Monitoring chemical contamination levels in the Mediterranean based on the use of mussel caging

Within the framework of the biointegrator network (RINBIO), 92 man-made cages containing mussels (Mytilus galloprovincialis), distributed over 1800 km of the French Mediterranean coast, made it possible to assess chemical contamination by heavy metals (Cd, Hg, Zn, Pb, Cu, Ni, Cr, As) and organic compounds (DDT, PCBs, HAP). The caging technique was adopted to compensate for the scarcity of natural shellfish stocks in the Mediterranean and to enable comparison of the sites regardless of their physicochemical and trophic characteristics. Models linking a biometric parameter (the condition index) to pollutant levels make it possible to adjust raw data on contamination for a reference individual, by making a clear distinction between physiological factors (growth) and environmental ones. The results demonstrate significant levels of pollutants in sites heretofore unsampled; the pollution occurs at limited areas, and the sources have been identified. Moreover, average contamination levels are comparable to those measured in wild species and in other areas. Overall, the research demonstrates the reliability of this methodological approach for monitoring marine pollution, especially in the Mediterranean.     

Neutron activation determination of the aerosol content of Greenland snow

Summary The concentrations of Na, Cl and SO₄ have been measured as a function of time in snow from Jarl-Joset, Greenland. Large sulfate to chloride ratios and a strong parallelity between sulfate- and sea salt components were obtained in the period 1880 to 1968. The possible origin of the excess sulfate and the reason for the parallelity are discussed.     

Sedimentation in the floodplains of the Mekong Delta,Vietnam Part II: deposition and erosion

Deposition and erosion play a key role in the determination of the sediment budget of a river basin, as well as for floodplain sedimentation. Floodplain sedimentation, in turn, is a relevant factor for the design of flood protection measures, productivity of agro‐ecosystems, and for ecological rehabilitation plans. In the Mekong Delta, erosion and deposition are important factors for geomorphological processes like the compensation of deltaic subsidence as well as for agricultural productivity. Floodplain deposition is also counteracting the increasing climate change induced hazard by sea level rise in the delta. Despite this importance, a sediment database of the Mekong Delta is lacking, and the knowledge about erosion and deposition processes is limited. In the Vietnamese part of the Delta, the annually flooded natural floodplains have been replaced by a dense system of channels, dikes, paddy fields, and aquaculture ponds, resulting in floodplain compartments protected by ring dikes. The agricultural productivity depends on the sediment and associated nutrient input to the floodplains by the annual floods. However, no quantitative information regarding their sediment trapping efficiency has been reported yet. The present study investigates deposition and erosion based on intensive field measurements in three consecutive years (2008, 2009, and 2010). Optical backscatter sensors are used in combination with sediment traps for interpreting deposition and erosion processes in different locations. In our study area, the mean calculated deposition rate is 6.86 kg/m² (≈ 6 mm/year). The key parameters for calculating erosion and deposition are estimated, i.e. the critical bed shear stress for deposition and erosion and the surface constant erosion rate. The bulk of the floodplain sediment deposition is found to occur during the initial stage of floodplain inundation. This finding has direct implications on the operation of sluice gates in order to optimize sediment input and distribution in the floodplains. Copyright © 2013 John Wiley & Sons, Ltd.     

Fiber Optic Measurements of Soil Moisture in a Waste Rock Pile

The design and construction of a waste rock pile influences water infiltration and may promote the production of contaminated mine drainage. The objective of this project is to evaluate the use of an active fiber optic distributed temperature sensing (aFO-DTS) protocol to measure infiltration and soil moisture within a flow control layer capping an experimental waste rock pile. Five hundred meters of fiber optic cable were installed in a waste rock pile that is 70 m long, 10 m wide, and was covered with 0.60 m of fine compacted sand and 0.25 m of non-reactive crushed waste rock. Volumetric water content was assessed by heating the fiber optic cable with 15-min heat pulses at 15 W/m every 30 min. To test the aFO-DTS system 14 mm of recharge was applied to the top surface of the waste rock pile over 4 h, simulating a major rain event. The average volumetric water content in the FCL increased from 0.10 to 0.24 over the duration of the test. The volumetric water content measured with aFO-DTS in the FCL and waste rock was within ±0.06 and ±0.03, respectively, compared with values measured using 96 dielectric soil moisture probes over the same time period. Additional results illustrate how water can be confined within the FCL and monitored through an aFO-DTS protocol serving as a practical means to measure soil moisture at an industrial capacity.     

