TheROSAT survey of extreme UV sources: a new window on the universe

This paper discusses the first all-sky suvey of cosmic extreme ultra-violet sources, discovered by theROSAT Wide Field Camera. Details of the instrument and the survey are presented, with comparisons made to previous selected surveys in the X-ray regime. The subsequent optical identification program is described, and the major results summarized. I then discuss the main classes of EUV emitters: active chromosphere stars and hot white dwarfs, and describe the importance of EUV obserevations in understanding the astrophysics of these objects. Many bright, and relatively nearby, sources have been identified with hitherto unrecognized active stars, representing the extremes in chromospheric and coronal activity, be it binary or age related. Many new hot DA white dwarfs have also been indentified, and the most exciting result in this area is the discovery that significant traces of heavier elements (e.g. C, N, O, Si, Fe & Al) exist in their atmospheres, substantially increasing their EUV opacities. The importance of hot white dwarfs as standard candles in probing the local interstellar medium is also discussed. Miscellaneous counterparts (AGN, PNN, O-B stars and CVs) that make up the rest of the sample of EUV sources are also briefly mentioned. I conclude the paper with a discussion of the new magnetic cataclysmic variables discovered at SAAO, which have been the subject of intensive follow-up observations.     

Surface chemical analysis in coal preparation research: complementary information from XPS and ToF-SIMS

The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface.     

Ion exchange reactions of KNiAsO4

The mica-like layer compound KNiAsO₄ easily exchanges its interlayer potassium ions for alkyl ammonium ions, RNH ₃ ⁺ (R=CH₃ - C₁₈H₃₇). Short chain ions (<>₄) will react in aqueous solution and longer chains in ethanolic solution. The reaction of KNiAsO₄ with aqueous solutions of methyl, ethyl and butyl ammonium chlorides of different concentrations has been investigated using a potassium ionselective electrode. Room temperature kinetic curves of percent exchange vs time were obtained. These indicate an apparent cooperative mechanism with some rearrangement of the alkyl ammonium ions between the layers during the reaction. KNiAsO₄ also reacts with water. This reaction may facilitate the exchange reaction with aqueous alkyl ammonium ions. The alkyl ammonium ions form ordered arrangements between the [NiAsO₄]^– layers. Small chains (<>₄) adopt a variety of configurations within the same product.Paper from the NATO Advanced Study Institute on Physical Properties and Thermodynamic Behaviour of Minerals, Cambridge 1987     

Zoning in garnets—Diffusion models

When reference frames and diffusing components are properly selected, the flux equations for diffusion of the major components in natural garnets may often be approximated by: J DC. In such cases it is shown that, for reasonable diffusion coefficients and boundary conditions, observed zoning profiles in natural garnets may be explained with pure diffusion models. These models allow for original inhomogeneities in the host rock and may be used to explain why single hand specimens may show such a variety of zoning profiles within a single mineral species.     

Petrology and geochemistry of Easter Island

Easter Island has developed around three volcanoes—Poike, an older (3 m.y.) strato-volcano, Rano Kau, a caldera, and the fissure complex of Terevaka and its associated cones. The lavas show a wide compositional spread from tholeiites and olivine tholeiites to hawaiites, mugearites, benmoreites, trachytes and rhyolites (comendites). Hawaiite is by far the most abundant rock type and trachytes and rhyolites are relatively rare. Intermediate and acid rocks are concentrated in the southwestern part of the island on or around Rano Kau.The basaltic rocks, which are plagioclase-phyric or aphyric, are transitional hypersthenenormative types characterized by high contents of Fe, Ti and Zr but low K and Mg. The Poike basalts are marginally lower in Zr, Nb, Y and Zn compared with those of the younger volcanoes, but the trachytes from this centre show anomalously high concentrations of Rb, Zr and Nb.The island's youngest flow, the Roiho basalt, is an olivine tholeiite with distinctly more alkaline affinities: it is olivine-microphyric with relatively high contents of Mg, Ni and K.The study was initiated whilst this author was at Department of Geology and Mineralogy, University of Oxford.     

Residual currents in juan de Fuca strait

Abstract

We examine the residual (non‐tidal) flow in Juan de Fuca Strait on the west coast of Canada using current and bottom pressure data collected on cross‐channel sections in the summers of 1975 and 1984. A positive estuarine circulation was evident in both sections but was better defined at the mid‐strait section than at the outer section near the mouth of the strait. Magnitudes of the volume transports in both the upper and lower layers of the channel ranged from ～ 0.25 X 10 m s at the mid‐strait section to ～ 0.15 X 10 m s～ at the outer section. The method of geostrophic levelling (Garrett and Pétrie, 1981; Pétrie et al, 1988) is used to determine the relationship between the daily averaged long‐strait velocity component and the cross‐strait pressure difference. A statistically significant relationship, consistent with a cross‐strait geostrophic balance, is obtained between the time series of shallow currents and shallow bottom pressures at the mid‐strait section. The deep currents and cross‐strait pressure differences were correlated at both sections but, because of the placement of the pressure gauges and/or ageostrophic effects such as bottom friction, were not related through a simple geostrophic balance. Cross‐spectral analysis and the calculation of the current amplitude ratios (square root of the energy ratio between the deep and shallow currents) are used to examine the baroclinicity of the flow as a function of frequency. Results suggest that flow variability in Juan de Fuca Strait is strongly baroclinic and has marked cross‐channel structure throughout the low‐frequency band.     

Optical follow-up of new Small Magellanic Cloud wing Be/X-ray binaries

We investigate the optical counterparts of recently discovered Be/X-ray binaries in the Small Magellanic Cloud (SMC). In total four sources, SXP101, SXP700, SXP348 and SXP65.8 were detected during the Chandra survey of the wing of the SMC. SXP700 and SXP65.8 were previously unknown. Many optical ground-based telescopes have been utilized in the optical follow-up, providing coverage in both the red and blue bands. This has led to the classification of all of the counterparts as Be stars and confirms that three lie within the Galactic spectral distribution of known Be/X-ray binaries. SXP101 lies outside this distribution and is the latest spectral type known. Monitoring of the Hα emission line suggests that all the sources barring SXP700 have highly variable circumstellar discs, possibly a result of their comparatively short orbital periods. Phase-resolved X-ray spectroscopy has also been performed on SXP65.8, revealing that the emission is indeed harder during the passage of the X-ray beam through the line of sight.