Copper,zinc, and organotin as long-term factors governing the distribution of organisms in the fal estuary in Southwest England

Evidence of long-term metal pollution in the Fal Estuary is provided by analyses of Cu in oyster (Ostrea edulis) communities extending over more than 120 yr and by analyses of Cu and Zn in sediments dating back to 1921. Indications are that levels of Cu pollution from mining have declined very slowly but that Zn pollution has not. In Restronguet Creek, the most heavily polluted area, metal levels in waters and sediments are elevated by orders of magnitude. The invertebrate fauna of the creek is limited, but far richer than might be predicted from laboratory toxicity data. The cockleCerastoderma edule exemplifies organisms that are excluded from the creek owing to the toxicity of dissolved Cu, whereasOstrea edulis, by virtue of its innate tolerance to Cu and Zn, grown in the Iower reaches. On the other hand, the population of the ragwornNereis diversicolor, which penetrates into the most heavily polluted areas, is demonstrably far more tolerant of Cu and Zn than population from clean areas and appears to be a tolerant strain. To a considerable degree, therefore, the distribution of species is dependent not only on the innate ability of some species to tolerate Cu and Zn, but on the capacities of other populations to develop metal resistance and thereby maintain their original range of distribution. Present-day problems in the Fal Estuary appear to stem not only from mining wastes but also from the increased usage of tributyltins in antifouling paints. In the dogwhelkNucella lapillus, the incidence of imposex (the appearance of a penis and other male characters in females) is virtually 100% at sites along the English Channel coast of southwest England. The degree of imposex is related to the body concentration of hexane-extractable organotin, which includes both tributyltin and dibutyltin fractions. The highest degree of imposex, where the female penis approaches that of the male in size, occurs in the Fal Estuary; also, in some males the penis becomes deformed. Populations of dogwhelks have declined dramatically in this estuary, and are also characterised by the presence of relatively fewer females and by the absence of juveniles and egg capsules. Reproductive failure in females is now known to be caused by blockage of the pallial oviduct during the development of imposex.     

Late Holocene chronology,origin, and evolution of the St. Bernard Shoals,Northern Gulf of Mexico,USA

Several shore-parallel marine sand bodies lie on the Louisiana continental shelf. They are Trinity Shoal, Ship Shoal, Outer Shoal, and the St. Bernard Shoals. These shoals mark the submerged positions of ancient shorelines associated with abandoned deltas. Three of these shoals are single elongate deposits. The fourth shoal, the St. Bernard Shoals, consists of a group of discrete sand bodies ranging in size from 44 to 0.05 km², 25 km southeast of the Chandeleur Islands in 15–18 m of water. The St. Bernard Shoals are stratigraphically above the St. Bernard delta complex, which was active 2,500–1,800 years b.p. Understanding the evolution of the St. Bernard Shoals is necessary to reconstruct the Holocene chronology of the St. Bernard delta complex and the eastern Louisiana continental shelf. For this study, 47 vibracores and 400 km of shallow seismic reflection data collected in 1987 across the Louisiana shelf were analyzed. In June 2008, 384 km of higher-resolution seismic reflection data were acquired across the study area and appended to the preexisting datasets. Vibracores were integrated with seismic profiles to identify facies and their regional distribution. Our results demonstrate that the deltaic package stratigraphically below the St. Bernard Shoals is chronologically younger than the northern distributaries, but derived from the same trunk distributary channel (Bayou la Loutre). The river eventually bypassed the northern distributaries, and began to deposit sediment further onto the continental shelf. After abandonment, the overextended delta lobe was rapidly transgressed, creating a transgressive shoreline that eventually coalesced with earlier shorelines in the region to form the Chandeleur Islands. The St. Bernard Shoals formed by the reworking of the relict distributary deposits exposed on the inner to mid shelf during and subsequent to shoreface ravinement.     

Quantifying groundwater–surface water interactions in a proglacial valley,Cordillera Blanca,Peru

