Major element geochemical variations in a Miocene-Pliocene Siwalik paleosol sequence: Implications to soil forming processes in the Himalayan foreland basin

Elemental mobility based on major element geochemistry from 58 horizons related to six paleosols profiles in a typical Miocene — Pliocene Siwalik fluvial sequence in the NW Himalaya has been reported here. The paleosols developed over felsic parent material of fine to medium grained sandstone indicate notable enrichment of sesquioxides (Al₂O₃ = 29 % and Fe₂O₃ = 54 %) depicting significant leaching and dissolution. The depletion of base cations (mean wt% of Na₂O = 0.24; CaO = 0.51) and SiO₂ (mean wt% = 63.6) in the pedogenic layers and its enrichment in the parental material (mean wt% of Na₂O = 0.44; CaO = 1.3; SiO₂ = 70.1) shows a good gradient of elemental mobility due to pedogenesis. Bivariate plots of the base ratios (Na₂O/K₂O, CaO/K₂O, and MgO/K₂O) vs. Al₂O₃ reveal independent distribution for parent material, pedogenic horizons and the incipient zone indicating the gradual addition/removal of immobile/mobile elements with varying pedogenesis. Discontinuous and segmented pattern of the geochemical parameters enables discrimination of multiple pedogenic episodes and recognition of soil welding processes in the multistorey composite paleosols. We also test the applicability of the geochemical climofunctions: the Mean Annual Precipitation (MAP) and Mean Annual Temperature (MAT); that demands more data for calibration in the Siwalik paleosols.     

Experimental determination of photostability and fluorescence‐based detection of PAHs on the Martian surface

Abstract– Even in the absence of any biosphere on Mars, organic molecules, including polycyclic aromatic hydrocarbons (PAHs), are expected on its surface due to delivery by comets and meteorites of extraterrestrial organics synthesized by astrochemistry, or perhaps in situ synthesis in ancient prebiotic chemistry. Any organic compounds exposed to the unfiltered solar ultraviolet spectrum or oxidizing surface conditions would have been readily destroyed, but discoverable caches of Martian organics may remain shielded in the subsurface or within surface rocks. We have studied the stability of three representative polycyclic aromatic hydrocarbons (PAHs) in a Mars chamber, emulating the ultraviolet spectrum of unfiltered sunlight under temperature and pressure conditions of the Martian surface. Fluorescence spectroscopy is used as a sensitive indicator of remaining PAH concentration for laboratory quantification of molecular degradation rates once exposed on the Martian surface. Fluorescence‐based instrumentation has also been proposed as an effective surveying method for prebiotic organics on the Martian surface. We find the representative PAHs, anthracene, pyrene, and perylene, to have persistence half‐lives once exposed on the Martian surface of between 25 and 60 h of noontime summer UV irradiation, as measured by fluorescence at their peak excitation wavelength. This equates to between 4 and 9.6 sols when the diurnal cycle of UV light intensity on the Martian surface is taken into account, giving a substantial window of opportunity for detection of organic fluorescence before photodegradation. This study thus supports the use of fluorescence‐based instrumentation for surveying recently exposed material (such as from cores or drill tailings) for native Martian organic molecules in rover missions.     

Near-infrared spectroscopy of dark asteroids

Near-infrared (J, H and K bands) spectra of nine dark asteroids (chosen among a sample of supposed primitive objects between C and D classes) have been obtained at the Mauna Kea Observatory (Hawaii) with the 2.2-m telescope using KSPEC as spectrograph. The aim of this work was to search for evidence of the presence of organic materials in these objects as found in other planetary bodies as 5145 Pholus, and in some cometary nuclei. A careful analysis of the data has revealed flat or slightly redder spectra than the solar one for all observed asteroids. No evidence of distinct absorption features was found.     

Controls on debris-flow initiation on burned and unburned hillslopes during an exceptional rainstorm in southern New Mexico,USA

AbstractUsing observations from 688 debris flows, we analyse the hydrologic and landscape characteristics that influenced debris-flow initiation mechanisms and locations in a watershed that had been partially burned by the 2012 Whitewater-Baldy Complex Fire in the Gila Mountains, southern New Mexico. Debris flows can initiate due to different processes. Slopes can fail as discrete landslides and then become fluidized and move downstream as debris flows (landslide initiated) or progressive bulking of sediment from a distributed area can become channelized and concentrated as it moves downslope (runoff generated). In this study, we have an unusual opportunity to investigate both types of debris-flow initiation mechanisms in our observations of debris flows, triggered by an exceptional rainstorm in the autumn of 2013. Additionally, we compare our observations with those of a dataset of 1138 debris flows in the Colorado Front Range, triggered during the same weather system. We found that runoff-generated debris flows dominated in burn areas, and runoff required to start these flows could be well characterized by the Shields stress. Landslide-initiated debris flows were dominant in unburned areas. Debris-flow densities were tied to total rainfall and precipitation intensities. Like the observations in the Colorado Front Range, debris-flow initiation locations were found primarily in areas of relatively sparse vegetation on south-facing slopes between 25 and 40°, and with upslope contributing areas less than 1000 m². In terms of preferential locations for debris-flow initiations, 2013 vegetation coverage, approximated by Green–Red Vegetation Index metrics, proved to be more influential than the 2012 burn-severity designation. The uniformity of observations between our study area and those in the Colorado Front Range indicate that the underlying hydrologic and landscape patterns of the debris-flow initiation locations documented in these studies could be applicable to the wider southwest and Rocky Mountain regions. © 2019 John Wiley & Sons, Ltd.     

