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241.
J.A. Saunders M.-K. Lee M. Shamsudduha P. Dhakal A. Uddin M.T. Chowdury K.M. Ahmed 《Applied Geochemistry》2008
Here new data from field bioremediation experiments and geochemical modeling are reported to illustrate the principal geochemical behavior of As in anaerobic groundwaters. In the field bioremediation experiments, groundwater in Holocene alluvial aquifers in Bangladesh was amended with labile water-soluble organic C (molasses) and MgSO4 to stimulate metabolism of indigenous SO4-reducing bacteria (SRB). In the USA, the groundwater was contaminated by Zn, Cd and SO4, and contained <10 μg/L As under oxidized conditions, and a mixture of sucrose and methanol were injected to stimulate SRB metabolism. In Bangladesh, groundwater was under moderately reducing conditions and contained ∼10 mg/L Fe and ∼100 μg/L As. In the USA experiment, groundwater rapidly became anaerobic, and dissolved Fe and As increased dramatically (As > 1000 μg/L) under geochemical conditions consistent with bacterial Fe-reducing conditions. With time, groundwater became more reducing and biogenic SO4 reduction began, and Cd and Zn were virtually completely removed due to precipitation of sphalerite (ZnS) and other metal sulfide mineral(s). Following precipitation of chalcophile elements Zn and Cd, the concentrations of Fe and As both began to decrease in groundwater, presumably due to formation of As-bearing FeS/FeS2. By the end of the six-month experiment, dissolved As had returned to below background levels. In the initial Bangladesh experiment, As decreased to virtually zero once biogenic SO4 reduction commenced but increased to pre-experiment level once SO4 reduction ended. In the ongoing experiment, both SO4 and Fe(II) were amended to groundwater to evaluate if FeS/FeS2 formation causes longer-lived As removal. Because As-bearing pyrite is the common product of SRB metabolism in Holocene alluvial aquifers in both the USA and Southeast Asia, it was endeavored to derive thermodynamic data for arsenian pyrite to better predict geochemical processes in naturally reducing groundwaters. Including the new data for arsenian pyrite into Geochemist’s Workbench, its stability field completely dominates in reducing Eh–pH space and “displaces” other As-sulfides (orpiment, realgar) that have been implied to be important in previous modeling exercises and reported in rare field conditions. 相似文献
242.
Kathleen A. Radloff Anya R. Manning Brian Mailloux Yan Zheng M. Moshiur Rahman M. Rezaul Huq Kazi M. Ahmed Alexander van Geen 《Applied Geochemistry》2008
Microbial Fe reduction is widely believed to be the primary mechanism of As release from aquifer sands in Bangladesh, but alternative explanations have been proposed. Long-term incubation studies using natural aquifer material are one way to address such divergent views. This study addresses two issues related to this approach: (1) the need for suitable abiotic controls and (2) the spatial variability of the composition of aquifer sands. Four sterilization techniques were examined using orange-colored Pleistocene sediment from Bangladesh and artificial groundwater over 8 months. Acetate (10 mM) was added to sacrificial vials before sterilization using either (1) 25 kGy of gamma irradiation, (2) three 1-h autoclave cycles, (3) a single addition of an antibiotic mixture at 1× or (4) 10× the typical dose, and (5) a 10 mM addition of azide. The effectiveness of sterilization was evaluated using two indicators of microbial Fe reduction, changes in diffuse spectral reflectance and leachable Fe(II)/Fe ratios, as well as changes in P-extractable As concentrations in the solid phase. A low dose of antibiotics was ineffective after 70 days, whereas autoclaving significantly altered groundwater composition. Gamma irradiation, a high dose of antibiotics, and azide were effective for the duration of the experiment. 相似文献
243.
