Non‐equilibrium concepts lead to a unified explanation of the formation of chondrules and chondrites

Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (p_Fe) is larger than the partial pressure at equilibrium (p_Fe(eq)). The supersaturation ratio S = p_Fe/p_Fe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H₂O ? H₂ + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites.     

2060 Chiron back to a minimum of brightness

The results of photometric observations of comet/asteroid 2060 Chiron at the Observatório do Pico dos Dias (Brazil-OPD) and the Observatoire de Haute-Provence (France-OHP) during 1994 and 1995 are presented. The analysis of the data shows a decrease of 2060 Chiron brightness from its peak values of 1988–1991. The absolute magnitude, H_v, varies from a maximum of 6.6 in February 1994 up to a minimum of 6.8 in June 1995. Therefore 2060 Chiron is back to a minimum of activity close to that of 1983–1985. The slope parameter G is found to be G = 0.71 ± 0.15. It is suggested that the H-G magnitude system, generally adopted to present 2060 Chiron brightness, is not the most appropriate due to the cometary activity of this object.     

Cygnus A

Cygnus A was the first hyper-active galaxy discovered, and it remains by far the closest of the ultra-luminous radio galaxies. As such, Cygnus A has played a fundamental role in the study of virtually all aspects of extreme activity in galaxies. We present a review of jet theory for powering the double-lobed radio emitting structures in powerful radio galaxies, followed by a review of observations of Cygnus A in the radio, optical, and X-ray relevant to testing various aspects of jet theory. Issues addressed include: jet structure from pc- to kpc-scales, jet stability, confinement, composition, and velocity, the double shock structure for the jet terminus and the origin of multiple radio hotspots, the nature of the filamentary structure in the radio lobes, and the hydrodynamic evolution of the radio lobes within a dense cluster atmosphere, including an analysis of pressure balance between the various gaseous components. Also discussed are relativistic particle acceleration and loss mechanisms in Cygnus A, as well as magnetic field strengths and geometries both within the radio source, and in the intracluster medium. We subsequently review the classification, cluster membership, and the emission components of the Cygnus A galaxy. The origin of the activity is discussed. Concentrating on the nuclear regions of the galaxy, we review the evidence for an obscured QSO, also given the constraints on the orientation of the radio source axis with respect to the sky plane. We present an overview of models of central engines in AGN and observations of Cygnus A which may be relevant to testing such models. We conclude with a brief section concerning the question of whether Cygnus A is representative of powerful high redshift radio galaxies. Received October 10, 1995     

Long-Term Changes of Polar Activity of the Sun

We discuss long-time changes of polar activity of the Sun using the new observational data sets in the optical range during 1872–2001. A study of the secular and cycle variations of the magnetic activity at the high-latitude regions is the main goal that includes polar magnetic field reversals during 1872–2001 and secular changes of the duration of polar activity cycles. The secular increase of the area of polar zones during the minimum activity in the last 120 years and as consequence a decrease of coronal temperature of the Sun in the high-latitude zones during the last 50 years. Correlation between the polar cycles of Caii-K bright points with the Wolf sunspot numbers cycles, W(t), and the 22-year polar magnetic cycles of Caii-K bright points at the high latitudes during 1905–1995 is discussed.     

Instrument development to search for biomarkers on mars: Terrestrial acidophile, iron-powered chemolithoautotrophic communities as model systems

Recent findings by the MER rover opportunity confirming the presence of iron minerals that can only be formed in the presence of water emphasize the study of analogous environments to Mars on Earth. The study of chemolithoautotrophic communities living in acidic iron-rich habitats is highly relevant in order to identify Mars analog environment-specific biomarkers. Iron oxidizing bacteria like Leptospirillum ferrooxidans and Acidithiobacillus ferrooxidans have ways of life for which it is feasible to identify a past or present hypothetical niche on Mars. We have developed a strategy for biomarker identification based on: (i) search for biosignatures on acid and metal-rich environments; (ii) development of an immunosensor microarray; and (iii) integration into an instrument for autonomous and remote operation. The instrument that we have built, called Signs Of LIfe Detector (SOLID), is capable of processing a variety of samples for the detection of specific biomarkers. Antibodies against several bacterial strains have been developed and tested in a microarray biosensor on SOLID. Tests with field samples have been successfully performed, allowing the detection of L. ferrooxidans, A. ferrooxidans present in sediment samples.     

