Succession de subfacies métamorphiques en Vanoise méridionale (Savoie)

The Southern Vanoise is localized in the internal part of the Western Alps, in the Briançonnais zone. In Vanoise the following units can be distinguished (Fig. 1): a pre-hercynian basement (micaschists, glaucophanites, basic rocks), a permian cover (micaschists) and a mesozoic-paleocene cover (carbonate rocks). This area has been affected by the alpine metamorphic event characterized here by high and intermediate pressure facies. The rocks paragenesis are often unbalanced.The paleozoic rocks (Table 1) contain mainly: quartz, albite, paragonite, phengite, blue amphibole, chlorite, green biotite, garnet (Table 2). These minerals were analysed by an electron microprobe (Tables 3, 4 and 5). Mineral composition is highly variable: glaucophane is zoned (Table 5), white micas are more or less substituted with phengite (3.22O₃/FeO + MgO)<0.53] whereas the Al rich chlorites [(Al₂O₃/FeO + MgO)>0.6] are associated with the less substituted white micas (Si=3.2) (Tables 3 and 4). The phengites with a Si content 3.2 occur in rocks where the retromorphic evolution is the most pronounced and penetrative. A metamorphic evolution is characterized by the disappearance of glaucophane which corresponds to the appearance of Al rich chlorite and to the decrease of phengitic substitution.The samples analysis are plotted in the tetraedric diagram: K₂O-Al₂O₃-Na₂O, Al₂O₃-FeO, MgO, on which a special mathematical treatment was applied. This method calculates the location of rocks composition in the four minerals space. This location is internal when the per cent amounts of all four relevant minerals are positive, if any of them is negative, the point is external (Tables 6–9).In Southern Vanoise micaschists, 2 subfacies are successively present (Fig. 3):Subfacies I: glaucophane-chlorite-phengite (Si⁴⁺ 3.5)-paragonite. Then subfacies II: chlorite-albite-phengite (Si⁴⁺ 3.2)-paragonite.In basic rocks is found essentially: Subfacies III: glaucophane-garnet-phengite-paragonite or IV: glaucophane-garnet-phengite-albite. Then subfacies V: green biotite-chlorite-albite-paragonite.The assemblages I and II proceed through reaction: 2 glaucophane +1 paragonite+2 H₂O4.2 albite + 1 chlorite.The assemblage V appears with reactions: 1.8 glaucophane +2 phengite0.4 chlorite+2 green biotite + 3.6 albite +0.4 H₂O or 2 glaucophane +2 phengite +0.5 garnet+ 6 H₂O2 green biotite +1 chlorite+4 albiteThese reactions are controlled by hydratation: the composition variation of phengite and associated chlorite during the metamorphic evolution determines the stability of some minerals (particularly the glaucophane in Na₂O poor rocks).In same rocks the results of mathematical treatment is not consistent with the data (Tables 2, 6–9). This discrepancy corresponds to a desequilibrium between chlorite and phengite.These results imply a continuous metamorphic evolution between two stages (Fig. 6): a first stage (1) at 8 kb, 350 ° C; a second stage (2) at 2 to 3 kb, 400–450 ° C.     

PbSrNd isotopic data of Indian Ocean ridges: new evidence of large-scale mapping of mantle heterogeneities

A PbSrNd isotope study of South West and East Indian Ridges confirms that the Indian Ocean belongs to a specific regional isotopic domain, as previously suggested by the results from islands of this ocean. The isotopic domain defined by the Indian MORB is indeed different from that of the North Atlantic and East Pacific Oceans. This demonstrates that the convective circulation of the upper mantle does not allow a rapid homogenization from one region to the other.The isotopic data of the Indian ridges can be interpreted by a contamination model, in which the depleted upper mantle (identical to that under the North Atlantic) is contaminated by two different types of contaminant, one corresponding to the source of the “central Indian Ocean” islands (Amsterdam, St. Paul, Marion, Prince Edward, Réunion, Rodriguez, Mauritius), and the other to a source similar to that of Walvis or Ninety East aseismic ridges. These two contaminants would have contributed to the ridge volcanism in different proportions over time.     

