Nicholas Crisp's “Porcellien”: A petrological comparison of sherds from the Vauxhall (London; ca. 1751–1764) and Indeo Pottery (Bovey Tracey,Devonshire; ca. 1767–1774) factory sites

The character of porcelain wares made by Nicholas Crisp early and late in his career was assessed using microchemical and petrographic data for sherds excavated from the sites of the factories he operated at Vauxhall and Bovey Tracey. The results indicate that, over time, Crisp increasingly made use of diverse types of pastes as he struggled to produce a commercially viable line of porcelain. Based on the analysis of a limited number of samples, he appears to have largely restricted himself at Vauxhall to using soapstone (Mg‐rich)‐ and flint‐glass (Pb‐rich) frit‐bearing pastes that varied in the amount of calcite they contained. He also experimented with Mg+Pb‐rich pastes at Bovey Tracey, but included a novel ingredient (barite) and varied the proportion of other minor constituents (e.g., bone ash), apparently in an effort to resolve some of the firing problems that plagued him at Vauxhall. In addition, Crisp appears to have produced bone ash (phosphatic) porcelain at Bovey Tracey, and, in collaboration with William Cookworthy, the proprietor of the Plymouth factory, fired a range of true porcelain (Si+Al‐rich) pastes. Bulk compositional data indicate that Crisp's diopside‐bearing Mg+Pb‐rich wares were derived from pastes containing talc and calcite rather than dolomite. The mineralogy of these and some contemporary magnesian/plombian porcelains are interpreted using the SiO₂‐CaO‐MgO phase diagram. This diagram shows that these wares can form and preserve diopside (Ca‐Mg silicate) given suitable bulk CaO contents and kiln‐firing temperatures. Phosphatic sherds from Bovey Tracey are compositionally distinct (lower SiO₂ and higher Al₂O₃ and bone‐ash components) from a single bone‐ash sample from Vauxhall, indicating that Crisp experimented with novel bone‐ash pastes, and was not positively influenced by the Vauxhall phosphatic recipe, if indeed one existed. True porcelains from Bovey Tracey have more extreme SiO₂/Al₂O₃ ratios (= 2.0 [two sherds]; 4.5 [one sherd]) than their Plymouth/Bristol counterparts (SiO₂/Al₂O₃ = 2.3–3.0). Collectively, the analytical data underscore the experimental—and ultimately unsuccessful—character of the diverse wares produced by Nicholas Crisp. © 2000 John Wiley & Sons, Inc.     

The need for and use of socio-economic scenarios for climate change analysis: A new approach based on shared socio-economic pathways

Socio-economic scenarios constitute an important tool for exploring the long-term consequences of anthropogenic climate change and available response options. A more consistent use of socio-economic scenarios that would allow an integrated perspective on mitigation, adaptation and residual climate impacts remains a major challenge. We assert that the identification of a set of global narratives and socio-economic pathways offering scalability to different regional contexts, a reasonable coverage of key socio-economic dimensions and relevant futures, and a sophisticated approach to separating climate policy from counter-factual “no policy” scenarios would be an important step toward meeting this challenge. To this end, we introduce the concept of “shared socio-economic (reference) pathways”. Sufficient coverage of the relevant socio-economic dimensions may be achieved by locating the pathways along the dimensions of challenges to mitigation and to adaptation. The pathways should be specified in an iterative manner and with close collaboration between integrated assessment modelers and impact, adaptation and vulnerability researchers to assure coverage of key dimensions, sufficient scalability and widespread adoption. They can be used not only as inputs to analyses, but also to collect the results of different climate change analyses in a matrix defined by two dimensions: climate exposure as characterized by a radiative forcing or temperature level and socio-economic development as classified by the pathways. For some applications, socio-economic pathways may have to be augmented by “shared climate policy assumptions” capturing global components of climate policies that some studies may require as inputs. We conclude that the development of shared socio-economic (reference) pathways, and integrated socio-economic scenarios more broadly, is a useful focal point for collaborative efforts between integrated assessment and impact, adaptation and vulnerability researchers.     

Effects of forest land management on erosion and revegetation after the eruption of Mount St. Helens

The 1980 eruption of Mount St. Helens covered soils with a tephra blanket and killed the forest tree cover in a 550 km² area. After the eruption, rates of sheetwash and rill erosion, and plant cover were measured on tephra-covered hillslopes which had been subject to three land-management practices: grass seeding; scarification, and salvage logging. On rapidly-eroding hillslopes subject to grass seeding, limited plant covers were established only after erosion had declined sharply. Logging of trees downed by the eruption and scarification of previously logged surfaces slowed erosion, although the effect was small because erosion rates had already slowed substantially by the time these two practices were implemented. The factors controlling erosion, revegetation, and their relative timing at Mount St. Helens are similar to those following explosive volcanic eruptions elsewhere, suggesting that grass seeding is not likely to be effective at slowing erosion following most tephra eruptions, and that early mechanical disturbance could be an effective erosion-control measure. The results also indicate that even without deliberate conservation measures, processes which mechanically disturb a surface layer of low hydraulic conductivity (such as frost-action or trampling) can radically reduce runoff and erosion before revegetation has an important effect.     

