Investigation of Failure Mechanisms and Migration of Organic Chemicals at Wilsonville, Illinois

Ground water contamination was discovered in 1981 in a monitoring well at the Earthline disposal facility near Wilsonville, Illinois. Organic chemicals had migrated at a rate 100 to 1000 times greater than predicted when the site received its permit to operate in 1978. Postulated failure mechanisms included migration through previously unmapped permeable zones, subsidence of an underground mine, organic-chemical and clay-mineral interactions, acid-mine drainage and clay interactions, trench-cover settlement, and erosion.
In this investigation, the Illinois State Geological Survey found the primary reason for the rapid migration: the presence of previously undetermined fractures and joints in glacial till. The inaccurate predictions of hydraulic conductivity were based on laboratory-determined values that did not adequately measure the effects of fractures and joints on the transit time calculations. Field-measured hydraulic conductivity values were generally 10 to 1000 times greater than their laboratory-measured counterparts, thus largely accounting for the discrepancy between predicted and actual migration rates in the transit time calculations. The problem was compounded, however, by the burial of liquid wastes and by trench covers that allowed excess surface runoff to enter the trenches. Organic-chemical and clay-mineral interactions may also have exacerbated the problem in areas where liquid organic wastes were buried.     

Mid-ultraviolet and optical photometry of helium stars

Mid-ultraviolet and optical photometric analysis of helium stars are presented. A linear relation exists between the effective temperature derived from model atmospheres and (1965-V)₀ index. The effective temperatures derived from (1965-V)₀ index are somewhat higher than that of MK spectral type estimates especially for late B-type helium objects.     

Nutrient (P, N) dynamics in the southwestern Kattegat, Scandinavia: sedimentation and resuspension effects

 The yearly nutrient supply from land and atmosphere to the study area in SW Kattegat is 10 900 tons of N and 365 tons of P. This is only few percent of the supply from adjacent marine areas, as the yearly transport through the study area is 218 000 tons of N and 18 250 tons of P. Yearly net deposition makes up 1340 tons of N (on average 2.5 g m^–2 yr^–1) and 477 ton of P (on average 0.9 g m^–2 yr^–1). Shallow-water parts of the study area have no net deposition because of frequent (>35% of the year) resuspension. Resuspension frequency in deep water is <1% of the year. Resuspension rates, as averages for the study area, are 10–17 times higher than net deposition rates. Because of resuspension, shallow-water sediments are coarse lag deposits with small amounts of organic matter (1.1%) and nutrients (0.04% N and 0.02% P). Deep-water sediments, in contrast, are fine grained with high levels of organic matter (11.7%) and nutrients (0.43% N and 0.15% P). Laboratory studies showed that resuspension changes the diffusive sediment water fluxes of nutrients, oxygen consumption, and penetration into the sediment. Fluxes of dissolved reactive phosphate from sediment to water after resuspension were negative in organic-rich sediments (13.2% organic matter) with low porosity (56) and close to zero in coarse sediments with a low organic matter content (2.3%) and high porosity (73). Fluxes of inorganic N after resuspension were reduced to 70% and 0–20% in relation to the rates before resuspension, respectively. Received: 10 July 1995 · Accepted: 19 January 1996     

A new method of initial orbit determination

Up to now we have been dealing with the construction of entirely analytical planetary theories such as VSOP82 (Bretagnon, 1982) and TOP82 (Simon, 1983). These theories take into account the whole of the Newtonian perturbations of nine point masses: the Sun, the Earth-Moon barycentre, the planets Mercury, Venus, Mars, Jupiter, Saturn, Uranus and Neptune. They also take into account perturbations due to some minor planets, to the action of the Moon and the relativistic effects. The perturbations of these last three types are in a very simple way under analytical form but they considerably increase the computations when introduced in the numerical integration programs.In the present paper we thus study a solution in which the Newtonian perturbations for the ten point masses are treated through numerical integration, the other perturbations being analytically added.     

Error estimates with L1 solutions

A method is given, based on the pseudoinverse of the equations of condition, to obtain error estimates for the solution in the normL ₁ of an over-determined linear system. The computational labor to obtain the errors, while not trivial, is less than that for various competing methods, particularly if there are many more equations of condition than unknowns. The error estimates for anL ₁ solution are substantially larger than those for a least squares solution of the some data. It is suggested that a complete discussion of a linear system include at least bothL ₁ and least squares solutions with their respective errors and the condition number of the linear system.     

Theoretical properties of radio-galaxies

We present optical photometric observations of the cataclysmic variables AO Psc and V 1223 Sgr, both of which are believed to contain slowly-rotating white-dwarf pulsars. These objectes belong to the new class of intermediate polars in which the magnetized-white-dwarf rotation period lies in between synchrous and extremely fast rotation periods. The observations reported here were carried out from the Kavalur Observatory using a 1 m reflector. High-time resolution light curves depicting a rich variety of flicker phenomena are presented. Results of a periodic analysis to search for coherent periodic modulations in the light curves are also presented. We have also derived the optical pulse profile of AO Psc and point out its similarities to the X-ray pulse profile.     

The three-dimensional geometry of the heliospheric current sheet

The three-dimensional geometry of the heliospheric current sheet seen from fixed points in interplanetary space is constructed for idealized (sinusoidal) magnetic neutral lines (equators) and for an observed magnetic equator on the basis of the “kinematic method” developed by Hakamada and Akasofu (1982). The cross-sections of the wavy current sheet at distances 1, 2 and 5 a.u. are also constructed for the idealized magnetic neutral lines.     

The Upper Pleistocene to Holocene sediments on the Mediterranean island of Lampedusa (Italy)

The island of Lampedusa lies on the northern edge of the African continental shelf, but during some Quaternary marine lowstands it was joined to the African continent. The study and dating of the aeolian, alluvial, detrital sediments, calcareous crusts and speleothems have established that the climatic–environmental variations recorded on the island can be related chronologically to those known for northern Libya, Tunisia and the Italian peninsula. During the Last Glacial Maximum, phases of Saharan dust accumulation on Lampedusa occurred, and were coeval with dust accumulation in crater lakes and on high mountains in central‐southern Italy, and with phases of glacial advance in the Apennines and in the Alps. During the late Holocene, accumulation of Saharan dust on Lampedusa occurred but there was little accumulation of dust on the northern side of the Mediterranean Sea. With the new data from Lampedusa, it is possible to envisage two different scenarios of atmospheric circulation relating to the Last Glacial Maximum and to the late Holocene. During the Last Glacial Maximum, southerly atmospheric circulation brought rainfall to the southern slopes of the Alps and to the Apennines. During the late Holocene, a prevalent westerly atmospheric circulation became established in the northern Mediterranean. Copyright © 2004 John Wiley & Sons, Ltd.