Ramesh Sivanpillai X. Ben Wu R. Srinivasan Charles T. Smith Michael G. Messina 《GeoJournal》2008,71(4):211-220
Comparing satellite data derived map products are affected by differences in data characteristics, image acquisition dates,
processing techniques, and classification schemes used for assigning pixels to a thematic class. By comparing two forest maps
generated from Landsat Enhanced Thematic Mapper Plus (ETM+) and Advanced Very High Resolution Radiometer (AVHRR) images acquired
on the same day, and processed using identical classification scheme and methods these differences were minimized. The ETM+
derived map had higher classification accuracy values and more precise area estimates than the AVHRR derived map. In the ETM+
derived map, 87 of the 599 verification data were misclassified, whereas in the AVHRR derived map, 155 of the 469 verification
data were misclassified. Detailed error analyses by land cover class revealed that a land use based definition of forest accounted
for 74% (64 out of 87) and 57% (89 out of 155) of the classification errors in ETM+ and AVHRR derived maps, respectively. 相似文献
244.
An increasingly utilized strategy for expanding conservation in the developing world has been the promotion of protected areas
that supersede national borders. Alternatively known as transfrontier biosphere reserves, transfrontier or transboundary conservation
areas, or Peace Parks, these protected areas are aggressively advanced by conservation agencies for their purported ecological
and economic benefits. This article provides a comparative assessment of two case studies to understand the various impacts
of transboundary conservation. The Great Limpopo Transfrontier Park, which unites protected areas in South Africa, Mozambique
and Zimbabwe, is contrasted with efforts to protect jaguars along the United States–Mexico border. We argue that while these
cases are promising for the purposes of biodiversity protection, they demonstrate that transboundary conservation can minimize
political context, contributes to the hegemony of international conservation agendas, and remains closely linked to economic
neoliberalism and decentralization in the developing world.
相似文献
Brian KingEmail: |
245.
S. T. G. Raghukanth 《Natural Hazards》2008,46(1):1-13
In this article, analytical methods have been used to estimate ground motion during the 8 October 2005, Kashmir earthquake.
Peak ground acceleration (PGA) values at several stations in the epicentral region have been estimated by empirical analytical
source mechanism models. As an alternate analysis, PGA estimates have also been obtained using the stochastic finite fault
seismological model. The estimated PGAs are compared with that obtained from damage values. A PGA contour map in the near-source
region is provided. It is found that very near to the epicenter, PGA would have reached more than 1 g. It is demonstrated
that empirical analytical models can be effectively used to estimate ground motion due to rupture of active faults. 相似文献
246.
Implementation of reconstructed geomorphologic units in landslide susceptibility mapping: the Melen Gorge (NW Turkey) 总被引:6,自引:2,他引:4
In the international literature, although considerable amount of publications on the landslide susceptibility mapping exist,
geomorphology as a conditioning factor is still used in limited number of studies. Considering this factor, the purpose of
this article paper is to implement the geomorphologic parameters derived by reconstructed topography in landslide susceptibility
mapping. According to the method employed in this study, terrain is generalized by the contours passed through the convex
slopes of the valleys that were formed by fluvial erosion. Therefore, slope conditions before landsliding can be obtained.
The reconstructed morphometric and geomorphologic units are taken into account as a conditioning parameter when assessing
landslide susceptibility. Two different data, one of which is obtained from the reconstructed DEM, have been employed to produce
two landslide susceptibility maps. The binary logistic regression is used to develop landslide susceptibility maps for the
Melen Gorge in the Northwestern part of Turkey. Due to the high correct classification percentages and spatial effectiveness
of the maps, the landslide susceptibility map comprised the reconstructed morphometric parameters exhibits a better performance
than the other. Five different datasets are selected randomly to apply proper sampling strategy for training. As a consequence
of the analyses, the most proper outcomes are obtained from the dataset of the reconstructed topographical parameters and
geomorphologic units, and lithological variables that are implemented together. Correct classification percentage and root
mean square error (RMSE) values of the validation dataset are calculated as 86.28% and 0.35, respectively. Prediction capacity
of the different datasets reveal that the landslide susceptibility map obtained from the reconstructed parameters has a higher
prediction capacity than the other. Moreover, the landslide susceptibility map obtained from the reconstructed parameters
produces logical results. 相似文献
247.