Particle dislodgement from a flat sand bed by wind

The rate, with respect to area and time, at which grains are dislodged from a sand bed for given wind conditions is an important factor in determining the grain transport rate and the intensity of grain activity in each of the transport modes. The literature of the subject contains little direct information about particle dislodgement. The paper describes a series of experiments in which dyed sand grains, spread on the surface of quartz dune sand in a wind-tunnel, were photographed at five second intervals while the sand was exposed to wind. The data on rate of loss of coloured grains was used, for two of three chosen size fractions, to deduce the dislodgement rate for each size fraction. The variation of this dislodgement rate with shear velocity is shown graphically for values of u_* between 24 cm s^?1 and 50 cm s^?1. Because of the artificial method of distribution of the coloured sand grains, the results should be applied with caution to natural conditions. The interpretation of the observations of dyed grain loss involved the numerical simulation of the process which comprises removal of coloured grains, slightly offset by replenishment as upwind coloured grains settle briefly in the observed zone. An estimation of grain excursion length has to be incorporated in the simulation. This estimation was made by trial, but general corroboration was found from earlier work. Comparisons are made between dislodgement rates obtained thus and rates estimated by Anderson (1986) and by Jensen and Sorensen (1986). Reasonable agreement with the latter is found in the u_* range 30 cm s^?1.     

Sulphur isotope equilibrium during sulphur hydrolysis at high temperatures

Studies of the sulphur hydrolysis reaction, 4S + 4H₂O /ag 3H₂S + HSO₄^? + H⁺, were conducted between 200 and 320°C in sealed silica glass tubes. The isotope exchange reaction: H₂¹⁸O + HS¹⁶O₄^? /ag H₂¹⁶O + HS¹⁸O₄^? is so rapid at the low pH (1.5–3) as to be unquenchable. However, the sulphur isotope exchange reaction: H₂³⁴S+ H³²SO₄^? /ag H₂³²S + H³⁴SO₄^? gave t12 values of 0.1, 0.3 and 1.7 days at 320, 260 and 200°C respectively and equilibrium H₂S - HSO₄^? sulphur isotope fractionation values of 20.9, 22.4, 24.8, 26.7 and 29.3‰ at 320, 290, 260, 230 and 200°C respectively. This latter data is represented by: 1000lnα_(HSO4^??H2S) = 5.07 (10⁶T^?2) + 6.33, and has valuable applications in geothermal and ore deposit studies.     

Rivers in Australia

As a continent, Australia is unusual. It has a long history of habitation by a relatively small population of Aboriginals with a low technology culture. Just over 200 years ago, in 1788, it was invaded by a technological society from the UK, and the settlers brought with them an understanding of rivers and the landscapes in which they were situated which was quite at odds with the reality of the Australian continent. Australia is a piece of old continental crust derived from the break-up of Gondwana that, unlike other Gondwana continents, has experienced little tectonic modification since the break-up. It is a low relief continent dominated by arid and semi arid climates. Australian river systems have poor slope-channel coupling and poor hydrological connectivity and are characterized by low rates of sediment delivery. The flow of Australian rivers has high interannual variability, two to three times that of comparable rivers elsewhere, and highly variable flood behavior. In this paper, examples are given of particular Australian rivers to illustrate the manner in which the morphological and climatic characteristics of the continent combine to produce some distinctive river systems.     

Towards a model for the in situ origin of PGE reefs in layered intrusions: insights from chromitite seams of the Rum Eastern Layered Intrusion, Scotland

The current debate on the origin of platinum-group element (PGE) reefs in layered intrusions centres mostly on gravity settling of sulphide liquid from overlying magma versus its introduction with interstitial melt/fluids migrating upward from the underlying cumulate pile. Here, we show that PGE-rich chromitite seams of the Rum Eastern Layered Intrusion provide evidence for an alternative origin of such deposits in layered intrusions. These laterally extensive 2-mm-thick chromitite seams occur at the bases of several cyclic mafic–ultramafic units and show lithological and textural relationships suggesting in situ growth directly at a crystal–liquid interface. This follows from chromitite development along the edges of steeply inclined culminations and depressions at unit boundaries, even where these are vertically oriented or overhanging. High concentrations of PGE (up to 2–3 ppm Pd + Pt) are controlled by fine-grained base-metal sulphides, which are closely associated with chromitite seams. The following sequence of events explains the origin of the PGE-rich chromitite seams: (a) emplacement of picritic magma that caused thermal and mechanical erosion of underlying cumulate, followed by in situ growth of chromite against the base, (b) precipitation of sulphide droplets on chromite grains acting as favourable substrate or catalyst for sulphide nucleation, (c) the scavenging of PGE by sulphide droplets from fresh magma continuously brought towards the base by convection. Since the rate of magma convection is 10⁵–10⁷ times higher than that of the solidification (km/year to km/day versus 0.5–1.0 cm/year), the in situ formed sulphide droplets can equilibrate with picritic magma of thousands to million times their own volume. As a result, the sulphide-bearing rocks are able to reach economic concentrations of PGE (several ppm). We tentatively suggest that the basic principles of our model may be used to explain the origin of PGE-rich chromitites and classical PGE reefs in other layered mafic–ultramafic intrusions.     

