High-pressure neutron diffraction study on H–D isotope effects in brucite

A neutron powder diffraction study of hydrogenated and deuterated brucite was conducted at ambient temperature and at pressures up to 9 GPa, using a Paris–Edinburgh high-pressure cell at the WAND instrument of the ORNL High Flux Isotope Reactor. The two materials were synthesized by the same method and companion measurements of neutron diffraction were conducted under the same conditions. Our refinement results show that the lattice-parameters of the a axis, parallel to the sheets of Mg–O octahedra, decrease only slightly with pressure with no effect of H–D substitution. However, the c axis of Mg(OD)₂ is shorter and may exhibit greater compressibility with pressure than that of Mg(OH)₂. Consequently, the unit-cell volume of deuterated brucite is slightly, but systematically smaller than that of hydrogenated brucite. When fitted to a third-order Birch–Murnaghan equation in terms of the normalized unit-cell volume, values of the bulk modulus for hydrogenated and deuterated brucite (K ₀ = 39.0 ± 2.8 and 40.4 ± 1.3 GPa, respectively) are, however, indistinguishable from each other within the experimental errors. The measured effect of H–D substitution on the unit-cell volume also demonstrates that brucite (and other hydrous minerals) preferentially incorporate deuterium over hydrogen under pressure, suggesting that the distribution of hydrogen isotopes in deep-earth conditions may differ significantly from that in near-surface environments.     

Evidence of centennial-scale drought from southeastern Massachusetts during the Pleistocene/Holocene transition

A principal method for studying past hydroclimatic change is the reconstruction of paleo-lake levels. Here, we provide high-resolution lake-level records from New Long Pond and Rocky Pond in southeastern Massachusetts, which each contain evidence for multiple, sub-centennial-to-millennial scale low stands during the transition between the Late Pleistocene (15.0 ka) and Middle Holocene (ca 7.0 ka). Data from New Long Pond also demonstrate sedimentary evidence for a drop in water levels in the early to mid AD 20th century, when long-term trends in instrumental data show lower-than-average precipitation in the northeastern United States. Local data show the most precipitous declines in precipitation and groundwater levels are concurrent with the most severe drought in the AD 1960s, which occurred during a period of low sea-surface temperatures in the western North Atlantic. Ground penetrating radar and sediment core data indicate five intervals with numerous paleo-shoreline deposits between ca 15.0 and 7.0 ka, similar to the layer deposited in the AD 1960s. Many of the intervals of low lake levels coincide with proposed meltwater release events or abrupt climate oscillations in the circum North Atlantic. For example, we document at least three low stands during the Younger Dryas (12.9–11.6 ka) and in association with the “9.2” and “8.2” ka events. The combined evidence of (1) concurrent paleo-droughts in southeastern New England with documented North Atlantic abrupt cooling events and (2) recent drought with the modern association of low sea-surface temperatures indicates that freshening and cooling of the western North Atlantic is a viable mechanism for decreasing moisture within the region. Large-scale changes in seasonality and ice sheet extent also may have increased the susceptibility of the northeast to dry conditions triggered by changes in the North Atlantic.     

Measurements of the upstream turbulent flow during wind tunnel simulations of agricultural field burning

Mean streamwise and vertical velocities as well as streamwise and vertical turbulence intensities were measured in a combustion wind tunnel used to collect pollutant emission data for agricultural field burning. Objectives were to compare the flow field upstream of a fire to that without a fire present and to compare the wind tunnel flow upstream of a fire to field conditions. Vertical centerline traverses with an anemometer were conducted for 32 separate wind tunnel operating configurations (wind speed, position in the tunnel, with or without fire, ceiling position, and floor condition) with one replication for each configuration (total of 64 traverses). Certain configurational changes in the wind tunnel had substantial effects on the flow field. Turbulence intensities and velocity profiles (as modeled by the log law-of-the-wall to determinez ₀ andu _* values) in the wind tunnel were comparable to those in the field as reported in the literature. Velocities and turbulence intensities were generally higher, however, with a fire present in the tunnel and all other conditions constant.     

A contribution to Pleistocene chronology in southeast Essex,England

Parallel to the Essex coast north of the mouth of the Thames, a series of gravel spreads ranging in altitude from near sea level westward to more than 200 ft O.D. (mean sea level) proved to be the remnants of an abandoned Thames/Medway terrace system, rather than a series of “raised” beaches, as their location had suggested. The seaward side of the ancient river valley has subsequently been “captured” by subsidence.Evidence is given for five terraces, with surface levels between 5 and 75 ft O.D. Because of subsidence of the Essex coast, the terrace levels are not easily correlatable with either the Thames or Medway terrace levels. Temporal placement is attempted on the basis of one site in the 25 ft Barling terrace, which yielded a Middle Acheulian archaeological assemblage associated with a cool temperate fauna including an early form of mammoth. An ice wedge cast in the Barling terrace was filled with floodloam which weathered to a parabraunerde soil during an interglacial climate warmer than now. For these reasons man is thought to have lived on the floodplain of the Barling terrace either at the onset of the Wolstonian (Riss) glacial or during an interstadial of that stage. The question of possible linkages between Swanscombe and Clacton terraces is discussed.     

