminifers of the equatorial pacific

The quantitative study of the distribution and taxonomic composition of recent living and dead (without plasma) benthic foraminifers revealed three foraminiferal assemblages in the bottom sediments of the Pacific Ocean at depths of 3350 to 4981 m. The assemblage dominated by the epibenthic Lagenammina difflugiformis, Reophax dentaliniformis, and Saccorhiza ramosa occupies the slopes of underwater hills. The assemblage with a high share of the infaunal Cribrostomoides subglobosum, C. nitidum, and Ammobaculites agglutinans is registered on the abyssal plateau. The assemblage with a significant proportion of the large Astrorhiza and Reophax species, which are characterized by an active way of life, populates gentle slopes and narrow depressions with potentially strong bottom currents.