Impacts of land-use and climate changes on surface runoff in a tropical forest watershed (Brazil)

ABSTRACT

Surface runoff generation capacity can be modified by land-use and climate changes. Annual runoff volumes have been evaluated in a small watershed of tropical forest (Brazil), using the Soil and Water Assessment Tool (SWAT) model. Firstly, the accuracy of SWAT in runoff predictions has been assessed by default input parameters and improved by automatic calibration, using 20-year observations. Then, the hydrological response under land uses (cropland, pasture and deforested soil) alternative to tropical forest and climate change scenarios has been simulated. SWAT application has showed that, if forest was replaced by crops or pasture, the watershed’s hydrological response would not significantly be affected. Conversely, a complete deforestation would slightly increase its runoff generation capacity. Under forecasted climate scenarios, the runoff generation capacity of the watershed will tend to decrease and will not be noticeably different among the representative concentration pathways. Pasture and bare soil will give the lowest and highest runoff coefficients, respectively.     

Cyclostratigraphy and high-frequency carbon isotope fluctuations in Upper Cretaceous shallow-water carbonates, southern Italy

Abstract A detailed carbon isotope study has been carried out on a Santonian (Upper Cretaceous) carbonate platform succession that crops out at Monte Sant'Erasmo (southern Italy). Previous centimetre‐scale studies on this succession have shown that high‐frequency eustatic changes, resulting from the Earth's orbital fluctuations, controlled the hierarchical organization of the depositional and early diagenetic features in elementary cycles, bundles (groups of three to five elementary cycles) and superbundles (groups of three or four bundles). The elementary cycles, which correspond to single beds, suggest a control caused by Earth's precession; the bundles and superbundles record the short (≈ 100 kyr) and long (≈ 400 kyr) eccentricity periodicity respectively. The δ¹³C signal of the Monte Sant'Erasmo succession is cyclic in nature and may be considered to be a reliable proxy for the sedimentary evolution (and related sea‐level history) of the analysed sequence. The carbon isotope cyclicity is recorded at bundle and superbundle level, but it is not evident at the scale of the elementary cycles, at least with the sampling interval used in this study. Spectral analysis of the δ¹³C record shows two main peaks corresponding to the short‐ and long‐eccentricity periodicity, whereas the precession signal is not evident in the power spectrum. In addition, lithofacies analysis shows that, in each bundle (and superbundle), higher C isotope values occur in sediments characterized by marine cements, whereas lower values are normally found in more restricted deposits overprinted by early meteoric diagenesis. Early diagenesis, driven by periodic sea‐level fluctuations, developed in either shallow‐subtidal (marine diagenesis) or subaerial‐exposed (meteoric overprint) sedimentary environments and directly influenced the carbon isotope signature. As a consequence, the δ¹³C record at Monte Sant'Erasmo reflects high‐frequency climatic oscillations controlling both environmental and early diagenetic changes. The long‐term isotopic record is similar to that of contemporaneous pelagic sections in England and elsewhere in Italy. It is concluded that the δ¹³C signature of shallow‐water carbonates, such as those of Monte Sant'Erasmo, offers great potential for correlation with coeval sections, including those of the pelagic realm.     

High-resolution cyclostratigraphic analysis from magnetic susceptibility in a Lower Kimmeridgian (Upper Jurassic) marl–limestone succession (La Méouge,Vocontian Basin,France)

