城市节水工作存在的问题及对策研究

水资源匮乏已成为当今社会发展不可回避的主要问题，成为制约国民经济快速、稳定、健康发展的“瓶颈”，解决这一问题成为当务之急，本文就城市节水存在的问题，提出了加强节水管理的综合性措施。     

Integrated methodology for flood risk assessment and application in urban communities of Pakistan

Flood disasters and its consequent damages are on the rise globally. Pakistan has been experiencing an increase in flood frequency and severity along with resultant damages in the past. In addition to the regular practices of loss and damage estimation, current focus is on risk assessment of hazard-prone communities. Risk measurement is complex as scholars engaged in disaster science and management use different quantitative models with diverse interpretations. This study tries to provide clarity in conceptualizing disaster risk and proposes a risk assessment methodology with constituent components such as hazard, vulnerability (exposure and sensitivity) and coping/adaptive capacity. Three communities from different urban centers in Pakistan have been selected based on high flood frequency and intensity. A primary survey was conducted in selected urban communities to capture data on a number of variables relating to flood hazard, vulnerability and capacity to compute flood risk index. Households were categorized into different risk levels, such as can manage risk, can survive and cope, and cannot cope. It was found that risk levels varied significantly across the households of the three communities. Metropolitan city was found to be highly vulnerable as compared to smaller cities due to weak capacity. Households living in medium town had devised coping mechanisms to manage risk. The proposed methodology is tested and found operational for risk assessment of flood-prone areas and communities irrespective of locations and countries.     

A chemical survey of the Mississippi estuary

A “snap shot” survey of the Mississippi estuary was made during a period of low river discharge, when the estuarine mixing zone was within the deltaic channels. Concentrations of H⁺, Ca²⁺, inorganic phosphorus and inorganic carbon suggest that the waters of the river and the low salinity (<5‰) portion of the estuary are near saturation with respect to calcite and sedimentary calcium phosphate. An input of oxidized nitrogen species and N₂O was observed in the estuary between 0 and 4‰ salinity. The concentrations of dissolved NH₄ ⁺ and O₂, over most of the estuary, appeared to be influenced by decomposition of terrestrial organic matter in bottom sediments. The estuarine bottom also appears to be a source of CH₄ which has been suggested to originate from petroleum shipping and refining operations. Estuarine mixing with offshore Gulf waters was the dominant influence on distributions of dissolved species over most of the estuary (i.e., from salinities >5‰). The phytoplankton abundance (measured as chlorophylla) increased as the depth of the mixed layer decreased in a manner consistent with that expected for a light-limited ecosystem. Fluxes of NO₃ ^?+NO₂ ^? and soluble inorganic phosphorus to the Gulf of Mexico were estimated to be 3.4±0.2×10³ g N s^?1 and 1.9±0.2 g P s^?1 respectively, at the time of this study.     

NOAA WP-3D instrumentation and flight operations on AGASP-II

The second Arctic Gas and Aerosol Sampling Program (AGASP-II) was conducted across the non-Soviet Arctic in March and April 1986, to study the aerosol, gaseous, chemical, and optical properties of Arctic haze. One component of the program was supported with an instrumented NOAA WP-3D atmospheric research aircraft. Measurements of wind, temperature, ozone, water vapor, condensation nucleus concentration, and aerosol scattering extinction coefficient were used to determine the locations and properties of haze layers. The first three NOAA WP-3D research flights were conducted north of Barrow, Alaska, and over the Beaufort Sea northeast of Barter Island, Alaska. The next three sampled conditions in the high Arctic near Alert, Northwest Territories, Canada. All basic meteorological, gas, and aerosol systems are described. The WP-3D flight tracks and operations are presented.     

