The composition,structure, and stability of guinier-preston zones in lunar and terrestrial orthopyroxene

Lunar and terrestrial orthopyroxenes (Mg,Fe,Ca)₂Si₂O₆ contain varying abundances of coherent, Ca-enriched Guinier-Preston (G.P.) zones. G.P. zones 5–6 unit cells thick have been found in one lunar sample whereas all other examples (lunar and terrestrial) are only one unit-cell-thick. Electron diffraction maxima from the larger lunar G.P. zones indicate that d ₁₀₀=18.52 Å whereas, d ₁₀₀=18.2 Å for the host. This increase in the a direction corresponds to an increase in calcium content in the G.P. zones over that of the host of ～25 mol% Ca₂Si₂O₆. Diffraction patterns of the hk0 net from an area containing G.P. zones show extra spots (h=2n+1) not observed in the host orthopyroxene (Pbca), that violate the a-glide of the host. The G.P. zones, therefore, have space group Pbc2₁ if it is assumed that the c-glide of pyroxene is retained and the space group of the G.P. zone is a subgroup of Pbca. The loss of the a-glide in the G.P. zones results in 4 distinct silica chains and 4 distinct cation sites M1A, M1B, M2A, M2B; by symmetry, equivalent M2A or M2B sites are clustered together in only one-half of the unit cell. As one-fourth of the divalent cations in the G.P. zones are calcium, ordering of Ca on M2A or M2B would produce a zone 9 Å thick extended parallel to (100) with the composition of Ca(Mg,Fe)Si₂O₆, but constrained by the host to the structure of orthopyroxene. This zone and the Ca-poor half-unit-cell then constitute an 18 Å thick G.P. zone. Heating experiments of varying duration indicate that the zones become unstable with respect to the host orthopyroxene at ～950°C for Wo_0.6 and ～1,050°C for Wo_2.5. The zones are interpreted in terms of the pyroxene subsolidus as a metastable phase having either a solvus relationship with orthopyroxene or originating as a distinct phase. The size, distribution, composition and structure of G.P. zones may be an important indicator of the low-temperature thermal history of orthopyroxene.     

An archaean granulite-grade tonalite-trondhjemite-granite suite from scourie,NW Scotland: Geochemistry and origin

The Lewisian complex of the Scourie-Badcall area is composed predominantly of banded tonalitic gneiss which intrudes layered gabbro-ultramafic complexes. Intrusive into both gabbro and tonalitic gneiss are homogeneous acid sheets which are trondhjemitic to granitic in composition. All rocks were subjected to granulite facies metamorphism. Smooth continuous trends on chemical variation diagrams suggest that the evolution of these rocks was dominated by fractional crystallisation. A scheme is proposed whereby a tonalitic melt was parental to trondhjemite and granite. Variation within tonalites was a function of the fractional crystallisation of hornblende and plagioclase, and trondhjemite was derived from tonalite by the fractional crystallisation of hornblende and/or plagioclase. Granite and granodiorite represent residual liquids which evolved along the quartz-feldspar cotectic surface; they were derived by the fractional crystallisation of plagioclase from a trondhjemite liquid. Some trondhjemitic sheets are quartz-plagioclase residues from which a granitic melt was removed. The associated gabbros and ultramafic rocks are not directly related to the proposed fractional crystallisation scheme and are not crystal residues removed from the tonalitic melt. Tonalites were probably derived from a basaltic source by partial melting or fractional crystallisation with either hornblende and/or garnet as residual phases.     

The physics of precipitation in cumulus clouds

Summary Over the past several years, the University of Chicago has conducted a program of research into the physics and chemistry of cumulus cloud precipitation. From these measurements it has been possible to isolate the sublimation-coalescence mechanism (Bergeron process) from the condensation-coalescence mechanism and to estimate the relative role of each process in the formation of rain n cumulus clouds. It is found that size of cloud capable of raining is a strong function of geography, that the environment of the cloud is very important in determining the probability of rain and that liquid water content is one of the most important within-cloud parameters.An essential part of the research concerned cloud treatment. Definite, positive treatment effects were demonstrated for rain initiation through coalescence using water spray. No effects were detectable from dry ice seeding of subcooled clouds, although any such effects may have been obscured by sample size (27 cloud pairs).Text of paper presented before Physical Society and Royal Meteorological Society Joint Conference on Cloud Physics, London, England, Jan. 4–5, 1956. The research reported in this paper has been sponsored by the Geophysics Research. Directorate of the Air Force Cambridge Research Center, Air Research and Development Command under Contract Nos. AF 19 (604)-618 and AF 19 (604)-1388.     

