Fluid regimes in the deformation of the Helvetic nappes,Switzerland, as inferred from stable isotope data

The stable isotope composition of veins, pressure shadows, mylonites and fault breccias in allochthonous Mesozoic carbonate cover units of the Helvetic zone show evidence for concurrent closed and open system of fluid advection at different scales in the tectonic development of the Swiss Alps. Marine carbonates are isotopically uniform, independent of metamorphic grade, where ¹³C=1.5±1.5 (1 ) and ¹⁸O=25.4±2.2 (1 ). Total variations of up to 2 in ¹³C and 1.5 in ¹⁸O occur over a cm scale. Calcite in pre- (Type I) and syntectonic (Type II) vein arrays and pressure shadows are mostly in close isotopic compliance with the matrix calcite, to within ±0.5, signifying isotopic buffering of pore fluids by host rocks during deformation, and closed system redistribution of carbonate over a cm to m scale. This is consistent with microstructural evidence for pressure solution — precipitation deformation.Type III post-tectonic veins occur throughout 5 km of structural section, extend several km to the basement, and accommodate up to 15% extension. Whereas the main population of Type III veins is isotopically undistinguishable from matrix carbonates, calcite in the largest of these veins is depleted in ¹⁸O by up to 23 but acquired comparable ¹³C values. This generation of veins involved geopressurized hydrothermal fluids at 200 to 350° C where ¹⁸O H₂O=–8 to +20, representing variable mixtures of ¹⁸O enriched pore and metamorphic fluids, with ¹⁸O depleted meteoric water. Calc-mylonites ( ¹⁸O=25 to 11) at the base of the Helvetic units, and syntectonic veins from the frontal Pennine thrust are characterized by a trend of ¹⁸O depletion relative to carbonate protoliths, due to exchange with an isotopically variable reservoir ( ¹⁸O H₂O=20 to 4). The upper limiting value corresponds to carbonate-buffered pore fluid, whereas the lower value is interpreted as ¹⁸O-depleted formation brines tectonically expelled at lithostatic pressure from the crystalline basement. Carbonate breccias in one of the large scale late normal faults exchanged with infiltrating ¹⁸O-depleted meteoric surface waters ( ¹⁸O=–8 to –10).During the main ductile Alpine deformation, individual lithological units and associated tectonic vein arrays behaved as closed systems, whereas mylonites along thrust faults acted as conduits for tectonically expelled lithostatically pressured reservoirs driven over tens of km. At the latest stages, marked by 5 to 15 km uplift and brittle deformation, low ¹⁸O meteoric surface waters penetrated to depths of several km under hydrostatic gradients.     

Field-aligned currents between 400 and 3000 km in auroral and polar latitudes

The polar orbiting magnetically stabilized satellite AZUR measured transverse magnetic variations in auroral and polar latitudes by means of a two component flux-gate magnetometer. Simultaneous measurements of $\text{λ2972}\text{A}\text{?}$ and $\text{λ3914}\text{A}\text{?}$ auroral emissions are related to low-energy zero-pitch-angle electron fluxes, which cause the transverse magnetic disturbances. Power spectra of the magnetic field variations are consistent with those of geomagnetic micropulsations.The sources of the field-aligned currents can be located in the Alfvén layer and in the magnetotail.     

Dépliage 3-D des anticlinaux bordant le synclinal fermé de la vallée des Ponts, Jura central, Suisse

The Ponts valley syncline is a closed basin within the Neuchâtel Jura fold and thrust belt. This syncline, apparently uplifted to an altitude of around 1000m is closed in the SW by an anticline with an oblique WNW-ESE direction. The 3-D geometry of the entire structure is examined and unfolded in detail. This syncline is filled with an unexpectedly thick series (~400m) of Tertiairy Molasse, as revealed by the CS-AMT (controlled source audio-magneto-telluric) and a reflexion seismic line. The latter also documents internal compressional structures within the well layered upper freshwater Molasse series. The 3-D configuration of the top Malm limestones has been constructed for the entire area based on new detailed geologic and structural mapping, hundreds of dip measurements, as well as geophysical data. The Malm marker bed displays three distinct types of structures: 1) Thrust faults with shallow dips, vergent to the NW and/or SE that are associated with folds interpreted as fault bend folds; 2) high angle inverse faults, mostly with a SE vergence are interpreted as inverted normal faults, inherited from a modest Oligo-Miocene extensional phase in a NW-SE direction; and 3) tear faults with a dominant N-S direction, probably inherited from an Oligocene extensional phase in association with the opening of the Rhine and Bresse grabens. Tear faults accommodate important lateral changes in fold geometry during the Late Miocene main folding-and-thrusting phase. All deformations are easily explained in an entirely thin-skinned fashion, taking place above a thick detachment horizon within Triassic evaporite series.Manuscrit reçu le 31 mars 2003 Révision acceptée le 23 juin 2004     