Type Ia Supernovae

Summary. Type Ia Supernovae are in many aspects still enigmatic objects. Their observational and theoretical exploration is in full swing, but we still have plenty to learn about these explosions. Recent years have already witnessed a bonanza of supernova observations. The increased samples from dedicated searches have allowed the statistical investigation of Type Ia Supernovae as a class. The observational data on Type Ia Supernovae are very rich, but the uniform picture of a decade ago has been replaced by several correlations which connect the maximum luminosity with light curve shape, color evolution, spectral appearance, and host galaxy morphology. These correlations hold across almost the complete spectrum of Type Ia Supernovae, with a number of notable exceptions. After 150 days past maximum, however, all observed objects show the same decline rate and spectrum. The observational constraints on explosion models are still rather sparse. Global parameters like synthesized nickel mass, total ejecta mass and explosion energetics are within reach in the next few years. These parameters bypass the complicated calculations of explosion models and radiation transport. The bolometric light curves are a handy tool to investigate the overall appearance of Type Ia Supernovae. The nickel masses derived this way show large variations, which combined with the dynamics from line widths, indicate that the brighter events are also coming from more massive objects. The lack of accurate distances and the uncertainty in the correction for absorption are hampering further progress. Improvements in these areas are vital for the detailed comparison of luminosities and the determination of nickel masses. Coverage at near-infrared wavelengths for a statistical sample of Type Ia Supernovae will at least decrease the dependence on the absorption. Some of the most intriguing features of Type Ia Supernovae are best observed at these wavelengths, like the second peak in the light curve, the depression in the J band, and the unblended [Feii] lines in the ashes. Received 24 January 2000 / Published online 8 May 2000     

Oxygen isotope studies of potassic volcanic rocks of the Roman Province,Central Italy

The ¹⁸O/¹⁶O ratios of rocks and coexisting minerals were measured for 93 samples of leucite-bearing lavas, pyroclastics, and related volcanic rocks from the Quaternary Roman Co-Magmatic Province, Italy. The ¹⁸O values were found to generally increase northward in the sequence: Ischia (5.8 to 7.0); Somma-Vesuvius and Phlegrean Fields (7.3 to 8.3); Alban Hills (7.3 to 8.7); M. Sabatini (7.3 to 9.7); Vico Volcano (7.4 to 10.2); and M. Vulsini (8.1 to 11.7). The northward increase in ¹⁸O parallels a similar increase in ⁸⁷Sr/⁸⁶Sr, and these data indicate that the Roman magmas have interacted strongly with high-¹⁸O continental crust. A marked increase in ¹⁸O occurs just north of Rome where the Roman Province begins to overlap the calc-alkaline, oversaturated Tuscan Magmatic Province. Therefore, some of the observed ¹⁸O/¹⁶O and ⁸⁷Sr/⁸⁶Sr enrichments in the Roman magmas may have been facilitated by direct mixing with the high-¹⁸O Tuscan magmas or because the high-¹⁸O country rocks underwent widespread heating during a couple of million years of Tuscan igneous activity. Although many of the Roman magmas underwent fractional crystallization without appreciable change in ¹⁸O, contamination has produced a correlation between ¹⁸O and SiO₂ content at several of the volcanic centers; thus the trachytes are typically higher in ¹⁸O than the undersaturated rocks. The major features of the oxygen isotope data can be explained in terms of a simple two-component mixing model in which one end-member was a primary, strongly undersaturated magma derived from the upper mantle, with ¹⁸O+6, ⁸⁷Sr/⁸⁶Sr0.704 to 0.705, and SiO₂<44wt.%. However, none of the analyzed samples have these values, as they have all been contaminated to some extent. The closest approach is found in some of the leucitepyroxenite ejecta from the Alban Hills. The second end-member, derived from the continental crust, had a variable composition with ¹⁸O+12 to +20, ⁸⁷Sr/⁸⁶Sr0.712 to 0.720, and SiO₂65wt.%, and it mixed in much greater proportions in the volcanoes north of Rome than in those of the Alban Hills or the Naples area. The widespread interactions between the Roman magmas and the continental crust are probably due to (1) the fact that such low-SiO₂ magmas always have a very strong tendency to interact with quartz-bearing rocks of the continental crust, and (2) in Italy, these magmas were emplaced into a tectonically very active area containing poorly consolidated sedimentary rocks, and in the northern part of the belt there had been a prior history of extensive calc-alkaline igneous activity.Publication of the Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, Contribution Number 2501.     

Mapping the vulnerability for evacuation of the Campi Flegrei territorial system in case of a volcanic unrest

Over the past few decades, intense urban expansion has occurred over the Campi Flegrei territorial system without considering the volcanic risk. In this active volcanic area, where a short period evacuation could be necessary, the emergency management cannot be based solely on hazard-related information. The territorial and social features must also be considered. In this framework, the main purpose of this research is to point out the seriousness of the present setting of the Campi Flegrei territorial system in case an evacuation is necessary. Following the concept of regional evacuation, the zone to be involved in emergency planning was identified as the whole of the area threatened by the volcanic events of the past 10?ka. Inside this area the spatial relation between the resident distribution and the outflows of roads, railway stations and harbours, to facilitate evacuation, was investigated. A spatial relational GIS-based procedure was used to draw the territorial system vulnerability map, depicting the zones with different capabilities to support the evacuation of residents in case of volcanic activity. Based on the concept that people could leave the dangerous area by the means of transport supplied by Civil Protection, and using the threshold value of over-crowding of 0.70 people/m², we identified the collection areas for residents to be immediately evacuated in case of volcanic unrest, and five macrozones displaying different capabilities to cope with an emergency phase.     

