Mineralogic variability of the uppermost mantle along mid-ocean ridges

Modal analyses of 273 different peridotites representing 43 dredge stations in the Atlantic, Caribbean, and Indian Oceans define three separate melting trends. Peridotites dredged in the vicinity of “mantle plumes” or hot spots have the most depleted compositions in terms of basaltic components, while peridotites dredged at locations removed from such regions are systematically less depleted. The modal data correlate well with mineral compositions, with the peridotites most depleted in pyroxene also having the most refractory mineral compositions. This demonstrates that they are the probable residues of variable degrees of mantle melting. Further, there is a good correlation between the modal compositions of the peridotites and the major element composition of spatially associated dredged basalts. This demonstrates for the first time that the two must be directly related, as is frequently postulated. The high degree of depletion of the peridotites in basaltic major element components in the vicinity of some documented mantle plumes provides direct evidence for a thermal anomaly in such regions—justifying their frequent designation as “hot spots”. The high incompatible element concentrations in these “plume” basalts, however, are contrary to what is expected for such high degrees of melting, and thus require either selective contributions from locally more abundant enriched veins and/or contamination by a volatile-rich metasomatic front from depth.     

Rapid responses of the prairie-forest ecotone to early Holocene aridity in mid-continental North America

The prairie-forest transition in midcontinental North America is a major physiognomic boundary, and its shifts during the Holocene are a classic example of climate-driven ecotonal dynamics. Recent work suggests asymmetrical Holocene behavior, with a relatively rapid early Holocene deforestation and more gradual reforestation later in the Holocene. This paper presents a new synthesis of the Holocene history of the Great Plains prairie-forest ecotone in the north-central US and central Canada that updates prior mapping efforts and systematically assesses rates of change. Changes in percent woody cover (%WC) are inferred from fossil pollen records, using the modern analog technique and surface-sediment pollen samples cross-referenced against remotely sensed observations. For contemporary pollen samples from the Great Plains, %WC linearly correlates to percent arboreal pollen (%AP), but regression parameters vary interregionally. At present, %AP is consistently higher than %WC, because of high background levels of arboreal pollen. Holocene maps of the eastern prairie-forest ecotone agree with prior maps, showing a rapid decrease in %WC and eastward prairie advance between 10,000 and 8000 ka (1 ka = 1000 calibrated years before present), a maximum eastward position of the ecotone from 7 to 6 ka, and increased %WC and westward prairie retreat after 6 ka. Ecotone position is ambiguous in Iowa and southeastern Minnesota, due to a scarcity of modern analogs for early-Holocene samples with high Ulmus abundances and for samples from alluvial sediments. The northern prairie-forest ecotone was positioned in central Saskatchewan between 12 and 10 ka, stabilized from 10 to 6 ka despite decreases in %WC at some sites, then moved south after 6 ka. In both east and north, ecotonal movements are consistent with a dry early Holocene and increasing moisture availability after 6 ka. Sites near the ecotone consistently show an asymmetric pattern of abrupt early Holocene deforestation (< 300 years) and gradual reforestation after 6 ka. Early Holocene decreases in %WC are faster than the corresponding drops in %AP, because the analog-based %WC reconstructions correct for the high background levels of arboreal pollen types that blur temporal variations in %AP. For example, at Elk Lake, the %AP decline lasts 1000 years, whereas the %WC decline occurs between adjacent pollen samples, approximately 300 years apart. Thus, early Holocene deforestation may have been even more abrupt than previously recognized. Rapid deforestation likely was promoted both by rapid climate changes around 8.2 ka and positive fire-vegetation feedbacks. Non-linear vegetational responses to hydrological variability are consistent with 1) other paleorecords showing rapid die-offs of some eastern tree species in response to aridity and 2) observations of threshold-type ecological responses to recent climate events. The 21st-century trajectory for the Great Plains prairie-forest ecotone is uncertain, because climate models differ over the direction of regional precipitation trends, but future drying would be more likely to trigger threshold-type shifts in ecotone position.     

