Submarine groundwater discharge(SGD) has received increasing attention by studies on coastal areas; however,its effects on biogeochemical zonation have not been investigated to date. The Huanghe River Estuary(HRE) is a world class river estuary with high turbidity, and heavy human regulation. This study investigated how SGD is related to the benthic biogeochemistry of the HRE. Based on the distribution of several parameters(e.g., salinity,temperature, dissolved oxygen(DO) levels, p H, radium iso... 相似文献
Hydrogeology Journal - Fresh groundwater is a critical resource supporting coastal ecosystems that rely on low-salinity, nutrient-rich groundwater discharge. This resource, however, is subject to... 相似文献
We present the elemental and isotopic composition of noble gases in the bulk solar wind collected by the NASA Genesis sample return mission. He, Ne, and Ar were analyzed in diamond-like carbon on a silicon substrate (DOS) and 84,86Kr and 129,132Xe in silicon targets by UV laser ablation noble gas mass spectrometry. Solar wind noble gases are quantitatively retained in DOS and with exception of He also in Si as shown by a stepwise heating experiment on a flown DOS target and analyses on other bulk solar wind collector materials. Solar wind data presented here are absolutely calibrated and the error of the standard gas composition is included in stated uncertainties. The isotopic composition of the light noble gases in the bulk solar wind is as follows: 3He/4He: (4.64 ± 0.09) × 10−4, 20Ne/22Ne: 13.78 ± 0.03, 21Ne/22Ne: 0.0329 ± 0.0001, 36Ar/38Ar 5.47 ± 0.01. The elemental composition is: 4He/20Ne: 656 ± 5, and 20Ne/36Ar 42.1 ± 0.3. Genesis provided the first Kr and Xe data on the contemporary bulk solar wind. The preliminary isotope and elemental composition is: 86Kr/84Kr: 0.302 ± 0.003, 129Xe/132Xe: 1.05 ± 0.02, 36Ar/84Kr 2390 ± 150, and 84Kr/132Xe 9.5 ± 1.0. The 3He/4He and the 4He/20Ne ratios in the Genesis DOS target are the highest solar wind values measured in exposed natural and artificial targets. The isotopic composition of the other noble gases and the Kr/Xe ratio obtained in this work agree with data from lunar samples containing “young” (∼100 Ma) solar wind, indicating that solar wind composition has not changed within at least the last 100 Ma. Genesis could provide in many cases more precise data on solar wind composition than any previous experiment. Because of the controlled exposure conditions, Genesis data are also less prone to unrecognized systematic errors than, e.g., lunar sample analyses. The solar wind is the most authentic sample of the solar composition of noble gases, however, the derivation of solar noble gas abundances and isotopic composition using solar wind data requires a better understanding of fractionation processes acting upon solar wind formation. 相似文献
Clinopyroxene-silicate liquid partition coefficients for U and Th have been determined by particle track radiography from 1 atm crystallization experiments at controlledfO2. Two natural basaltic and one synthetic composition were studied atfO2 values from the NiNiO oxygen buffer to 1 log unit more oxidizing than FeFeO (IW+ 1). Over the range offO2 values and compositions studied,DUcpx/liq = 0.0034–0.015,DThcpx/liq = 0.008–0.036, andDThDU= 3.4–1.1. With decreasingfO2,DThDU can decrease by up to a factor of 3 for a given composition, primarily from an increase inDUcpx/liq, which we interpret as resulting from an increase in the proportion of tetravalent U in the system with decreasingfO2. This demonstrates that crystal-liquid UTh fractionation isfO2 dependent and that U in terrestrial magmas is not entirely tetravalent.DThcpx/liq appears to decrease in the two basalts at the lowestfO2, possibly as a result of changes in composition withfO2.
Our data show the sense of UTh fractionation by clinopyroxene-liquid partitioning is consistent with previous experimental determinations, in thatDThcpxDUcpx> 1 in all cases. This indicates that, during partial melting, the liquid will have aTh/U ratio less than the clinopyroxene in the source. The observed238U230Th disequilibrium in MORB requires that the partial melt should have aTh/U ratio greater than the bulk source, and, therefore, cannot result from clinopyroxene-liquid partitioning. Further, the magnitudes of the measured partition coefficients are too small to generate significant UTh fractionation in either direction. Assuming that clinopyroxene contains the bulk of the U and Th in MORB source, our results indicate that238U230Th disequilibrium in MORB may not be caused by partial melting at all. 相似文献
The development of location-aware technologies, such as smartphones, raises serious questions regarding locational privacy and the ethical use of geographic data. The degree to which these concepts are taught in undergraduate geographic information science (GISci) courses is unknown. A survey of GISci educators shows that issues of privacy and ethics are important in a GISci education. However, a large proportion of GISci educators are not concerned about the loss of locational privacy and many do not devote classes to the subject. Those not teaching the subject cite lack of course time and the need for more information. 相似文献
In an effort to elucidate the mechanism of formation and accretion of ferromanganese nodules, transverse sections of undisturbed botryoid surfaces of nodules from the abyssal central North Pacific were examined by X-ray analyses both by multiple replicate sample transects and mapping. Surface concentrations of Mn and Fe were found of the size and shape of microorganisms. Abundant microorganism-like objects covering the surface and the apparent absence of Si (i.e. no sediment) with the Mn and Fe concentrations suggests microorganisms may be involved either in the selective accretion or removal of these metals. If metal accretion was simply physicochemical, one would expect a more or less even distribution of Mn and Fe on the botryoid surfaces.The replicate X-ray sample transects showed that Mn and Fe have a distribution corresponding to botryoid zonation. Areas of high Mn X-ray intensity were found associated with the cap and equatorial zones of the botryoid. Most of the valley zone of the botryoid show a more or less even Mn distribution and an increase in Fe X-ray intensity. At the base of the botryoid both metals apparently precipitously decrease. 相似文献