Effect of boron on the water speciation in (alumino)silicate melts and glasses

The investigation of hydrous boro(alumino)silicate melts and glasses with near infrared (NIR) spectroscopy revealed an important effect of boron on the water speciation. In the NIR spectra of B-bearing glasses new hydroxyl-related bands develop at the high frequency side of the 4500 cm⁻¹ peak. In NaAlSi₃O₈ + B₂O₃ glasses this new peak is present as a shoulder at 4650 cm⁻¹, and in NaAlSi₃O₈-NaBSi₃O₈ (Ab-Rd) glasses it appears as a resolved peak at 4710 cm⁻¹. These bands increase with increasing boron concentration, suggesting that they are due to B-OH complexes. Furthermore, the variations in the NIR spectra indicate that with increasing B-content, but constant total water concentration, the amount of structurally bonded hydroxyl groups increases at the expense of molecular H₂O. For example, at a total water concentration of 4 wt.%, pure Rd-glass contains ∼50% more water as hydroxyl groups than pure Ab-glass.In-situ NIR spectroscopy at high P and T using a hydrothermal diamond-anvil cell was used to gain information about the temperature dependence of the water speciation in NaBSi₃O₈ melts. The data demonstrate the conversion of molecular H₂O to hydroxyl groups with increasing temperature. However, a fully quantitative evaluation of the high T spectra was hampered by problems with defining the correct baseline in the spectra. As an alternative approach annealing experiments on a Rd-glass containing 2.8 wt.% water were performed. The results confirm the conversion of H₂O to OH groups with increasing T, but also suggest that the OH groups represented by the 4710 cm⁻¹ peak (B-OH) participate much less in the conversion reaction compared to X-OH, represented by the 4500 cm⁻¹ peak.     

Towards a Higher Comparability of Geothermometric Data Obtained by Raman Spectroscopy of Carbonaceous Material. Part 2: A Revised Geothermometer

The estimation of the peak metamorphic temperature by Raman spectroscopy of carbonaceous material (RSCM) is influenced by several bias sources grouped in measuring conditions, spectral processing and sample heterogeneity. The measuring conditions (selected excitation wavelength) and the operator bias during spectral processing have a pronounced impact on the temperature estimate and thus on the comparability and portability of thermometric data obtained by RSCM. Several calibration lines of RSCM geothermometers are published already, but no standardised approach exists. Samples of carbonaceous material bearing metasediments with well‐established metamorphic conditions of the central and western Alps compile a reference series. By applying an automated, iterative and randomised curve‐fitting approach, a consistent and user input‐independent RSCM geothermometer is presented, which covers peak metamorphic temperatures from ca. 160 to 600 °C. The method is hardware independent because the measuring conditions bias is excluded by the use of the reference series and the automated curve‐fitting approach reduces the spectral processing bias effectively, increasing the method's comparability and portability. By distributing the reference series and the automated curve‐fitting software, a laboratory will be able to derive a laboratory specific calibration line for the RSCM geothermometer.     

Water solubility in haplogranitic melts coexisting with H2O-H2 fluids

The water solubility in haplogranitic melts (normative composition Ab₃₉Or₃₂Qz₂₉) coexisting with H₂O-H₂ fluids at 800 and 950 °C and 1, 2 and 3 kbar vapour pressure has been determined using IR spectroscopy. The experiments were performed in internally heated pressure vessels and the hydrogen fugacity (f _H2) was controlled using the double capsule technique and oxygen buffer assemblages (WM and IW). Due to the limited lifetimes of these oxygen buffers the water solubility was determined from diffusion profiles (concentration-distance profiles) measured with IR spectroscopy in the quenched glasses. The reliability of the experimental strategy was demonstrated by comparing the results of short- and long-duration experiments performed with pure H₂O fluids. The water solubility in Ab₃₉Or₃₂Qz₂₉ melts equilibrated with H₂O-H₂ fluids decreases progressively with decreasing f _H2O, as f _H2 (or X _H2) increases in the fluid phase. The effect of H₂ on the evolution of the water solubility is similar to that of CO₂ or another volatile with a low solubility in the melt and can be calculated in a first approximation with the Burnham water solubility model. Recalculation of high temperature water speciation for AOQ melts coexisting with H₂O-H₂ fluids at 800 °C, 2 kbar suggests that the concentrations of molecular H₂O are proportional to f _H2O (calculated using available mixing models), indicating Henrian behaviour for the solubility of molecular H₂O in haplogranitic melts. Received: 29 June 1998 / Accepted: 10 March 1999     