Vertical and lateral organization of a carbonate deep-water slope marginal to a submarine fan system, Miocene, southern Turkey

Organization is recognized in the forereef–deep water slope–submarine fan system of the Burdigalian-Langhian Kaplankaya Formation. A basinwards transition from a prograding shelfal reef complex, through forereef talus, deep-water slope and laterally encroaching bypass deep-water clastic system is described, although the deep-water slope makes up the bulk of the succession. Considerable thickness variations occur between the reef and deep-water clastic complexes; these are controlled by sea-floor topography, carbonate foreslope gradient and degree of mass wasting off the platform and foreslope. The vertical and lateral heterogeneity of the Kaplankaya deep-water slope system is described from a number of localities along a 40-km-long and up to 3-km-wide exposed section of the northern margin of the Miocene Adana Basin, a foreland basin setting resulting from thrust sheet loading from the north during the Tauride Orogeny. Detailed field mapping is supplemented with vertical sedimentary logs, photomosaics, palaeontological and petrological data to investigate stratal variation, diagnostic architectural elements, controls on slope progradation, differential timing of basinward encroachment of the reefal complex and lateral onlap of the deep-water clastic system onto the slope. Three-dimensional models are presented showing the vertical and lateral facies associations in different parts of the deep-water slope system, and provide a basis for architectural prediction of geometry and relative position in such environments.     

The Cainozoic geology of the Middle Shoalhaven Plain

The Middle Shoalhaven Plain is a large, tray‐like depression bounded in the west by the Mulwaree fault and in the east by cliffed Permian sediments. The plain is probably Mesozoic in origin and was partially alluviated during the Early to mid‐Eocene. Much of the plain and sediments were covered by basalts during the Late Eocene. This was followed by an episode of deep weathering, which culminated in the formation of widespread bauxitic and lateritic crusts and manganocrete and silcrete during the mid‐Tertiary. A second minor weathering event is recorded during the latest Tertiary to Early Pleistocene. Two new basalt dates are consistent with earlier ones at about 43 Ma. Palaeomagnetism shows bauxites and ferricretes to be mid‐Tertiary.     

Al(III) and Fe(III) binding by humic substances in freshwaters, and implications for trace metal speciation

Published experimental data for Al(III) and Fe(III) binding by fulvic and humic acids can be explained approximately by the Humic Ion-Binding Model VI. The model is based on conventional equilibrium reactions involving protons, metal aquo ions and their first hydrolysis products, and binding sites ranging from abundant ones of low affinity, to rare ones of high affinity, common to all metals. The model can also account for laboratory competition data involving Al(III), Fe(III) and trace elements, supporting the assumption of common binding sites. Field speciation data (116 examples) for Al in acid-to-neutral waters can be accounted for, assuming that 60-70 % (depending upon competition by iron, and the chosen fulvic acid : humic acid ratio) of the dissolved organic carbon (DOC) is due to humic substances, the rest being considered inert with respect to ion binding. After adjustment of the model parameter characterizing binding affinity within acceptable limits, and with the assumption of equilibrium with a relatively soluble form of Fe(OH)₃, the model can simulate the results of studies of two freshwater samples, in which concentrations of organically complexed Fe were estimated by kinetic analysis.The model was used to examine the pH dependence of Al and Fe binding by dissolved organic matter (DOM) in freshwaters, by simulating the titration with Ca(OH)₂ of an initially acid solution, in equilibrium with solid-phase Al(OH)₃ and Fe(OH)₃. For the conditions considered, Al, which is present at higher free concentrations than Fe(III), competes significantly for the binding of Fe(III), whereas Fe(III) has little effect on Al binding. The principal form of Al simulated to be bound at low pH is Al³⁺, AlOH²⁺ being dominant at pH >6; the principal bound form of Fe(III) is FeOH²⁺ at all pH values in the range 4-9. Simulations suggest that, in freshwaters, both Al and Fe(III) compete significantly with trace metals (Cu, Zn) for binding by natural organic matter over a wide pH range (4-9). The competition effects are especially strong for a high-affinity trace metal such as Cu, present at low total concentrations (∼1 nM). As a result of these competition effects, high-affinity sites in humic matter may be less important for trace metal binding in the field than they are in laboratory systems involving humic matter that has been treated to remove associated metals.     

