A SEM-based method to determine the mineralogical composition and the particle size distribution of suspended sediment

A robust method for characterizing the mineralogy of suspended sediment in continental rivers is introduced. It encompasses 3 steps: the filtration of a few milliliters of water, measurements of X-ray energy dispersive spectra using Scanning Electron Microscopy (SEM), and robust machine learning tools of classification. The method is applied to suspended particles collected from various Amazonian rivers. A total of more than 204,000 particles were analyzed by SEM-EDXS (Energy Dispersive X-ray Spectroscopy), i.e. about 15,700 particles per sampling station, which lead to the identification of 15 distinct groups of mineralogical phases. The size distribution of particles collected on the filters was derived from the SEM micrographs taken in the backscattered electron imaging mode and analyzed with ImageJ freeware. The determination of the main mineralogical groups composing the bulk sediment associated with physical parameters such as particle size distribution or aspect ratio allows a precise characterization of the load of the terrigenous particles in rivers or lakes. In the case of the Amazonian rivers investigated, the results show that the identified mineralogies are consistent with previous studies as well as between the different samples collected. The method enabled the evolution of grain size distribution from fine to coarse material to be described in the water column. Implications about hydrodynamic sorting of mineral particles in the water column are also briefly discussed. The proposed method appears well suited for intensive routine monitoring of suspended sediment in river systems.     

Assessment of the geometry and volumes of small surface water reservoirs by remote sensing in a semi-arid region with high reservoir density

Water fluxes in highly impounded regions are heavily dependent on reservoir properties. However, for large and remote areas, this information is often unavailable. In this study, the geometry and volume of small surface reservoirs in the semi-arid region of Brazil were estimated using terrain and shape attributes extracted by remote sensing. Regression models and data classification were used to predict the volumes, at different water stages, of 312 reservoirs for which topographic information is available. The power function used to describe the reservoir shapes tends to overestimate the volumes; therefore, a modified shape equation was proposed. Among the methods tested, four were recommended based on performance and simplicity, for which the mean absolute percentage errors varied from 24 to 39%, in contrast to the 94% error achieved with the traditional method. Despite the challenge of precisely deriving the flooded areas of reservoirs, water management in highly reservoir-dense environments should benefit from volume prediction based on remote sensing.     

Peat layer accumulation and post‐burial deformation during the mid‐late Holocene in the Po coastal plain (Northern Italy)

Peat horizons are characteristic features of delta plains worldwide. In this study, we tested the use of peat‐based correlations to assess the deformation of Holocene strata in the Po coastal plain (Northern Italy). The Holocene stratigraphy, about 30 km inland from the modern coastline consists of a peat‐bearing, estuarine and deltaic succession, up to 23 m thick. Through the analysis of 31 core data and 100 piezocone penetration tests, we identified and mapped three 10–40 cm‐thick peat layers (T1–T3) dated to 6.6–5.8, 5.5–5.0 and 3.3–2.7 cal kyr BP respectively. These peat horizons were found to be suitable stratigraphic markers within the Holocene succession over an area of about 200 km². The mid‐late Holocene palaeogeography, reconstructed through high‐resolution peat correlation, supported by 72 radiocarbon dates, highlights a typical upper delta plain environment, with ribbon‐shaped distributary channels and swamp interdistributary areas. Peat layers are inclined towards E‐NE with gradients that increase downsection from ~0.016% (T3) to 0.021% (T1). The gradient of the oldest peat horizon is one order of magnitude larger than the slope of the modern delta plain (~0.0025%). We infer that peat horizons accumulated during periods of low sediment supply mainly controlled by autogenic processes and were deformed after deposition. Differential compaction of underlying sedimentary strata and recent tectonic activity of the buried Apenninic thrust systems are the most likely drivers of strata deformation. Based on isochore maps, we document that higher sedimentation rates in topographically depressed areas compensated, in part at least, the ongoing deformation, keeping unaltered the topographic gradient and the depositional environment. This study demonstrates that peat‐based correlation and mapping can shed lights on the mechanisms of strata accumulation and deformation in deltaic settings, constituting a robust basis for reconstructing delta evolution.     