Methanogenesis in the sediment of the acidic Lake Caviahue in Argentina

The biogeochemistry of methane in the sediments of Lake Caviahue was examined by geochemical analysis, microbial activity assays and isotopic analysis. The pH in the water column was 2.6 and increased up to a pH of 6 in the deeper sediment pore waters. The carbon isotope composition of CH₄ was between − 65 and − 70‰ which is indicative for the biological origin of the methane. The enrichment factor ε increased from − 46‰ in the upper sediment column to more than − 80 in the deeper sediment section suggesting a transition from acetoclastic methanogenesis to CO₂ reduction with depth. In the most acidic surface layer of the sediment (pH < 4) methanogenesis is inhibited as suggested by a linear CH₄ concentration profile, activity assays and MPN analysis. The CH₄ activity assays and the CH₄ profile indicate that methanogenesis in the sediment of Lake Caviahue was active below 40 cm depth. At that depth the pH was above 4 and sulfate reduction was sulfate limited. Methane was diffusing with a flux of 0.9 mmol m^− 2 d^− 1 to the sediment surface where it was probably oxidized. Methanogenesis contributed little to the sediments carbon budget and had no significant impact on lake water quality. The high biomass content of the sediment, which was probably caused by the last eruption of Copahue Volcano, supported high rates of sulfate reduction which probably raised the pH and created favorable conditions for methanogens in deeper sediment layers.     

Reservoirs as sentinels of catchments: the Rappbode Reservoir Observatory (Harz Mountains, Germany)

Reservoirs can be viewed as sentinels of their catchments and a detailed monitoring of reservoir systems informs about biogeochemical and hydrological processes at the catchment scale. We developed a comprehensive online monitoring system at Rappbode reservoir, the largest drinking water reservoir in Germany, and its inflows. The Rappbode Reservoir Observatory comprises of a set of online-sensors for the measurement of physical, chemical, and biological variables and is complemented by a biweekly limnological sampling schedule. Measurement stations are deployed at the four major inflows into the system, at the outlets of all pre-reservoirs, as well as in the main reservoir. The newly installed monitoring system serves both scientific monitoring and process studies, as well as reservoir management. Particular emphasis is paid to the monitoring of short-term dynamics and many variables are measured at high temporal resolution. As an example, we quantitatively documented a flood event which mobilised high loads of dissolved organic carbon and changed the characteristics of the receiving reservoir from eutrophic to dystrophic within a few days. This event could have been completely missed by conventional biweekly sampling programs, but is relevant for biogeochemical fluxes at the catchment scale. We also show that the high frequency data provide a deeper insight into ecosystem dynamics and lake metabolism. The Rappbode Reservoir Observatory; moreover, offers a unique study site to apply, validate, and develop state of the art lake models to improve their predictive capabilities.     

Extensional neotectonics around the bend of the Western/Central Alps: an overview

The Western Alps’ active tectonics is characterized by ongoing widespread extension in the highest parts of the belt and transpressive/compressive tectonics along its borders. We examine these contrasting tectonic regimes using a multidisciplinary approach including seismotectonics, numerical modeling, GPS, morphotectonics, fieldwork, and brittle deformation analysis. Extension appears to be the dominant process in the present-day tectonic activity in the Western Alps, affecting its internal areas all along the arc. Shortening, in contrast, is limited to small areas located along at the outer borders of the chain. Strike-slip is observed throughout the Alpine realm and in the foreland. The stress-orientation pattern is radial for σ3 in the inner, extensional zones, and for σ1 in the outer, transcurrent/tranpressional ones. Extensional areas can be correlated with the parts of the belt with the thickest crust. Quantification of seismic strain in tectonically homogeneous areas shows that only 10–20% of the geodesy-documented deformation can be explained by the Alpine seismicity. We propose that, Alpine active tectonics are ruled by isostasy/buoyancy forces rather than the ongoing shortening along the Alpine Europe/Adria collision zone. This interpretation is corroborated by numerical modeling. The Neogene extensional structures in the Alps formed under increasingly brittle conditions. A synthesis of paleostress tensors for the internal parts of the West-Alpine Arc documents major orogen-parallel extension with a continuous change in σ3 directions from ENE–WSW in the Simplon area, to N–S in the Vanoise area and to NNW–SSE in the Briançon area. Minor orogen-perpendicular extension increases from N to S. This second signal correlates with the present-day geodynamics as revealed by focal-plane mechanisms analysis. The orogen-parallel extension could be related to the opening of the Ligurian Sea during the Early-Middle Miocene and to compression/rotation of the Adriatic indenter inducing lateral extrusion.