A contribution to Pleistocene chronology in southeast Essex,England

Parallel to the Essex coast north of the mouth of the Thames, a series of gravel spreads ranging in altitude from near sea level westward to more than 200 ft O.D. (mean sea level) proved to be the remnants of an abandoned Thames/Medway terrace system, rather than a series of “raised” beaches, as their location had suggested. The seaward side of the ancient river valley has subsequently been “captured” by subsidence.Evidence is given for five terraces, with surface levels between 5 and 75 ft O.D. Because of subsidence of the Essex coast, the terrace levels are not easily correlatable with either the Thames or Medway terrace levels. Temporal placement is attempted on the basis of one site in the 25 ft Barling terrace, which yielded a Middle Acheulian archaeological assemblage associated with a cool temperate fauna including an early form of mammoth. An ice wedge cast in the Barling terrace was filled with floodloam which weathered to a parabraunerde soil during an interglacial climate warmer than now. For these reasons man is thought to have lived on the floodplain of the Barling terrace either at the onset of the Wolstonian (Riss) glacial or during an interstadial of that stage. The question of possible linkages between Swanscombe and Clacton terraces is discussed.     

内蒙锡林浩特晚石炭世辉长质岩体的成因:陆内伸展背景下富水地幔源区熔融的产物

内蒙中部晚石炭世岩浆活动的成因及动力学背景对于揭示古亚洲洋俯冲和兴蒙造山带演化的具有重要意义。本文选取锡林浩特南部晚石炭世辉长质侵入体为研究对象,开展高精度SIMS锆石U-Pb定年、全岩主微量和Sr-Nd-Hf同位素分析,旨在讨论其岩石成因,为制约兴蒙造山带的演化和理解深部流体循环过程提供更多信息。辉长质岩体样品的锆石CL图像呈弱环状结构、条带状或岩浆生长带(Th/U=0. 3～2. 5)。SIMS锆石U-Pb定年结果表明,锡林浩特辉长质岩体的侵位年龄为316. 9±2. 2Ma,为兴蒙造山带晚石炭世区域性岩浆活动的产物。该岩体经历了橄榄石和单斜辉石的分离结晶作用,但受堆晶作用和地壳物质混染作用的影响较小;同时具有较低的87Sr/86Sr初始比值(0. 7034～0. 7041),但相对高的εNd(t)(+5. 58～+6. 88)和εHf(t)值(+12. 07～+13. 44),并显示Rb、Sr、U和Pb等流体活动性元素相对富集,但Nb和Ta等非流体活动性元素相对亏损的特征,暗示其起源于遭受含水流体交代富集的地幔源区。流体交代富集作用很可能发生在源区部分熔融过程中或者在部分熔融之前较短的时间内,即反映较为年轻的交代事件。锡林浩特辉长闪长岩具有相对较高的Si O_2(51. 7%～53. 2%)、Cr (138. 4×10~(-6)～757. 2×10~(-6))和Ni (50. 4×10-6～141. 1×10~(-6))含量以及Zn/Fe比值(10. 8～11. 5),但相对较低的Al2O3(13. 1%～16. 8%)含量,暗示源区可能富含斜方辉石,由橄榄岩+辉石岩脉组成。通过对比总结兴蒙造山带晚石炭世岩浆岩岩石组合的地球化学特征以及其他地质资料,本文认为古亚洲洋在晚石炭世之前已经闭合,而锡林浩特辉长质岩体形成于陆内伸展的构造背景。结合同期玄武岩母岩浆的高含水量特征(高达4. 41%),本文认为锡林浩特及其邻区晚石炭世岩浆活动是遭受地幔转换带滞留俯冲板块析出富水流体交代的地幔源区部分熔融的产物,从而建立了深部流体循环过程与造山后伸展背景下岩浆活动的成因联系。     

Apparent conflicting Roadian–Wordian (middle Permian) CA-IDTIMS and palynology ages from the Canning Basin,Western Australia

U–Pb dating of zircons from thin middle Permian tuffs in the Canning Basin of Western Australia by chemical abrasion-isotope dilution thermal ionisation mass spectrometry reveals a conflict with the established spore-pollen zonation. Normally, the first appearance datum of Dulhuntyispora granulata across the continent lies stratigraphically above assemblages assigned to the Microbaculispora villosa Zone. However, the youngest tuffs within non-marine facies from the M. villosa Zone in Pittston SD-1, drilled in the southwest of the Canning Basin, yielded an age of 267.04 ± 0.14 Ma, which is 1.7 million years younger than tuffs associated with the D. granulata Zone in marginal-marine facies from core holes 350–400 km to the northeast. The apparent conflict in ages is possibly due to the non-marine depositional environment having wielded a strong local influence on the palynoflora along the edge of this basin. Although the present information indicates an age 2.5 million years younger than the 266.6 Ma age previously suggested for the top of the M. villosa Zone, revisions to the ages of Roadian–Wordian spore-pollen zones are not considered justifiable without further supporting evidence. Furthermore, considerable care is needed when comparing palynological assemblages from significantly differing facies. Two basaltic sills (43.5 m and 20 m thick) immediately below the tuffaceous beds in Pittston SD-1 are coincidental, as Ar–Ar dating indicates a Late Triassic age for the intrusions.     