A myriad of downstream communities and industries rely on streams fed by both groundwater discharge and glacier meltwater draining the Cordillera Blanca, Northern Peruvian Andes, which contains the highest density of glaciers in the tropics. During the dry season, approximately half the discharge in the region's proglacial streams comes from groundwater. However, because of the remote and difficult access to the region, there are few field methods that are effective at the reach scale to identify the spatial distribution of groundwater discharge. An energy balance model, Rhodamine WT dye tracing, and high‐definition kite‐borne imagery were used to determine gross and net groundwater inputs to a 4‐km reach of the Quilcay River in Huascaran National Park, Peru. The HFLUX computer programme ( http://hydrology.syr.edu/hflux.html ) was used to simulate the Quilcay River's energy balance using stream temperature observations, meteorological measurements, and kite‐borne areal photography. Inference from the model indicates 29% of stream discharge at the reach outlet was contributed by groundwater discharge over the study section. Rhodamine WT dye tracing results, coupled with the energy balance, show that approximately 49% of stream water is exchanged (no net gain) with the subsurface as gross gains and losses. The results suggest that gross gains from groundwater are largest in a moraine subreach but because of large gross losses, net gains are larger in the meadow subreaches. These insights into pathways of groundwater–surface water interaction can be applied to improve hydrological modelling in proglacial catchments throughout South America. Copyright © 2016 John Wiley & Sons, Ltd.     

A contribution to Pleistocene chronology in southeast Essex,England

Parallel to the Essex coast north of the mouth of the Thames, a series of gravel spreads ranging in altitude from near sea level westward to more than 200 ft O.D. (mean sea level) proved to be the remnants of an abandoned Thames/Medway terrace system, rather than a series of “raised” beaches, as their location had suggested. The seaward side of the ancient river valley has subsequently been “captured” by subsidence.Evidence is given for five terraces, with surface levels between 5 and 75 ft O.D. Because of subsidence of the Essex coast, the terrace levels are not easily correlatable with either the Thames or Medway terrace levels. Temporal placement is attempted on the basis of one site in the 25 ft Barling terrace, which yielded a Middle Acheulian archaeological assemblage associated with a cool temperate fauna including an early form of mammoth. An ice wedge cast in the Barling terrace was filled with floodloam which weathered to a parabraunerde soil during an interglacial climate warmer than now. For these reasons man is thought to have lived on the floodplain of the Barling terrace either at the onset of the Wolstonian (Riss) glacial or during an interstadial of that stage. The question of possible linkages between Swanscombe and Clacton terraces is discussed.     

Vertical and lateral organization of a carbonate deep-water slope marginal to a submarine fan system, Miocene, southern Turkey

Organization is recognized in the forereef–deep water slope–submarine fan system of the Burdigalian-Langhian Kaplankaya Formation. A basinwards transition from a prograding shelfal reef complex, through forereef talus, deep-water slope and laterally encroaching bypass deep-water clastic system is described, although the deep-water slope makes up the bulk of the succession. Considerable thickness variations occur between the reef and deep-water clastic complexes; these are controlled by sea-floor topography, carbonate foreslope gradient and degree of mass wasting off the platform and foreslope. The vertical and lateral heterogeneity of the Kaplankaya deep-water slope system is described from a number of localities along a 40-km-long and up to 3-km-wide exposed section of the northern margin of the Miocene Adana Basin, a foreland basin setting resulting from thrust sheet loading from the north during the Tauride Orogeny. Detailed field mapping is supplemented with vertical sedimentary logs, photomosaics, palaeontological and petrological data to investigate stratal variation, diagnostic architectural elements, controls on slope progradation, differential timing of basinward encroachment of the reefal complex and lateral onlap of the deep-water clastic system onto the slope. Three-dimensional models are presented showing the vertical and lateral facies associations in different parts of the deep-water slope system, and provide a basis for architectural prediction of geometry and relative position in such environments.     

The Cainozoic geology of the Middle Shoalhaven Plain

The Middle Shoalhaven Plain is a large, tray‐like depression bounded in the west by the Mulwaree fault and in the east by cliffed Permian sediments. The plain is probably Mesozoic in origin and was partially alluviated during the Early to mid‐Eocene. Much of the plain and sediments were covered by basalts during the Late Eocene. This was followed by an episode of deep weathering, which culminated in the formation of widespread bauxitic and lateritic crusts and manganocrete and silcrete during the mid‐Tertiary. A second minor weathering event is recorded during the latest Tertiary to Early Pleistocene. Two new basalt dates are consistent with earlier ones at about 43 Ma. Palaeomagnetism shows bauxites and ferricretes to be mid‐Tertiary.     