Type Ia Supernovae

Summary. Type Ia Supernovae are in many aspects still enigmatic objects. Their observational and theoretical exploration is in full swing, but we still have plenty to learn about these explosions. Recent years have already witnessed a bonanza of supernova observations. The increased samples from dedicated searches have allowed the statistical investigation of Type Ia Supernovae as a class. The observational data on Type Ia Supernovae are very rich, but the uniform picture of a decade ago has been replaced by several correlations which connect the maximum luminosity with light curve shape, color evolution, spectral appearance, and host galaxy morphology. These correlations hold across almost the complete spectrum of Type Ia Supernovae, with a number of notable exceptions. After 150 days past maximum, however, all observed objects show the same decline rate and spectrum. The observational constraints on explosion models are still rather sparse. Global parameters like synthesized nickel mass, total ejecta mass and explosion energetics are within reach in the next few years. These parameters bypass the complicated calculations of explosion models and radiation transport. The bolometric light curves are a handy tool to investigate the overall appearance of Type Ia Supernovae. The nickel masses derived this way show large variations, which combined with the dynamics from line widths, indicate that the brighter events are also coming from more massive objects. The lack of accurate distances and the uncertainty in the correction for absorption are hampering further progress. Improvements in these areas are vital for the detailed comparison of luminosities and the determination of nickel masses. Coverage at near-infrared wavelengths for a statistical sample of Type Ia Supernovae will at least decrease the dependence on the absorption. Some of the most intriguing features of Type Ia Supernovae are best observed at these wavelengths, like the second peak in the light curve, the depression in the J band, and the unblended [Feii] lines in the ashes. Received 24 January 2000 / Published online 8 May 2000     

Perturbations of the Kepler Problem in Global Coordinates

The usual action-angle variables for the Kepler Problem (the Delaunay variables) are not globally defined, leaving out some orbits (circular orbits or those lying on the xy-plane). Moreover they are trascendental functions of the physical variables, making it quite difficult to write the perturbed Hamiltonian. The way-out proposed here is to pass to a 8-dimensional rank-6 Poisson manifold, that is, to parametrize the state of the Kepler Problem with two 4-dimensional vectors mutually orthogonal and of equal norm. This revised version was published online in July 2006 with corrections to the Cover Date.     

Retrograde mineral and fluid evolution in high-pressure metapelites (Schistes lustrés unit, Western Alps)

Fluid inclusions have been analysed in successive generations of syn-metamorphic segregations within low-grade, high-pressure, low-temperature (HP–LT) metapelites from the Western Alps. Fluid composition was then compared to mass transfer deduced from outcrop-scale retrograde mineral reactions. Two types of quartz segregations (veins) occur in the `Schistes lustrés' unit: early blueschist-facies carpholite-bearing veins (BS) and retrograde greenschist-facies chlorite-bearing veins (GS). Fluid inclusions in both types of segregations are aqueous (no trace of dissolved gases such as CO₂, CH₄, N₂), with significant differences in density and composition (salinity). BS fluids are moderately saline fluids (average 9.1 wt% eq. NaCl) characterized by a chronological trend towards more dilute composition (from 15 down to 0 wt% eq. NaCl), whereas GS fluids have a very constant salinity of ∼3.7 wt% eq. NaCl. Both types of inclusions were continuously reset to lower densities along the retrograde path, until a temperature of ∼300 °C. Mass-balance calculations, together with fluid inclusion data, suggest that GS fluids result from the mixing between two fluid sources: one initial, early metamorphic, moderately saline HP fluid and a second nearly pure water fluid provided by the breakdown of carpholite. Estimates of the amount of water released by carpholite breakdown result in a dilution of the interstitial fluid phase (from 10 to 2.5–4 wt% eq. NaCl) consistent with the actual shift of the fluid composition. Alkali elements required for the formation of the GS chlorite + phengite assemblage after carpholite could be locally provided by HP phengite. This is taken as an indirect evidence that, during the generation of both BS and GS fluids, mixing with externally derived fluids may have been very limited. The location, amount and constant composition of the less saline GS fluids appear to be related to an interconnected porosity at the time of inclusion formation. Received: 19 October 1998 / Accepted: 19 July 2000     