Geochronology of Quaternary glaciations from the tropical Cordillera Huayhuash, Peru

The Cordillera Huayhuash in the central Peruvian Andes (10.3°S, 76.9°W) is an ideal mountain range in which to study regional climate through variations in paleoglacier extents. The range trends nearly north-south with modern glaciers confined to peaks >4800 m a.s.l. Geomorphology and geochronology in the nearby Cordillera Blanca and Junin Plain reveal that the Peruvian Andes preserve a detailed record of tropical glaciation. Here, we use ASTER imagery, aerial photographs, and GPS to map and date glacial features in both the western and eastern drainages of the Cordillera Huayhuash. We have used in situ produced cosmogenic ¹⁰Be concentrations in quartz bearing erratics on moraine crests and ice-polished bedrock surfaces to develop an exposure age chronology for Pleistocene glaciation within the range. We have also collected sediment cores from moraine-dammed lakes and bogs to provide limiting ¹⁴C ages for glacial deposits. In contrast to the ranges to the north and south, most glacial features within the Cordillera Huayhuash are Lateglacial in age, however we have identified features with ages that span 0.2 to 38 ka with moraine sets marking the onset of glacier retreat at 0.3 ka, 9–10 ka, 13–14 ka, 20–22 ka, and >26 ka. The range displays a pronounced east-west variation in maximum down-valley distance from the headwall of moraine crests with considerably longer paleoglaciers in the eastern drainages. Importantly, Lateglacial paleoglaciers reached a terminal elevation of 4000 m a.s.l. on both sides of the Cordillera Huayhuash; suggesting that temperature may have been a dominant factor in controlling the maximum glacier extent. We suggest that valley morphology, specifically valley slope, strongly influences down-valley distance to the maximum glacier extent and potential for moraine preservation. While regionally there is an extensive record of older (>50 ka) advances to the north (Cordillera Blanca) and to the south (Junin region), the apparent lack of old moraines in this locality may be explained by the confined morphology of the Cordillera Huayhuash valleys that has inhibited the preservation of older glacial geomorphic features.     

Feldspar dissolution rates in the Topopah Spring Tuff, Yucca Mountain, Nevada

Two different field-based methods are used here to calculate feldspar dissolution rates in the Topopah Spring Tuff, the host rock for the proposed nuclear waste repository at Yucca Mountain, Nevada. The center of the tuff is a high silica rhyolite, consisting largely of alkali feldspar (60 wt%) and quartz polymorphs (35 wt%) that formed by devitrification of rhyolitic glass as the tuff cooled. First, the abundance of secondary aluminosilicates is used to estimate the cumulative amount of feldspar dissolution over the history of the tuff, and an ambient dissolution rate is calculated by using the estimated thermal history. Second, the feldspar dissolution rate is calculated by using measured Sr isotope compositions for the pore water and rock. Pore waters display systematic changes in Sr isotopic composition with depth that are caused by feldspar dissolution. The range in dissolution rates determined from secondary mineral abundances varies from 10⁻¹⁶ to 10⁻¹⁷ mol s⁻¹ kg tuff⁻¹ with the largest uncertainty being the effect of the early thermal history of the tuff. Dissolution rates based on pore water Sr isotopic data were calculated by treating percolation flux parametrically, and vary from 10⁻¹⁵ to 10⁻¹⁶ mol s⁻¹ kg tuff⁻¹ for percolation fluxes of 15 mm a⁻¹ and 1 mm a⁻¹, respectively. Reconciling the rates from the two methods requires that percolation fluxes at the sampled locations be a few mm a⁻¹ or less. The calculated feldspar dissolution rates are low relative to other measured field-based feldspar dissolution rates, possibly due to the age (12.8 Ma) of the unsaturated system at Yucca Mountain; because oxidizing and organic-poor conditions limit biological activity; and/or because elevated silica concentrations in the pore waters (50 mg L⁻¹) may inhibit feldspar dissolution.