High-resolution magnetic susceptibility (MS) analysis was carried out on a Lower Kimmeridgian alternating marl–limestone succession of pelagic origin that crops out at La Méouge (Vocontian Basin, southeastern France). The aim of the study was to characterize the strong, dm-scale sedimentary cyclicity of the succession at a very high resolution, and to analyze the cycles for evidence of astronomical forcing. From marl to limestone, MS varies progressively and closely tracks the highest frequency cyclicity corresponding to the basic marl–limestone couplets. Long-term wavelength cycling modulates the high-frequency cyclicity (couplets), and appears to be controlled by clay content. Spectral analysis of the MS record reveals the presence of the complete suite of orbital frequencies in the precession, obliquity, and eccentricity (95–128 ka and 405 ka) bands with very high amplitude of the precession index cycles originating from dm-scale couplets. 405 ka-eccentricity cycles are very pronounced in the MS maxima of the marl members of the couplets, suggesting eccentricity-driven detrital input to the basin. 405 ka-orbital tuning of the MS maxima further sharpens all of the orbital frequencies present in the succession. These results are similar to those of previous studies at La Méouge that used carbonate content observed in field. Our results are also in accordance with cyclostratigraphic studies in Spain and Canada that report dominant precession index forcing. By contrast, in the Kimmeridge Clay (Dorset, UK), obliquity forcing dominates cyclic sedimentation, with weaker influence from the precession index. Ammonite zone duration estimates are made by counting the interpreted precession cycles, and provide an ultra-high resolution assessment of geologic time. In sum, this study demonstrates the power of the MS as a proxy in characterizing the high-resolution cyclostratigraphy of Mesozoic sections, particularly in alternating marl–limestone successions, and for high-resolution correlation and astronomical calibration of the geologic time scale.     

Study of the interaction between U(VI) and the anoxic corrosion products of carbon steel

The objective of this study was to investigate the removal mechanism of U(VI) from groundwater by magnetite as the main product of anoxic steel corrosion. For this purpose, a systematic sequence of batch experiments was conducted to focus the active role of magnetite in the reduction of U under different conditions. Results indicated that under anoxic conditions U(VI) was sorbed at the magnetite surface, whereas under reducing conditions at different H₂(g) pressures, U was present in tetravalent form as amorphous UO₂.     

Field instrumentation for high‐resolution parallel monitoring of bedrock erosion and bedload transport

River incision is fundamental in shaping the Earth's surface. In mountainous regions with steep river beds, fluvial bedrock erosion by bedload transport is an important mechanism forming channels. However, there are only a few complete field datasets that can be used to improve process understanding and evaluate erosion models, especially at the process scale. To provide a simultaneous dataset of hydraulics, bedload transport and bedrock erosion at high temporal and spatial resolution, a new measuring device has been installed in the Erlenbach, a gauged stream in the Swiss Pre‐Alps. In this stream, bedload transport rates can be calculated from surveying deposits and from geophone plate sensors and bedload transport samples can be taken directly by an automated moving basket system. To measure bedrock erosion rates simultaneously, two natural stone slabs were mounted flush with the channel bed in a steel frame hosting various measurement devices. Force sensors below the slabs record normal stress and shear stress. At‐a‐point erosion rates on the slab surfaces are continuously measured at sub‐millimetre precision at three locations on each slab. In addition, the slab topography is monitored following erosive flood events. In this article (i) the ‘erosion scale’ device is described, (ii) data resolution and data quality is assessed by means of tests and event data, and (iii) the first transport event is discussed. The erosion scales are confirmed to provide data at high spatio‐temporal resolution for process analysis. The preliminary data show evidence for the tools effect in bedrock erosion. The bedrock slabs can be exchanged to obtain measurements for catchments with different lithologies for comparison. Copyright © 2014 John Wiley & Sons, Ltd.     

Spatial reconstruction of rainfall fields from rain gauge and radar data

Rainfall is a phenomenon difficult to model and predict, for the strong spatial and temporal heterogeneity and the presence of many zero values. We deal with hourly rainfall data provided by rain gauges, sparsely distributed on the ground, and radar data available on a fine grid of pixels. Radar data overcome the problem of sparseness of the rain gauge network, but are not reliable for the assessment of rain amounts. In this work we investigate how to calibrate radar measurements via rain gauge data and make spatial predictions for hourly rainfall, by means of Monte Carlo Markov Chain algorithms in a Bayesian hierarchical framework. We use zero-inflated distributions for taking zero-measurements into account. Several models are compared both in terms of data fitting and predictive performances on a set of validation sites. Finally, rainfall fields are reconstructed and standard error estimates at each prediction site are shown via easy-to-read spatial maps.