On the stability of particular solutions of the singly averaged Hill problem

We consider the particular solutions of the evolutionary system of equations in elements that correspond to planar and spatial circular orbits of the singly averaged Hill problem. We analyze the stability of planar and spatial circular orbits to inclination and eccentricity, respectively. We construct the instability regions of both particular solutions in the plane of parameters of the problem.     

Geochemistry of metabauxites in the Bergsträsser Odenwald (Mid German Crystalline Rise) and palaeoenvironmental implications

Summary Pre- to early Variscan metamorphosed volcano-sedimentary series of the western (Bergstr?sser) Odenwald have been intruded by Variscan calc-alkaline magmatites with plate margin affinities. Within the NE-SW trending metabasic and metapelitic series, intercalations of anomalously aluminous- and iron-rich compositions representing former bauxites are distinguishable. Geochemical data indicate that the Al-, Fe-rich rocks are the metamorphic equivalents of a former bauxitic-ferralitic weathering profile, now comprising spinel fels (top) with relics of pisolitic structures, corundum-chlorite fels, corundum-cordierite-plagioclase gneiss, sillimanite-cordierite-plagioclase gneiss, cordierite-plagioclase gneiss and kinzigite (base) displaying a decrease of weathering in the order as listed. The evolution of such terrestrial sediments is related to specific climatic, environmental, and physico-chemical conditions similar to those of the present-day tropical to subtropical humid regions with high seasonal rains and intensive drainage. Comparison with palaeomagnetic and palaeoclimatic data indicate that the Odenwald metabauxites originally formed during the Lower to Mid-Devonian. Our results imply that, during this geological time span, parts of the precursors of the Mid-German Crystalline Rise not only transversed low latitudes but also were exposed to terrestrial weathering.

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Zusammenfassung Die Geochemie der Metabauxite im Bergstr?sser Odenwald (Mitteldeutsche Kristallinschwelle) und ihre Bedeutung für das Pal?omilieu Im westlichen (Bergstr?sser) Odenwald intrudierten variszische Plattenrand-Kalkalkali-Magmatite in pr?- bis früh-variszische, ehemalige vulkano-sediment?re Serien. Innerhalb der heute NE-SW streichenden Metabasit- und Metapelitzüge treten lokal Al-Fe-reiche Einschaltungen auf, die strukturell und geochemisch als metamorphe ?quivalente eines ehemaligen bauxitisch-ferralitischen Verwitterungsprofils klassifiziert werden k?nnen. Sie umfassen Spinellfelse mit erhaltenen, ehemaligen zonierten Pisolithen, Korund-Chloritfelse, Korund-Cordierit-Plagioklasgneise, Sillimanit-Cordierit-Plagioklasgneise, Cordierit-Plagioklasgneise und Kinzigite. Bauxite k?nnen als terrestrische Bildungen nur unter speziellen klimatischen und physiko-chemischen Bedingungen entstehen. Pal?omagnetische und pal?oklimatische Daten legen die Bildung der ehemaligen Bauxite im unteren bis mittleren Devon nahe. Daraus folgt, da? w?hrend dieser geologischen Zeitspanne die Vorl?ufer der mitteldeutschen Kristallinschwelle bei der Norddrift nicht nur ?quatorn?he passierten, sondern auch partiell ungest?rte, terrestrische, tropisch-subtropische Verwitterungsprozesse abliefen.

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Received June 10, 1999; revised version accepted October 30, 2000