Determination of trace and rare-earth elements in Chinese soil and clay reference materials by ICP-MS

Inductively coupled plasma mass spectrometry(ICP-MS) has become a powerful tool for providing reliable analytical results in many laboratories around the word. In this study, the mixture of HF and HNO3 acids in high-temperature and high-pressure closed-vessel digestion technique were used to decompose some Chinese reference materials, and thirty seven elements were determined by ICP-MS. Most of the results for Chinese soil reference materials were found to be in reasonable agreement with the reference values, except Cs, Ta, Li, Ge, Zn, Nd, Tb and Ta whose values need to be revised. Their precisions were typically lower than 5% RSD. However, the Precisions of Chinese clay reference materials, especially for GBW03102 and GBW03102a, were significantly different with reference values, probably reflecting the existence of a coarser-grained fraction(70 μm) in samples, and the formation of fluorides in Al-rich samples during sample decomposition by using the mixture of HF and HNO3 acids. Moreover, thirty-seven trace elements covering the mass range from Li to U in four Chinese clay reference materials were firstly provided with good precision and accuracy in this study.     

Cornetite: Modulated densely-packed Cu2+ oxysalt

Summary The crystal structure of cornetite, Cu₃(PO₄)(OH)₃, orthorhombic, a = 10.854(1), b = 14.053(3), c = 7.086(2), Å, V = 1080.8(3) ų, Z = 8, space group Pbca, has been refined to an R-index of 3.9% for 1231 observed reflections (I > 3I), measured with MoK X-radiation on an automated four-circle diffractometer. The structure consists of edge sharing zig-zag chains of distorted octahedra, cross-linked by edge-sharing octahedral dimers into complex octahedral layers. Adjacent layers are corner-linked together by neighbouring octahedra and PO₄ tetrahedra into a densely-packed heteropolyhedral framework, in which the phosphate tetrahedra share edges with the octahedral dimers. The polyhedral layers exhibit a commensurate modulation that results from the interaction between local relaxation of Jahn-Teller distorted octahedra and the long-range requirements of translational periodicity.

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Cornetit: Ein moduliertes, dicht gepacktes Oxosalz des zweiwertigen Kupfers

Zusammenfassung Die Kristallstruktur des Cornetits, Cu₃(PO4)(OH)3, orthorhombisch, a = 10,854(1), b = 14,053(3), c = 7,086(2,) Å, V = 1080,8(3) ų, Z = 8, Raumgruppe Pbca, wurde mit 1231 beobachteten Röntgenreflexen (I > 3I), die mit MoK-Strahlung auf einem automatischen Vierkreis-Diffraktometer gesammelt worden waren, auf einen R-Wert von 3,9% verfeinert. Die Struktur besteht aus kantenverknüpften Zickzack-Ketten verzerrter Oktaeder, die über kantenverknüfte Oktaeder-Dimere zu komplizierten Oktaederschichten verbunden sind. Benachbarte Schichten sind über Ecken durch benachbarte Oktaeder und PO₄-Tetraeder zu einem dichtgepackten, heteropolyedrischen Gerüst verknüpft, in welchem die Phosphattetraeder mit den Oktaeder-Dimeren Kanten gemeinsam haben. Die Polyederschichten zeigen eine kommensurable Modulierung, die aus der Wechselwirkung zwischen der lokalen Relaxation von Jahn-Teller-verzerrten Oktaedern und den Forderungen der translatorischen Periodizität über größere Entfernungen resultiert.

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With 5 Figures     

大九湖泥炭地现代植物不同组分的δ18O特征及其古气候意义

最初学者利用泥炭植物同位素重建气候变化是参考树轮的研究方法,而树轮中不同组分的同位素对气候变化的响应不同。泥炭地植物不同组分的同位素对气候的响应是否也存在差异,需要进一步探讨和研究。此外,不同泥炭地植物δ¹⁸O的气候学解译存在一定的争议,这些解译的差异要求我们在利用泥炭δ¹⁸O重建古气候时需结合泥炭地现代过程的监测。文章以中国东部季风区的大九湖泥炭地为研究区域,测试研究区现代植被α纤维素与综纤维素的δ¹⁸O,对比两者的分布特征及其在时间序列上的相关性,进而探讨它们对气候因子的响应程度。结果表明：大九湖泥炭地植物δ¹⁸O分布较离散,平均值为25.09‰,α纤维素的δ¹⁸O比综纤维素δ¹⁸O偏正0.79‰~1.06‰,两种组分的δ¹⁸O在季节变化序列上没有明显的相关性。通过与区域气候因子的对比,我们发现温度是影响该地区植物δ¹⁸O变化的主要因素,而且植物α纤维素的δ¹⁸O比综纤维素的δ¹⁸O对温度响应更敏感,植物α纤维素更适用于作为研究古气候变化的载体,这一结果为中国东部季风内将泥炭地植物α纤维素的δ¹⁸O作为温度变化的代用指标提供了实验支持。