Influence of Thermal Effects on the Wind Field Within the Urban Environment

Micrometeorological conditions in the vicinity of urban buildings strongly influence the requirements that are imposed on building heating and cooling. The goal of the present study, carried out within the Advance Tools for Rational Energy Use towards Sustainability (ATREUS) European research network, is the evaluation of the wind field around buildings with walls heated by solar radiation. Two computational fluid dynamics (CFD) codes were validated against extensive wind-tunnel observations to assess the influence of thermal effects on model performance. The code selected from this validation was used to simulate the wind and temperature fields for a summer day in a specific region of the city of Lisbon. For this study, the meteorological data produced by a non-hydrostatic mesoscale atmospheric model (MM5) were used as boundary conditions for a CFD code, which was further applied to analyze the effects of local roughness elements and thermodynamic conditions on the air flow around buildings. The CFD modelling can also provide the inflow parameters for a Heating, Ventilation and Air Conditioning (HVAC) system, used to evaluate the building energy budgets and to predict performance of the air-conditioning system. The main finding of the present three-dimensional analyses is that thermal forcing associated with the heating of buildings can significantly modify local properties of the air flow.     

A petrologic and trace element study of Dar al Gani 476 and Dar al Gani 489: Twin meteorites with affinities to basaltic and lherzolitic shergottites

Abstract— We present the results of a combined mineralogic‐petrologic and ion microprobe study of two martian meteorites recently recovered in the Lybian Sahara, Dar al Gani 476 (DaG 476) and Dar al Gani 489 (DaG 489). Having resided in a hot desert environment for an extended time, DaG 476 and DaG 489 were subjected to terrestrial weathering that significantly altered their chemical composition. In particular, analyses of some of the silicates show light rare earth element (LREE)‐enrichment resulting from terrestrial alteration. In situ measurement of trace element abundances in minerals allows us to identify areas unaffected by this contamination and, thereby, to infer the petrogenesis of these meteorites. No significant compositional differences between DaG 476 and DaG 489 were found, supporting the hypothesis that they belong to the same fall. These meteorites have characteristics in common with both basaltic and lherzolitic shergottites, possibly suggesting spatial and petrogenetic associations of these two types of lithologies on Mars. However, the compositions of Fe‐Ti oxides and the size of Eu anomalies in the earliest‐formed pyroxenes indicate that the two Saharan meteorites probably experienced more reducing crystallization conditions than other shergottites (with the exception of Queen Alexandra Range (QUE) 94201). As is the case for other shergottites, trace element microdistributions in minerals of the DaG martian meteorites indicate that closed‐system crystal fractionation from a LREE‐depleted parent magma dominated their crystallization history. Furthermore, rare earth element abundances in the orthopyroxene megacrysts are consistent with their origin as xenocrysts rather than phenocrysts.     

EFFECTIVE DISCHARGE CALCULATION GUIDE

1 mTRonvcnox: moareS Aun CoxcmSAJluvial rivers have the pOtenhal to adjust their shaPe and dimensions to all flows that tranSPOrtsediment, but Inglis (l94l) suggested that, for rivers that are in regime, a single steady flow could beidenhfied which would Produce the same bankfll dimensions as the natural sequence of events. Hereferrd to this now as the dondnan discharge.Wolman and Mller (l960) idenhfied that the flow doing most bed material transPort over a period ofyears may be taken tO…     

Effects of experimental warming on soil microbial communities in two contrasting subalpine forest ecosystems,eastern Tibetan Plateau,China

