Formation of silica oncoids around geysers and hot springs at El Tatio, northern Chile

Siliceous oncoids, up to 4 cm in diameter, are common on the laterally extensive sinter aprons that surround the spectacular geysers and hot springs at El Tatio in northern Chile. Many of these complex oncoids developed close to geyser and spring vents that discharge boiling water. Internally the oncoids, which are composed of precipitated amorphous silica, are formed of complex arrays of spicules and concentric laminae as well as detrital volcanic grains. Spicular growth is dominant in most examples. The formation and growth of the spicules and concentric laminae were mediated by a microbial community which included filamentous microbes, mucus, and possibly bacteria. The microbes and mucus were silicified by replacement and encrustation. In some laminae the filamentous microbes lay parallel to the growth surface; in other laminae most filaments forming the thin mats were suberect. Amorphous silica precipitated between the filaments occluded porosity and commonly disguised the microbial fabric. The oncoids grew on the proximal sinter aprons around the geyser vents and hot spring pools. Most growth took place subaerially with the silica delivered to the precipitation sites by splashing water from the geysers and/or periodic shallow flooding of the discharge aprons. Unlike silica oncoids at other geothermal sites, vertical growth of oncoids that formed in some rimstone pools was not limited by water depth.     

Redetermination of the transformation enthalpies of the xanthoconite–proustite, pyrostilpnite–pyrargyrite and trechmannite–smithite phase transitions

 We report here refined values of the transformation enthalpy for xanthoconite to proustite (54.81 kJ/mol) and pyrostilpnite to pyrargyrite (40.32 kJ/mol). Additionally, the enthalpy for the transformation of trechmannite to smithite (5.82 kJ/mol) has been determined. The refinement was possible by taking into account a previously unknown dependence of electrochemical signals on the amount of substance undergoing the reduction process. Received December 21, 1995/Revised, accepted June 29, 1996     

The Organization of Production in High Technology Industries: An Empirical Assessment*

Recent attention given to the concept of vertical integration and disintegration of production processes has identified the existence of a continuum, with small, flexibly specialized producers at one end and large, mass production units at the other end. Firms along the continuum constantly strive for the optimum combination of economies of scale and scope. This paper attempts to identify the organizational characteristics of high technology firms in one industrial complex of the U.S. Manufacturing Belt. A principal components analysis is performed on a number of theoretically relevant variables for a sample of high technology establishments in Northeast Ohio. The results indicate that the region contains a variety of organizational forms ranging from isolated workshops to large, vertically integrated assembly plants. These findings conform to expectations derived from recent conceptualizations in the literature. Additional empirical research will further enhance understanding of the processes that shape the organization of production in territorial complexes.