     

Relationship between footwall composition,crustal contamination,and fluid–rock interaction in the Platreef,Bushveld Complex,South Africa

In the northern limb of the 2.06-Ga Bushveld Complex, the Platreef is a platinum group elements (PGE)-, Cu-, and Ni-mineralized zone of pyroxenite that developed at the intrusion margin. From north to south, the footwall rocks of the Platreef change from Archaean granite to dolomite, hornfels, and quartzite. Where the footwall is granite, the Sr-isotope system is more strongly perturbed than where the footwall is Sr-poor dolomite, in which samples show an approximate isochron relationship. The Nd-isotope system for samples of pyroxenite and hanging wall norite shows an approximate isochron relationship with an implied age of 2.17 ± 0.2 Ga and initial Nd-isotope ratio of 0.5095. Assuming an age of 2.06 Ga, the ɛNd values range from −6.2 to −9.6 (ave. −7.8, n = 17) and on average are slightly more negative than the Main Zone of the Bushveld. These data are consistent with local contamination of an already contaminated magma of Main Zone composition. The similarity in isotope composition between the Platreef pyroxenites and the hanging wall norites suggests a common origin. Where the country rock is dolomite, the Platreef has generally higher plagioclase and pyroxene δ ¹⁸O values, and this indicates assimilation of the immediate footwall. Throughout the Platreef, there is considerable petrographic evidence for sub-solidus interaction with fluids, and the Δ _{plagioclase–pyroxene} values range from −2 to +6, which indicates interaction at both high and low temperatures. Whole-rock and mineral δD values suggest that the Platreef interacted with both magmatic and meteoric water, and the lack of disturbance to the Sr-isotope system suggests that fluid–rock interaction took place soon after emplacement. Where the footwall is granite, less negative δD values suggest a greater involvement of meteoric water. Consistently higher values of Δ _{plagioclase–pyroxene} in the Platreef pyroxenites and hanging wall norites in contact with dolomite suggest prolonged interaction with CO₂-rich fluid derived from decarbonation of the footwall rocks. The overprint of post crystallization fluid–rock interaction is the probable cause of the previously documented lack of correlation between PGE and sulfide content on the small scale. The Platreef in contact with dolomite is the focus of the highest PGE grades, and this suggests that dolomite contamination played a role in PGE concentration and deposition, but the exact link remains obscure. It is a possibility that the CO₂ produced by decarbonation of assimilated dolomite enhanced the process of PGE scavenging by sulfide precipitation.     

Application of statistical methods for predicting uniaxial compressive strength of limestone rocks using nondestructive tests

Uniaxial compressive strength (UCS) of an intact rock is an important geotechnical parameter for engineering applications. Using standard laboratory tests to determine UCS is a difficult, expensive and time-consuming task. The main purpose of this study is to develop a general model for predicting UCS of limestone samples and to investigate the relationships among UCS, Schmidt hammer rebound and P-wave velocity (V _P). For this reason, some samples of limestone rocks were collected from the southwestern Iran. In order to evaluate a correlation, the measured and predicted values were examined utilizing simple and multivariate regression techniques. In order to check the performance of the proposed equation, coefficient of determination (R ²), root-mean-square error, mean absolute percentage error, variance accounts for (VAF %), Akaike Information Criterion and performance index were determined. The results showed that the proposed equation by multivariate regression could be applied effectively to predict UCS from its combinations, i.e., ultrasonic pulse velocity and Schmidt hammer hardness. The results also showed that considering high prediction performance of the models developed, they can be used to perform preliminary stages of rock engineering assessments. It was evident that such prediction studies not only provide some practical tools but also contribute to better understanding of the main controlling index parameters of UCS of rocks.