Al(III) and Fe(III) binding by humic substances in freshwaters, and implications for trace metal speciation

Published experimental data for Al(III) and Fe(III) binding by fulvic and humic acids can be explained approximately by the Humic Ion-Binding Model VI. The model is based on conventional equilibrium reactions involving protons, metal aquo ions and their first hydrolysis products, and binding sites ranging from abundant ones of low affinity, to rare ones of high affinity, common to all metals. The model can also account for laboratory competition data involving Al(III), Fe(III) and trace elements, supporting the assumption of common binding sites. Field speciation data (116 examples) for Al in acid-to-neutral waters can be accounted for, assuming that 60-70 % (depending upon competition by iron, and the chosen fulvic acid : humic acid ratio) of the dissolved organic carbon (DOC) is due to humic substances, the rest being considered inert with respect to ion binding. After adjustment of the model parameter characterizing binding affinity within acceptable limits, and with the assumption of equilibrium with a relatively soluble form of Fe(OH)₃, the model can simulate the results of studies of two freshwater samples, in which concentrations of organically complexed Fe were estimated by kinetic analysis.The model was used to examine the pH dependence of Al and Fe binding by dissolved organic matter (DOM) in freshwaters, by simulating the titration with Ca(OH)₂ of an initially acid solution, in equilibrium with solid-phase Al(OH)₃ and Fe(OH)₃. For the conditions considered, Al, which is present at higher free concentrations than Fe(III), competes significantly for the binding of Fe(III), whereas Fe(III) has little effect on Al binding. The principal form of Al simulated to be bound at low pH is Al³⁺, AlOH²⁺ being dominant at pH >6; the principal bound form of Fe(III) is FeOH²⁺ at all pH values in the range 4-9. Simulations suggest that, in freshwaters, both Al and Fe(III) compete significantly with trace metals (Cu, Zn) for binding by natural organic matter over a wide pH range (4-9). The competition effects are especially strong for a high-affinity trace metal such as Cu, present at low total concentrations (∼1 nM). As a result of these competition effects, high-affinity sites in humic matter may be less important for trace metal binding in the field than they are in laboratory systems involving humic matter that has been treated to remove associated metals.     

Feldspar dissolution rates in the Topopah Spring Tuff, Yucca Mountain, Nevada

Two different field-based methods are used here to calculate feldspar dissolution rates in the Topopah Spring Tuff, the host rock for the proposed nuclear waste repository at Yucca Mountain, Nevada. The center of the tuff is a high silica rhyolite, consisting largely of alkali feldspar (60 wt%) and quartz polymorphs (35 wt%) that formed by devitrification of rhyolitic glass as the tuff cooled. First, the abundance of secondary aluminosilicates is used to estimate the cumulative amount of feldspar dissolution over the history of the tuff, and an ambient dissolution rate is calculated by using the estimated thermal history. Second, the feldspar dissolution rate is calculated by using measured Sr isotope compositions for the pore water and rock. Pore waters display systematic changes in Sr isotopic composition with depth that are caused by feldspar dissolution. The range in dissolution rates determined from secondary mineral abundances varies from 10⁻¹⁶ to 10⁻¹⁷ mol s⁻¹ kg tuff⁻¹ with the largest uncertainty being the effect of the early thermal history of the tuff. Dissolution rates based on pore water Sr isotopic data were calculated by treating percolation flux parametrically, and vary from 10⁻¹⁵ to 10⁻¹⁶ mol s⁻¹ kg tuff⁻¹ for percolation fluxes of 15 mm a⁻¹ and 1 mm a⁻¹, respectively. Reconciling the rates from the two methods requires that percolation fluxes at the sampled locations be a few mm a⁻¹ or less. The calculated feldspar dissolution rates are low relative to other measured field-based feldspar dissolution rates, possibly due to the age (12.8 Ma) of the unsaturated system at Yucca Mountain; because oxidizing and organic-poor conditions limit biological activity; and/or because elevated silica concentrations in the pore waters (50 mg L⁻¹) may inhibit feldspar dissolution.     

Spatial Analysis of Environmental Change Impacts on Wheat Production in Mid-Lower North, South Australia

Three environmental change scenarios (the best scenario, the most likely scenario and the worst scenario) were used by the APSIM (Agricultural Production System sIMulator) Wheat module to study the possible impacts of future environmental change (climate change plus pCO₂ change) on wheat production in the Mid-Lower North of South Australia. GIS software was used to manage spatial-climate data and spatial-soil data and to present the results. Study results show that grain yield (kg ha⁻¹) was adversely affected under the worst environmental change scenario (−100% ∼ −42%) and the most likely environmental change scenario (−58% ∼ −3%). Grain nitrogen content (% N) either increased or decreased depending on the environmental change scenarios used and climate divisions (−25% ∼ +42%). Spatial variability was found for projected impact outcomes within climate divisions indicating the necessity of including the spatial distribution of soil properties in impact assessment.