Constraints on the structure and dynamics of the β-cristobalite polymorphs of SiO2 and AlPO4 from 31P, 27Al and 29Si NMR spectroscopy to 770 K

Nuclear magnetic resonance spectroscopic data are presented for the cristobalite polymorphs of AlPO₄ and SiO₂ from RT to 770 K, through their respective α-β transitions. The nuclear magnetic resonance (NMR) data include chemical shifts for ³¹P, ²⁷Al, and ²⁹Si, ²⁷Al quadrupole coupling parameters, and ³¹P and ²⁷Al spin-lattice relaxation rates. Also presented are electron diffraction patterns of β-cristobalite AlPO₄ that show diffuse scattering similar to that reported previously for SiO₂. For the α-phases of both AlPO₄ and SiO₂, the chemical shifts decrease approximately linearly with increasing temperature from RT to T_c and discontinuously by -2 to -3 ppm from α to β. This result is consistent with a small, continuous increase in the mean T-O-T angle (〈θ〉) of the α-phases with increasing T and an increase of 〈θ〉 by about 4° across the α-β transition for both cristobalite and its AlPO₄ analogue. Based on the ²⁹Si chemical shifts, the mean Si-O-Si angle for β-cristobalite is 152.7±1° near T_c. For AlPO₄-cristobalite, the ²⁷Al nuclear quadrupole coupling constant (C_Q) decreases approximately linearly from 1.2 MHz at RT to 0.94 MHz near T_c (493±10 K). At the α-β transition the ²⁷Al C_Q approaches zero, in agreement with the cubic average structure observed by diffraction. The satellite transitions retain a small frequency distribution above the α-β transition from electric field gradients attributed to defects. The short-range cubic symmetry of the Al-site and non-linear Al-O-P angle support a dynamically disordered model of the β-cristobalite structure. Complete averaging of the ²⁷Al quadrupole coupling in the β-phase indicates that the lifetime of any short-range ordered domains must be shorter than about 1 μs.     

High‐frequency precipitation and stream water quality time series from Plynlimon,Wales: an openly accessible data resource spanning the periodic table

This scientific briefing announces the availability of a new multi‐element high‐frequency water quality data set that is openly accessible to the research community. The data set comprises up to 2 years of 7‐hourly water quality data for two streams and one rainfall site in the Upper Severn catchment at Plynlimon in Mid‐Wales. The measurements cover 50 analytes ranging from H⁺ to U and spanning six orders of magnitude in concentration, including major, minor and trace elements as well as nutrients, and they complement decades of weekly measurements of the same analytes at the Upper Severn. Together, the weekly and 7‐hourly time series provide a unique data set for studying both long‐term trends and short‐term dynamics. The data show complex behaviour over a wide range of timescales, challenging our understanding of catchment processes and informing future modelling efforts. Copyright © 2013 John Wiley & Sons, Ltd.     

Effects of the invasive plant Lupinus polyphyllus on vertical accretion of fine sediment and nutrient availability in bars of the gravel-bed Paloma river

Floodplain vegetation is fundamental in fluvial systems, controlling river corridor geomorphology and ecology through a series of hydraulic, sedimentological, and biological processes. Changes caused by introduced plant species can thus result in shifts in river regime, succession trajectories and nutrient availability, affecting native biodiversity. The exotic bigleaf or marsh lupine Lupinus polyphyllus, introduced in Patagonia in the last decades, is aggressively invading fluvial corridors. It fills unoccupied ecological niches in southern Chilean rivers, due to its capacity for nitrogen fixation, its perennial habit, and high shoot density and leaf surface area.We investigated the effects of L. polyphyllus on vertical accretion of fine sediment, and soil carbon and nitrogen content, on gravel bars of the Paloma river, Chilean Patagonia, where lupine is believed to have been introduced in 1994. We sampled plot pairs with and without lupine, with each pair located at the same elevation above river stage, and plots distributed over the reach scale. We measured the thickness of the fine soil horizon, grain size distribution, and soil carbon and nitrogen content. We also compared aerial photographs to evaluate changes in spatial coverage of lupine along the study reach.Presence of lupine was strongly correlated with a thicker layer of finer sediment, in turn characterized by higher organic carbon, carbon to nitrogen ratio, and inorganic carbon content. Contrary to our expectations, we did not find any significant differences in total nitrogen. Aerial photographs did not reveal important differences in coverage between 2007 and 2010, but plant density appears to have increased between the two dates, and invaded gravel bars also appear to be more stable. Lupine dominance of otherwise sparsely vegetated gravel bars in Patagonian rivers appears to have greatest consequences on bar physical structure (increased rates of accretion of fines) and secondary repercussions on soil quality (increase in recalcitrant organic matter), with potential transient effects on nutrient availability (possible increased soil metabolism, followed by carbon mineralization and loss of lupine nitrogen subsidy).