Sediment–water interactions of natural oestrogens under estuarine conditions

The natural human female hormones oestrone and 17β-oestradiol have been implicated in the disruption of endocrine systems in some wildlife adjacent to sewage effluents. The sorption behaviour of these two compounds under estuarine conditions was studied by spiking either 2.55 μg of oestrone or 2.65 μg of 17β-oestradiol in kinetic experiments. In equilibrium experiments, 3 ng of oestrone or 3.2 ng of 17β-oestradiol was added in each of the centrifuge tubes. Sorption onto sediment particles was relatively slow, with sorption equilibrium being reached in about 70 and 170 h for oestrone and 17β-oestradiol, respectively. The effects of a variety of environmental parameters on sorption were studied including salinity, sediment concentration (SC), the presence of a third phase, particle size and, also, surfactant concentrations. Results show that although salinity did not induce any statistically significant effect on the sorption of 17β-oestradiol, it did statistically enhance the sorption of oestrone, and a salting constant of 0.3 l mol⁻¹ was derived. The partition coefficient for both compounds decreased with increasing sediment concentration, a phenomenon that has been widely reported and attributed to the presence of colloids (which could enhance dissolved concentrations). In this paper, the true partition coefficients for sediment particles (K_p^true) and colloidal particles (K_c^true) have been calculated, and a K_p^true value of 141 and 102 ml g⁻¹ was obtained for oestrone and 17β-oestradiol, respectively. In addition, K_c^true values for oestrone (222×10² ml g⁻¹) and 17β-oestradiol (135×10² ml g⁻¹) were two orders of magnitude higher than their respective K_p^true values, suggesting that the colloidal particles are significantly stronger sorbents for natural oestrogens than sediment particles. Particles of different sizes were found to have different partition coefficients due to the strong relationships between partition coefficients for the two compounds and particulate organic carbon (POC) contents and specific surface areas (SSAs). The presence of a surfactant was shown to reduce the partition coefficients for the two compounds, although its concentrations being used were higher than those normally found in the natural environment.     

Sedimentology of a subtidal,tide-dominated sand body in the Yellow Sea,southwest Korea

Odanam Satoe, a subtidal, tide-dominated sand body in the Yellow Sea, Korea, is linear in plan and asymmetrical in cross-section. It consists of fine- to medium-grained, well-sorted subangular sand. Bedforms consist of high-amplitude (1–2 m) sandwaves on the lower flanks of the gentler-sloping bar surface, and medium-amplitude (0.5-1 m) sandwaves on the sand body trough adjoining the steeper face, the bar crest and shallower parts of the gently sloping bar surface. Bedforms are absent on the relatively steeper bar surface, which is characterized by 2° slopes. Bedform orientation on the gentler slope is oblique by 30° to the bar crest, parallel to the sand-body crest on the crest itself, and opposite to the steeper sand-body face in the trough below the steeper slope of the bar.Bottom current velocity data show that tidal currents are semi-rotary with a flood time—velocity asymmetry over the gentler slope, and ebb time—velocity asymmetry over the steeper slope during most of the tidal cycle. Tidal-current flow parallels bar elongation over the steeper slope, whereas over the gentler slope, tidal-current flow is directed at 30° to the bar crest and changes to normal to the crest one hour prior to low tide. Bedform orientation mapped with side-scan sonar shows agreement with these flow directions.Sand dispersal around the sand body is controlled by time—velocity asymmetry and partial rotary flow directions of tidal currents. This circulation causes not only a trapezoidal mode of grain dispersal, but also westerly migration of the sand body documented from comparative bathymetric surveys in 1964 and 1980.     

Onshore Neogene stratigraphy in the North of the Alboran Sea (Betic Internal Zones): Paleogeographic implications

The Neogene is the period in which the Betic Cordillera, the Rif, and the Alboran Sea acquired their present configuration. The Neogene sediments of the Betic Internal Zones (located directly to the North of the Alboran Sea) show the effects of important periods of deformation. Deposition was clearly controlled by tectonics. Therefore the generation, evolution, and total or partial destruction of basins and the formation of new, often superimposed, basins are common phenomena, according to the locations of the basins in the Betic Cordillera and to the different geodynamic situations.     

Trace element fractionation and distribution in turbidites,homogeneous and pelagic deposits; the Zaire Fan,Southeast Atlantic Ocean

In turbidites, homogeneous and pelagic deposits of the Zaire Fan Th, La, Sm, and Rb and to a lesser extent Yb and Ta correlate strongly. La, Sm, Yb, Rb, Ta, and Th increase two-fold in Te3 turbidite intervals relative to Te 1 due to an increase in clay fraction with which these elements occur associated preferentially.Hf and Zr are anomalously high in Tel and Tel intervals which is probably a result of mineral separation. Zr is absent in Te3 intervals and the homogenous and pelagic deposits. Ba, Br. and U are lowest in turbidites and highest in homogenous continental slope deposits which is probably caused by upwelling. Cc anomalies may be related to the crystallinity of smectite.     