Soil microbial communities are primarily regulated by environmental temperature. Our study investigated the effects of global warming on soil microbial community composition as measured via phospholipid fatty acid (PLFA) analysis and soil chemical characteristics in relation to soil depth in a dragon spruce plantation and a spruce-fir-dominated natural forestin the Eastern Tibetan Plateau. Open-top chambers were utilized to increase the soil and air temperature. Soil samples were collected from the 0-10 cm, 10-20 cm, and 20-30 cm layers after a 4-year warming. Our results showed that the soil microbial community and the contents of TC (Total carbon), TN (Total nitrogen), NO ₃ ^- , and NH ₄ ⁺ responded differently to warming in the two contrasting forests, especially at the 0-10 cm soil depth. Warming increased soil microbial biomass at the 0-20 cm depth of soil in natural forest but reduced it at the 0-10 cm depth ofsoil in the plantation. In contrast, the TC and TN contents were reduced in most soil layers of a natural forest but increased in all of the soil layers of the plantation under warming conditions. This result suggested that the effects of warming on soil microbial community and soil C and N pools would differ according to soil depth and forest types; thus, the two contrasting forests would under go differing changes following the future climate warming in this region.     

Form, function and feedbacks in a tidally dominated ooid shoal, Bahamas

Although the general aspects of oolitic depositional systems are well documented, seascape‐scale (≈10³–10⁶ m²) patterns of oolitic shoals and the details of processes acting on them are not well understood or quantified. To begin to fill this basic gap in understanding, this paper describes the morphology and hydrodynamics of Lily Bank, a Modern tidally dominated Bahamian ooid shoal. In this study, integrating remote sensing imagery with quantitative, geo‐located bathymetrical, hydrological and granulometric data in a Geographic Information System documents geomorphic and sedimentological patterns and facilitates interpreting these patterns in the context of the processes operating in this system. The results of these analyses reveal that parabolic bars up to several kilometres in wavelength and several metres in height form a common morphologic motif, although there is considerable variation on that general theme. The seascape‐scale configuration of bars and superimposed sedimentary structures is closely linked to spatial patterns of tidal movements, and includes the presence of mutually evasive flood and ebb channels. Sedimentologically, bars are neither homogenous nor random bodies; instead, granulometric parameters such as sorting and percentage mud vary systematically, as shaped by hydro‐geomorphic controls. The best sorted, coarsest ooids are on bar crests, whereas the finest grains are found in the lower energy, deeper interior and flanking regions. In short, results clearly document hydrodynamic‐bathymetrical influences on these ooid shoals and their granulometry, linkages akin to siliciclastic analogues. Sedimentological, hydrodynamic and geomorphic observations are consistent with a conceptual model for the formation of parabolic bars in which initial irregularities in non‐parabolic bars are enhanced through their effect of focusing flow. Constricted flow leads to higher flow velocities, tidal flow velocity asymmetries, differential net sediment transport and growth of bathymetrical highs. This bathymetrical divergence creates separate paths for flood‐ and ebb‐tides, facilitating emergence of better‐developed parabolic forms. The resultant parabolic geometries and component bedforms appear to be either in dynamic equilibrium with both ebb‐ and flood‐tide flows, or evolving toward that state. In exploring patterns and processes within carbonate shoals, this study illustrates some of the first documented insights on quantitative details of morphology and dynamics and in the links between geomorphic framework and grain‐size and sorting in an oolitic carbonate system. Assuming a continuity of processes between ancient and modern, the insights from this shoal provide information on possible facies geometries and on the characteristics of grains and depositional porosity of analogous facies within ancient ooid shoals.     

A review of the LATEX project: mesoscale to submesoscale processes in a coastal environment

The main objective of the LAgrangian Transport EXperiment (LATEX) project was to study the influence of coastal mesoscale and submesoscale physical processes on circulation dynamics, cross-shelf exchanges, and biogeochemistry in the western continental shelf of the Gulf of Lion, Northwestern Mediterranean Sea. LATEX was a five-year multidisciplinary project based on the combined analysis of numerical model simulations and multi-platform field experiments. The model component included a ten-year realistic 3D numerical simulation, with a 1 km horizontal resolution over the gulf, nested in a coarser 3 km resolution model. The in situ component involved four cruises, including a large-scale multidisciplinary campaign with two research vessels in 2010. This review concentrates on the physics results of LATEX, addressing three main subjects: (1) the investigation of the mesoscale to submesoscale processes. The eddies are elliptic, baroclinic, and anticyclonic; the strong thermal and saline front is density compensated. Their generation processes are studied; (2) the development of sampling strategies for their direct observations. LATEX has implemented an adaptive strategy Lagrangian tool, with a reference software available on the web, to perform offshore campaigns in a Lagrangian framework; (3) the quantification of horizontal mixing and cross-shelf exchanges. Lateral diffusivity coefficients, calculated in various ways including a novel technique, are in the range classically encountered for their associated scales. Cross-shelf fluxes have been calculated, after retrieving the near-inertial oscillation contribution. Further perspectives are discussed, especially for the ongoing challenge of studying submesoscale features remotely and from in situ data.