Geophysical exploration for geothermal low enthalpy resources in Lipari Island, Italy

Integrated geophysical surveys were performed in two sites, Fossa di Fuardo and Terme di San Calogero in Lipari Island, Southern Italy with the intent of the exploration of low-enthalpy geothermal fluids. Both sites show strong geochemical and geologic evidences of hydrothermal activity. The geophysical methods consist of two microgravimetric surveys, two 2D geoelectric profiles, a seismic reflection profile and a five seismic refraction profiles. The seismic methods allowed us to locate the main subsurface seismic discontinuities and to evaluate their geometrical relationships. The gravity field was used to constraint the seismic discontinuities, while the electric prospecting let discriminate more conductive areas, which could correspond to an increase in thermal fluid circulation in the investigated sites.The results obtained by the different geophysical methods are in good agreement and permit the definition of a reliable geo-structural model of the subsurface setting of the two investigated areas. A low-enthalpy geothermal reservoir constituted by a permeable pyroclastic and lava sequence underlying two shallow impermeable formations was found at Fossa del Fuardo. The reservoir is intersected by some sub-vertical faults/fractures that probably play an important role in convoying the thermal water up to the surface. At the other site, Terme di S. Calogero, the geophysical surveys showed that an intense circulation of fluids affects the subsurface of the area. This circulation concentrates along a ENE-trending fault located at a little distance from the thermal resort. The hot fluids may upraise along the fault if the width of the ascent area is smaller than 20 m.     

High-pressure behaviour of Ca-rich C 2 /c clinopyroxenes along the join diopside-enstatite (CaMgSi2O6-Mg2Si2O6)

 An in situ high-pressure (HP) X-ray diffraction investigation of synthetic diopside and of the Ca_0.8Mg_1.2Si₂O₆ clinopyroxene (Di₈₀En₂₀) was performed up to respectively P=40.8 and 15.1 GPa, using high brilliance synchrotron radiation. The compression of the cell parameters is markedly anisotropic, with β_b ⋙ β_c > β_a > β_asinβ for any pressure range and for both diopside and Di₈₀En₂₀. The compressibility along the crystallographic axes decreases significantly with pressure and is higher in Di₈₀En₂₀ than in diopside. The β cell parameter decreases as well with pressure, at a higher rate in Di₈₀En₂₀. The cell volume decreases at almost the same rate for the two compositions, since in diopside a higher compression along a* occurs. A change in the mechanism of deformation at P higher than about 5–10 GPa is suggested for both compositions from the analysis of the strain induced by compression. In diopside at lower pressures, the deformation mainly occurs, at a similar rate, along the b axis and at a direction 145° from the c axis on the (0 1 0) plane. At higher pressures, instead, the deformation occurs mostly along the b axis. In Di₈₀En₂₀ the orientation of the strain axes is the same as in diopside. The substitution of Ca with Mg in the M2 site induces at a given pressure a higher deformation on (0 1 0) with respect to diopside, but a similar change in the compressional behaviour is found. Changes in the M2 polyhedron with pressure can explain the above compressional behaviour. A third-order Birch-Murnaghan equation of state was fit to the retrieved volumes, with K=105.1(9) GPa, K′=6.8(1) for diopside and K=107.3(1.4) GPa, K′=5.7(3) for Di₈₀En₂₀; the same equation can be applied for any pressure range. The elasticity of diopside is therefore not significantly affected by Mg substitution into the M2 site, in contrast to the significant stiffening occurring for Ca substitution into Mg-rich orthopyroxenes. Received: 3 January 2000 / Accepted: 21 May 2000     

Methodology of X-ray fluorescence analysis of suspended matter in estuarine waters

Twenty-seven samples of suspended sediments collected on Millipore filters from the St. Lawrence estuary were directly analysed for Si, Al, Ca, Mg, Na, K, Fe, Ti, Mn, Ni, Co, Cu, Cr and Zn by X-ray fluorescence using standards prepared from suspended matter collected by continuous flow centrifugation. Calibration curves prepared from the analysis of these standards could be directly used in calculating the weight percent of elements for the unknown samples, if the weight of the total suspended matter on the filters did not exceed 25 mg.