Breaking wave impact on vertical and sloping coastal structures

The results of laboratory experiments on the maximum and bottom impact pressures from waves breaking directly on vertical and sloping faced coastal structures are presented. Direct wave breaking on a wall is classified as early, late, and perfect breaking. Although the present study is aimed at dealing with the type of impact resulting from the perfect breaking, to some extent the occurrence of early and late breaking are unavoidable. The wave impact pressures, therefore, have a random nature of variation from impact-to-impact under the same conditions. The maximum and bottom impact pressures on walls are treated statistically. The effects of the wall angle and foreshore slope on these two quantities are examined. The results show that for practical applications, the still-water level can be taken as the acting place for the maximum impact pressure on the wall. Simultaneous impact pressure distribution below and above still-water level may be approximated as parabolic and linear, respectively. Finally, using a wall deflection criterion, a water depth region in front of the wall is defined, where the breaking wave forces may reach a critical level.     

Harpacticoida taxocen diversity in the silty-sandy littoral zone of Kandalaksha Bay of the White Sea

The fauna composition, ecological groups, and life forms of Harpacticoids of soft littoral grounds from 15 sites off the Karelian coast in Kandalaksha Bay of the White Sea were studied. Six types of harpacticoid taxocens with different sets of dominating species are described. On silty sands with clear signs of desalination, the Stenchelia palustris taxocen is common; medium-grained sands are characterized by the Heterolaophonte minuta, Paraleptastacus kliei — Huntemannia jadensis, and Amphiascoides nanus — Scottopsyllus minor taxocens; while on coarse sands, the Ameira parvula and Ameira scotti — Mesochra lilljeborgi taxocens have developed. The diversity of the taxocens is partly explained by the differences in the grain-size composition and salinity at different sites. In addition, groups of various taxocens dwelling on the same type of the sediments were found in different minor bights of the coastline.     

Interstitial water chemistry of villefranche bay sediments: Trace metal diagenesis

Pore water aliquots were taken with an in situ close interval sampler: the “Peeper”.We report here the pore water concentration profiles of TCO₂, SO₄, TH₂S, Ca and the trace metals Mn, Cu, Pb, Cd and Cr from sediments of a relatively polluted area, the Villefranche Bay, on the French Riviera (close to Nice).We investigated the major ion concentrations in order to establish geochemical mass balances of organic matter oxidation. ΔTCO₂/ΔSO₄ was <−2.0, reflecting the precipitation of calcite as confirmed by the calcium profile. Reduction of sulfate led to increasing sulfide concentrations with depth.Trace metal interstitial water concentrations decreased from 63 to 5 nM, 18 to 4 nM and 6.6 to less than 2 nM for Cu, Pb and Cr, respectively. Cd showed a different pattern with top and deep values of 0.7 nM and a minimum of 0.27 nM.Thermodynamic calculations were performed which suggest the potential formation of mineral phases such as sulfides.     

Cytochrome P450 differences in normal and imposex-affected female whelk Buccinum undatum from the open North Sea

Normal and imposex-affected female Buccinum undatum were sampled from the open North Sea at three locations, one with low, and two with high shipping densities. Cytochrome P450 components and P450 aromatase activity were determined in the microsomal fractions isolated from pooled digestive gland/gonads. Cytochrome P450 aromatase activity was significantly higher (P < 0.05) in normal females collected in the low shipping density area (1,325 +/- 295 fmol/h/mg protein) than levels from imposex animals from a high shipping density area (620 +/- 287 fmol/h/mg protein). A negative correlation was found between aromatase activity and organotin body burden (r = -0.99). Levels of CYP450, cytochrome b5 and NADPH cytochrome c reductase activity did not show differences among groups. This is the first field evidence of depressed aromatase activity in imposex affected females, although additional research under laboratory controlled conditions is required to fully understand the mechanisms underlying the development of imposex in this species.     

The dissociation constants of carbonic acid in seawater at salinities 5 to 45 and temperatures 0 to 45°C

The pK₁^* and pK₂^* for the dissociation of carbonic acid in seawater have been determined from 0 to 45°C and S = 5 to 45. The values of pK₁^* have been determined from emf measurements for the cell:

Pt](1 − X)H2 + XCO2|NaHCO3, CO2 in synthetic seawater|AgC1; Ag

where X is the mole fraction of CO₂ in the gas. The values of pK₂^* have been determined from emf measurements on the cell:

Pt, H2(g, 1 atm)|Na2CO3, NaHCO3 in synthethic seawater|AgC1; Ag

The results have been fitted to the equations:

lnK^*₁ = 2.83655 − 2307.1266/T − 1.5529413 lnT + (−0.20760841 − 4.0484/T)S^0.5 + 0.08468345S − 0.00654208S¹

InK^*₂ = −9.226508 − 3351.6106/T− 0.2005743 lnT + (−0.106901773 − 23.9722/T)S^0.5 + 0.1130822S − 0.00846934S^1.5

where T is the temperature in K, S is the salinity, and the standard deviations of the fits are σ = 0.0048 in lnK₁^* and σ = 0.0070 in lnK₂^*.Our new results are in good agreement at S = 35 (±0.002 in pK₁^*and ±0.005 in pK₂^*) from 0 to 45°C with the earlier results of Goyet and Poisson (1989). Since our measurements are more precise than the earlier measurements due to the use of the Pt, H₂|AgCl, Ag electrode system, we feel that our equations should be used to calculate the components of the carbonate system in seawater.