Evaluation of Weather Catastrophe Data for Use in Climate Change Investigations

A 1950–1994 data set of major weather losses developed by the property insurance industry was examined to assess its potential utility in climate change research and use in assessing the relevance of recent extreme losses in the United States. A process for adjusting these historical storm losses to ever-changing factors including dollar values, amount of insurance coverage per area, and the sensitivity of society to damaging storms was developed by the industry. Analysis of the temporal frequency and losses of these adjusted weather catastrophes revealed differences according to the amount of loss. Temporal changes since 1975 in the catastrophes causing $35 to $100 million in loss were strongly related to changes in U.S. population, whereas catastrophes that created insured losses greater than $100 million appear related to both shifting weather conditions and to regional population changes. This evaluation revealed that the industry's catastrophe adjustment technique did not adequately allow for changes in various demographic and social factors affecting damage; however, results suggest use of population values for normalizing the adjusted catastrophe database to allow meaningful studies of their temporal variability.     

A flexible climate model for use in integrated assessments

 Because of significant uncertainty in the behavior of the climate system, evaluations of the possible impact of an increase in greenhouse gas concentrations in the atmosphere require a large number of long-term climate simulations. Studies of this kind are impossible to carry out with coupled atmosphere ocean general circulation models (AOGCMs) because of their tremendous computer resource requirements. Here we describe a two dimensional (zonally averaged) atmospheric model coupled with a diffusive ocean model developed for use in the integrated framework of the Massachusetts Institute of Technology (MIT) Joint Program on the Science and Policy of Global Change. The 2-D model has been developed from the Goddard Institute for Space Studies (GISS) GCM and includes parametrizations of all the main physical processes. This allows it to reproduce many of the nonlinear interactions occurring in simulations with GCMs. Comparisons of the results of present-day climate simulations with observations show that the model reasonably reproduces the main features of the zonally averaged atmospheric structure and circulation. The model’s sensitivity can be varied by changing the magnitude of an inserted additional cloud feedback. Equilibrium responses of different versions of the 2-D model to an instantaneous doubling of atmospheric CO₂ are compared with results of similar simulations with different AGCMs. It is shown that the additional cloud feedback does not lead to any physically inconsistent results. On the contrary, changes in climate variables such as precipitation and evaporation, and their dependencies on surface warming produced by different versions of the MIT 2-D model are similar to those shown by GCMs. By choosing appropriate values of the deep ocean diffusion coefficients, the transient behavior of different AOGCMs can be matched in simulations with the 2-D model, with a unique choice of diffusion coefficients allowing one to match the performance of a given AOGCM for a variety of transient forcing scenarios. Both surface warming and sea level rise due to thermal expansion of the deep ocean in response to a gradually increasing forcing are reasonably reproduced on time scales of 100–150 y. However a wide range of diffusion coefficients is needed to match the behavior of different AOGCMs. We use results of simulations with the 2-D model to show that the impact on climate change of the implied uncertainty in the rate of heat penetration into the deep ocean is comparable with that of other significant uncertainties. Received: 10 March 1997 / Accepted: 20 October 1997     

Mean Profiles of Moisture Fluxes in Snow-Filled Boundary Layers

Profiles of moisture fluxes have been examined for convective boundary layers containing clouds and snow, using data derived from aircraft measurements taken on four dates during the 1983/1984 University of Chicago lake-effect snow project. Flux profiles were derived from vertical stacks of aircraft cross-wind flight legs taken at various heights over Lake Michigan near the downwind shore. It was found that, if ice processes are taken into account, profiles of potential temperature and water content were very similar to those presented in past studies of convective boundary layers strongly heated from below. Profiles of total water content and equivalent potential temperature adjusted for ice were nearly invariant with height, except very near the top of the boundary layer, suggesting that internal boundary-layer mixing processes were rapid relative to the rates at which heat and vapour were transported into the boundary layer through entrainment and surface fluxes. Ice was found to play a significant, measurable role in boundary-layer moisture fluxes. It was estimated that 40 to 57% of the upward vapour flux was returned to the surface in the form of snow, converting about 45 to 64% of the surface latent heat flux into sensible heat in the snow-producing process. Assuming advective fluxes are relatively small (thought to be appropriate after the first few tens of km over the lake as suggested by past studies), the boundary layer was found to warm at a rate faster than could be explained by surface heat fluxes and latent heat releases alone, the remainder of the heating presumably coming from radiational processes and entrainment. Discussions of moisture phase change processes throughout the boundary layer and estimates of errors of these flux measurements are presented.