The origin and evolution of mineralizing fluids in the Cretaceous Gyeongsang Basin, Southeastern Korea

Ferroalloy, base-metal and precious-metal deposits in or around the Gyeongsang Basin, which is located in the Cretaceous volcano-sedimentary terrain at the southeastern Korea, displays a genetic relationship with subvolcanic activities of Late Cretaceous to Tertiary age. Diverse mineralization, which occurs as vein, breccia-pipe, porphyry-style and skarn deposits, took place from 108 to 45 Ma that overlapped with polyphase episodes of igneous activity. Based on the mineralogy, host rock, fluid inclusion and stable isotope data of the deposits, the systematic variation of physicochemical conditions is thought to be due to their relative positions with respect to a magma source that is genetically related to a low to intermediate-sulfidation porphyry system. There appears to be a systematic decrease towards δ¹⁸O_H2O values from copper (-gold) and ferroalloy deposits through polymetallic to precious-metal ones. However, Cu (-Au) or Fe–Mo–W deposits are proximal to a magmatic source, whereas polymetallic or precious-metal deposits are more distal to transitional.     

Geospatial blending to improve spatial mapping of precipitation with high spatial resolution by merging satellite‐based and ground‐based data

Estimating accurate spatial distribution of precipitation is important for understanding the hydrologic cycle and various hydro‐environmental applications. Satellite‐based precipitation data have been widely used to measure the spatial distribution of precipitation over large extents, but an improvement in accuracy is still needed. In this study, three different merging techniques (Conditional Merging, Geographical Differential Analysis and Geographical Ratio Analysis) were used to merge precipitation estimations from Communication, Ocean and Meteorological Satellite (COMS) Rainfall Intensity data and ground‐based measurements. Merged products were evaluated with varying rain‐gauge network densities and accumulation times. The results confirmed that accuracy of detecting quantitative rainfall was improved as the accumulation time and network density increased. Also, the impact of spatial heterogeneity of precipitation on the merged estimates was investigated. Our merging techniques reproduced accurate spatial distribution of rainfall by adopting the advantages of both gauge and COMS estimates. The efficacy of the merging techniques was particularly pronounced when the spatial heterogeneity of hourly rainfall, quantified by variance of rainfall, was greater than 10 mm²/accumulation time². Among the techniques analysed, Conditional Merging performed the best, especially when the gauge density was low. This study demonstrates the utility of the COMS Rainfall Intensity product, which has a shorter latency time (1 h) and higher spatio‐temporal resolution (hourly, 4 km by 4 km) than other widely used satellite precipitation products in estimating precipitation using merging techniques with ground‐based point measurements. The outcome has important implications for various hydrologic modelling approaches, especially for producing near real‐time products. Copyright © 2016 John Wiley & Sons, Ltd.     

Identification of groundwater recharge sources and processes in a heterogeneous alluvial aquifer: results from multi‐level monitoring of hydrochemistry and environmental isotopes in a riverside agricultural area in Korea

We evaluated sources and pathways of groundwater recharge for a heterogeneous alluvial aquifer beneath an agricultural field, based on multi‐level monitoring of hydrochemistry and environmental isotopes of a riverside groundwater system at Buyeo, Korea. Two distinct groundwater zones were identified with depth: (1) a shallow oxic groundwater zone, characterized by elevated concentrations of NO₃^? and (2) a deeper (>10–14 m from the ground surface) sub‐oxic groundwater zone with high concentrations of dissolved Fe, silica, and HCO₃^?, but little nitrate. The change of redox zones occurred at a depth where the aquifer sediments change from an upper sandy stratum to a silty stratum with mud caps. The δ¹⁸O and δ²H values of groundwater were also different between the two zones. Hydrochemical and δ¹⁸O? δ²H data of oxic groundwater are similar to those of soil water. This illustrates that recharge of oxic groundwater mainly occurs through direct infiltration of rain and irrigation water in the sandy soil area where vegetable cropping with abundant fertilizer use is predominant. Oxic groundwater is therefore severely contaminated by agrochemical pollutants such as nitrate. In contrast, deeper sub‐oxic groundwater contains only small amounts of dissolved oxygen (DO) and NO₃^?. The ³H contents and elevated silica concentrations in sub‐oxic groundwater indicate a somewhat longer mean residence time of groundwater within this part of the aquifer. Sub‐oxic groundwater was also characterized by higher δ¹⁸O and δ²H values and lower d‐excess values, indicating significant evaporation during recharge. We suggest that recharge of sub‐oxic groundwater occurs in the areas of paddy rice fields where standing irrigation and rain water are affected by strong evaporation, and that reducing conditions develop during subsequent sub‐surface infiltration. This study illustrates the existence of two groundwater bodies with different recharge processes within an alluvial aquifer. Copyright © 2009 John Wiley & Sons, Ltd.     