Peat layer accumulation and post‐burial deformation during the mid‐late Holocene in the Po coastal plain (Northern Italy)

Peat horizons are characteristic features of delta plains worldwide. In this study, we tested the use of peat‐based correlations to assess the deformation of Holocene strata in the Po coastal plain (Northern Italy). The Holocene stratigraphy, about 30 km inland from the modern coastline consists of a peat‐bearing, estuarine and deltaic succession, up to 23 m thick. Through the analysis of 31 core data and 100 piezocone penetration tests, we identified and mapped three 10–40 cm‐thick peat layers (T1–T3) dated to 6.6–5.8, 5.5–5.0 and 3.3–2.7 cal kyr BP respectively. These peat horizons were found to be suitable stratigraphic markers within the Holocene succession over an area of about 200 km². The mid‐late Holocene palaeogeography, reconstructed through high‐resolution peat correlation, supported by 72 radiocarbon dates, highlights a typical upper delta plain environment, with ribbon‐shaped distributary channels and swamp interdistributary areas. Peat layers are inclined towards E‐NE with gradients that increase downsection from ~0.016% (T3) to 0.021% (T1). The gradient of the oldest peat horizon is one order of magnitude larger than the slope of the modern delta plain (~0.0025%). We infer that peat horizons accumulated during periods of low sediment supply mainly controlled by autogenic processes and were deformed after deposition. Differential compaction of underlying sedimentary strata and recent tectonic activity of the buried Apenninic thrust systems are the most likely drivers of strata deformation. Based on isochore maps, we document that higher sedimentation rates in topographically depressed areas compensated, in part at least, the ongoing deformation, keeping unaltered the topographic gradient and the depositional environment. This study demonstrates that peat‐based correlation and mapping can shed lights on the mechanisms of strata accumulation and deformation in deltaic settings, constituting a robust basis for reconstructing delta evolution.     

The Titan N/N and C/C isotopic ratios in HCN from Cassini/CIRS

We report the detection of H¹³CN and HC¹⁵N in mid-infrared spectra recorded by the Composite Infrared Spectrometer (CIRS) aboard Cassini, along with the determination of the ¹²C/¹³C and ¹⁴N/¹⁵N isotopic ratios. We analyzed two sets of limb spectra recorded near 13-15° S (Tb flyby) and 83° N (T4 flyby) at 0.5 cm⁻¹ resolution. The spectral range 1210-1310 cm⁻¹ was used to retrieve the temperature profile in the range 145-490 km at 13° S and 165-300 km at 83° N. These two temperature profiles were then incorporated in the atmospheric model to retrieve the abundance profile of H¹²C¹⁴N, H¹³CN and HC¹⁵N from their bands at 713, 706 and 711 cm⁻¹, respectively. The HCN abundance profile was retrieved in the range 90-460 km at 15° S and 165-305 km at 83° N. There is no evidence for vertical variations of the isotopic ratios. Constraining the isotopic abundance profiles to be proportional to the HCN one, we find at 15° S, and at 83° N, two values that are statistically consistent. A combination of these results yields a ¹²C/¹³C value equal to 75±12. This global result, as well as the 15° S one, envelop the value in Titan's methane (82.3±1) [Niemann, H.B., and 17 colleagues, 2005. Nature 438, 779-784] measured at 10° S and is slightly lower than the terrestrial inorganic standard value (89). The ¹⁴N/¹⁵N isotopic ratio is found equal to at 15° S and at 83° N. Combining the two values yields ¹⁴N/¹⁵N = 56 ± 8, which corresponds to an enrichment in ¹⁵N of about 4.9 compared with the terrestrial ratio. These results agree with the values obtained from previous ground-based millimeter observations [Hidayat, T., Marten, A., Bézard, B., Gautier, D., Owen, T., Matthews, H.E., Paubert, G., 1997. Icarus 126, 170-182; Marten, A., Hidayat, T., Biraud, Y., Moreno, R., 2002. Icarus 158, 532-544]. The ¹⁵N/¹⁴N ratio found in HCN is ∼3 times higher than in N₂ [Niemann, H.B., and 17 colleagues, 2005. Nature 438, 779-784], which implies a large fractionation process in the HCN photochemistry.