Nonlinear Analysis of Local Site Effects on Seismic Ground Response in the Bam Earthquake 总被引:1,自引:0,他引:1
M. H. T. Rayhani M. H. El Naggar S. H. Tabatabaei 《Geotechnical and Geological Engineering》2008,26(1):91-100
The influence of local geologic and soil conditions on the intensity of ground shaking is addressed in this study. The amplification
of the ground motion due to local site effects resulted in severe damage to dwellings in the Bam area during the 2003 Bam
Earthquake. A unique set of strong motion acceleration recordings was obtained at the Bam accelerograph station. Although
the highest peak ground acceleration recorded was the vertical component (nearly 1 g), the longitudinal component (fault-parallel
motion) clearly had the largest maximum velocity as well as maximum ground displacement. Subsurface geotechnical and geophysical
(down-hole) data in two different sites have been obtained and used to estimate the local site condition on earthquake ground
motion in the area. The ground response analyses have been conducted considering the nonlinear behavior of the soil deposits
using both equivalent linear and nonlinear approaches. The fully nonlinear method embodied in FLAC was used to evaluate the
nonlinear soil properties on earthquake wave propagation through the soil layer, and compare with the response from the equivalent
linear approach. It is shown that thick alluvium deposits amplified the ground motion and resulted in significant damage in
residential buildings in the earthquake stricken region. The comparison of results indicated similar response spectra of the
motions for both equivalent and nonlinear analyses, showing peaks in the period range of 0.3–1.5 s. However, the amplification
levels of nonlinear analysis were less than the equivalent linear method especially in long periods. The observed response
spectra are shown to be above the NEHRP building code design requirements, especially at high frequencies. 相似文献
248.
T. G. Sitharam Pijush Samui P. Anbazhagan 《Geotechnical and Geological Engineering》2008,26(5):503-517
Geospatial technology is increasing in demand for many applications in geosciences. Spatial variability of the bed/hard rock
is vital for many applications in geotechnical and earthquake engineering problems such as design of deep foundations, site
amplification, ground response studies, liquefaction, microzonation etc. In this paper, reduced level of rock at Bangalore,
India is arrived from the 652 boreholes data in the area covering 220 km2. In the context of prediction of reduced level of rock in the subsurface of Bangalore and to study the spatial variability
of the rock depth, Geostatistical model based on Ordinary Kriging technique, Artificial Neural Network (ANN) and Support Vector
Machine (SVM) models have been developed. In Ordinary Kriging, the knowledge of the semi-variogram of the reduced level of
rock from 652 points in Bangalore is used to predict the reduced level of rock at any point in the subsurface of the Bangalore,
where field measurements are not available. A new type of cross-validation analysis developed proves the robustness of the
Ordinary Kriging model. ANN model based on multi layer perceptrons (MLPs) that are trained with Levenberg–Marquardt backpropagation
algorithm has been adopted to train the model with 90% of the data available. The SVM is a novel type of learning machine
based on statistical learning theory, uses regression technique by introducing loss function has been used to predict the
reduced level of rock from a large set of data. In this study, a comparative study of three numerical models to predict reduced
level of rock has been presented and discussed. 相似文献
249.
Roger T. Trindell 《The Professional geographer》1969,21(5):328-332
250.
A. Tárczy-Hornoch 《Pure and Applied Geophysics》1962,52(1):53-58
Zusammenfassung Es werden mit Hilfe der sphärischen Trigonometrie und der Ausgleichsrechnung Methoden angegeben, die die Berechnung der bestanschmiegenden Ebene an eine Anzahl von Geraden mit einem gemeinsamen Punkt ermöglichen.
Summary With the aid of the spherical trigonometry and the adjustment, methods are given to determin the best-fitting plane for a given set of directions through a common point.相似文献