Mid-Holocene tropical Pacific climate state,annual cycle,and ENSO in PMIP2 and PMIP3

Using the Paleoclimate Modeling Inter-comparison Project Phase 2 and 3 (PMIP2 and PMIP3), we investigated the tropical Pacific climate state, annual cycle, and El Niño-Southern Oscillation (ENSO) during the mid-Holocene period (6,000 years before present; 6 ka run). When the 6 ka run was compared to the control run (0 ka run), the reduced sea surface temperature (SST) and the reduced precipitation due to the basin-wide cooling, and the intensified cross-equatorial surface winds due to the hemispheric discrepancy of the surface cooling over the tropical Pacific were commonly observed in both the PMIP2 and PMIP3, but changes were more dominant in the PMIP3. The annual cycle of SST was weaker over the equatorial eastern Pacific, because of the orbital forcing change and the deepening mixed layer, while it was stronger over the equatorial western pacific in both the PMIP2 and PMIP3. The stronger annual cycle of the equatorial western Pacific SST was accompanied by the intensified annual cycle of the zonal surface wind, which dominated in the PMIP3 in particular. The ENSO activity in the 6 ka run was significantly suppressed in the PMIP2, but marginally reduced in the PMIP3. In general, the weakened air-sea coupling associated with basin-wide cooling, reduced precipitation, and a hemispheric contrast in the climate state led to the suppression of ENSO activity, and the weakening of the annual cycle over the tropical eastern Pacific might lead to the intensification of ENSO through the frequency entrainment. Therefore, the two opposite effects are slightly compensated for by each other, which results in a small reduction in the ENSO activity during the 6 ka in the PMIP3. On the whole, in PMIP2/PMIP3, the variability of canonical (or conventional) El Niño tends to be reduced during 6 ka, while that of CP/Modoki El Niño tends to be intensified.     

Assessing the ecosystem health status of Korea Gwangyang and Jinhae bays based on a planktonic index of biotic integrity (P-IBI)

To assess the responses of planktonic organisms to pollutants in the coastal ecosystems of Gwangyang and Jinhae bays in Korea, we investigated seasonal changes in various biological factors during the period from 2010 to 2012. Based on the characteristics of nutrient uptake by planktonic organisms under the coastal pollution conditions, we focused on four major parameters: total phytoplankton, harmful algal bloom (HAB) species, heterotrophic bacteria (HB) and Escherichia coli to develop a planktonic index of biotic integrity (P-IBI). The threshold values for abundances of total phytoplankton, HAB species and HB were based on the zero Z-score following normal distribution of the data for each parameter during the three years. Based on this approach, the threshold values were: 1.2 × 10⁶ cells L^?1 for total phytoplankton; 3.3 × 10⁴ cells L^?1 for HAB species; and 1.7 × 10⁶ cells mL^?1for HB. Five grade levels for the P-IBI were established, based on the zero Z-scores. The threshold value for E. coli not to be normalized was based on the USEPA and the Korean Ministry of Oceans and Fisheries guidelines. Validity of the grades and threshold values for each parameter established using the field data were tested by algal bioassays in a mesocosm enclosure, which supported the threshold values obtained in the field. In Gwangyang Bay, the annual integrated score for the P-IBI in 2010 was better than in the other years of the study. In Jinhae Bay, the P-IBI for the inner area of Masan Bay was Grade IV–V, indicating unhealthy conditions relative to the central and western outer areas, where the P-IBI varied from Grade II to III. The P-IBI values for Gwangyang and Jinhae bays were mostly rated as “Good (Grade II) or Fair (Grade III)”, except for a few stations in the semi-enclosed areas of the inner part of Jinhae Bay. From an overall view based on the P-IBI developed in this study, the coastal ecosystem health status in Gwangyang Bay was in a better condition than Jinhae Bay. The P-IBI indicated also a change to an unhealthy status during the rainy periods of spring and summer, whereas during winter and autumn the index indicated healthy conditions.     

Occurrence and accumulation features of polycyclic aromatic hydrocarbons and synthetic musk compounds in finless porpoises (Neophocaena phocaenoides) from Korean coastal waters

Reports of the occurrence and accumulation patterns of polycyclic aromatic hydrocarbons (PAHs) and synthetic musk compounds (SMCs) in marine mammals are scarce. In this study, the concentrations and accumulation profiles of PAHs and SMCs were determined in blubber from finless porpoises in Korean coastal waters. Total concentrations of PAHs and SMCs ranged from 6.0 to 432 (mean: 160) ng/g lipid weight and from 17 to 144 (mean: 52) ng/g lipid weight, respectively. Residue levels of PAHs were lower than those reported from other studies, while residue levels of SMCs were relatively higher than those reported in other studies. Naphthalene was the most abundant PAH and HHCB was the dominant SMC observed in finless porpoises. The concentrations of PAHs and SMCs were not correlated with each other, but were significantly correlated within the same chemical groups. No correlations were found between body size and residue levels of PAHs and SMCs.