History and mechanism of eruption of soda-rhyolite and alkali basalt,Socorro Island,Mexico

Socorro Island is the summit of a large volcanic mountain located on the Clarion Fracture Zone in the east Pacific. Two major periods of volcanic activity can be recognized on the island. The first (pre-caldera) period was characterized by eruptions of olivine-poor alkali basalt, followed by quiet effusion of soda rhyolite including varieties transitional to pantellerite. This period of activity terminated with the formation of a caldera by collapse. A relatively prolonged period of quiescence ended with rifting and down-faulting of the western side of the island along a north-south fracture system, accompanied by violently explosive eruptions of soda rhyolite which built a large tephra cone over the position of the old caldera. The locus of eruptive activity moved outward and downward along tension fractures and old tectonic rifts as the central vents became blocked by domes of dense obsidian. Low level eruptions of viscous soda rhyolite including pantellerite commenced without preliminary explosive eruptions and built numerous endogenous and exogenous domes. Basaltic eruptions were rare and confined to low-level vents. During the growth of the volcano the direction of active rifting appears to have changed from east-west to northwest-southeast to north-south. Little is known of the submarine portion of the volcano, but the topography seems to reflect the three directions of rifting. The oldest submarine lavas are assumed to be basaltic and are probably of late Tertiary age. The eruptive history of Socorro suggests that the underlying magma column became stratified toward the end of the active period.     

Hydrothermal convection in carbonaceous chondrite parent bodies

Numerical simulations of the thermal evolution of carbonaceous chondrite parent bodies indicate a period of several million years during which convective motion of water could occur. The present study considers variations of permeability, radiogenic heating, and body radius. The model accounts for the radial variation of gravity within the body, melting of ice, freezing of liquid water, and variable water properties and incorporates a realistic equation of state for water. Some regions of a parent body experience no pore water flow while other regions experience hundreds of pore volumes of liquid water flow. The spatial heterogeneity in pore water flow reflects the convective pattern in the body. Hydrothermal alteration of minerals inside the parent body will accordingly vary greatly with location in the body, and one parent body could be the source of chemically diverse meteorites.     

Redistribution of sea level rise associated with enhanced greenhouse warming: a simple model study

Future sea level rise from thermal expansion of the World Ocean due to global warming has been explored in several recent studies using coupled ocean-atmosphere models. These coupled models show that the heat input by the model atmosphere to the ocean in such an event could be quite non-uniform in different areas of the ocean. One of the most significant effects predicted by some of the models is a weakening of the thermohaline circulation, which normally transports heat poleward. Since the greatest heat input from enhanced greenhouse warming is in the higher latitudes, a weakening of the poleward heat transport effectively redistributes the heat anomaly and the associated sea level rise to lower latitudes. In this study, the mechanism of ocean circulation spindown and heat redistribution was studied in the context of a much simpler, linearized shallow water model. Although the model is much simpler than the three-dimensional ocean circulation models used in the coupled model experiments, and neglects several important physical effects, it has a nearly 10-fold increase in horizontal resolution and clearer dynamical interpretations. The results indicated that advanced signals of sea level rise propagated rapidly through the action of Kelvin and Rossby waves, but the full adjustment toward a more uniform sea level rise took place much more slowly. Long time scales were required to redistribute mass through narrow currents trapped along coasts and the equatorial wave guide. For realistic greenhouse warming, the model showed why the sea level rise due to ocean heating could be far from uniform over the globe and hence difficult to estimate from coastal tide gauge stations.     

The steric component of sea level rise associated with enhanced greenhouse warming: a model study

Climate change due to enhanced greenhouse warming has been calculated using the coupled GFDL general circulation model of the atmosphere and ocean. The results of the model for a sustained increase of atmospheric carbon dioxide of 1% per year over a century indicate a marked warming of the upper ocean. Results of the model are used to study the rise in sea level caused by increase in ocean temperatures and associated changes in ocean circulation. Neglecting possible contributions due to changes in the volume of polar ice sheets and mountain glaciers, the model predicts an average rise in sea level of approximately 15 ± 5 cm by the time atmospheric carbon dioxide doubles. Heating anomalies are greatest in subpolar latitudes. This effect leads to a weakening of the ocean thermohaline circulation. Changes in thermohaline circulation redistribute heat within the ocean from high latitudes toward the equator, and cause a more uniform sea level rise than would occur otherwise.