A lagoonal interlude with occasional hypersalinity in the deposition of the Early–Middle Miocene Brasso Formation of Trinidad

An outcrop of the Early–Middle Miocene age Brasso Formation along the Guaico-Tamana Road of Trinidad was logged and sampled for 20 m at 1 m intervals. The log revealed two sand- and silt-rich successions separated by a claystone-rich interval with thinner sands. One horizon yielded gypsum that is concluded to indicate that conditions occasionally became hypersaline. With the exception of one laminated siltstone interval ～1 m thick, all the beds lacked primary sedimentary structures, but many contained much mollusc debris. The lack of primary structures is thought to reflect bioturbation. Pyrite was common throughout much of the section, but replaced by hematite in two intervals. The pyrite is indicative of anoxic conditions in the sediment below the bioturbated layer, while the hematite shows that conditions occasionally became strongly oxic. The development of low-diversity benthonic foraminiferal communities dominated by porcellaneous-walled Quinqueloculina seminulangulata supports a model of occasional hypersalinity. These conditions are concluded to have developed in a leaky lagoon situated between the carbonate bioherms of the Tamana Formation of Central Trinidad and the mountainous allochthon of the Northern Range. Occasional high numbers of planktonic foraminifera are suggested to result from onshore winds blowing surface seawater into the lagoon. The lagoonal interlude came at the end of a tectonically-induced transgressive–regressive cycle. The influence of tectonics on the deposition of the Brasso Formation complicates at least for the Early–Middle Miocene any attempt to tie the sequence stratigraphy of Trinidad to a global sea-level model. It remains to be seen how much this is true for the remainder of the Neogene succession.     

An assessment of the utility of regional diatom‐based tidal‐level transfer functions

In order to understand natural sea‐level variability, and to enhance future predictions, accurate and precise estimates of Holocene tidal levels are required. Although the application of diatom‐based transfer functions can yield such data, these work best when underpinned by local training sets. Urbanized estuaries offer little prospect of obtaining local training sets and, instead, the reliability of regional transfer functions has to be assessed. The performance of a published regional (UK) diatom‐based tidal‐level transfer function applied to fossil assemblages from two contrasting core sites in the Mersey Estuary, UK, is assessed using modern analogue techniques and sediment isotope data. We find that, although estimated tidal levels coincide with changes in organic matter source, the frequent lack of modern analogues mean that palaeotide estimates are without basis. This is likely a consequence of the site‐specific nature of diatom assemblages in higher intertidal and supratidal areas in particular, where local factors are expected to exert a greater control on their ecology. This situation may be partly resolved by constructing and applying much larger regional training sets from multiple higher intertidal and supratidal sites (where intact). Otherwise the application of alternative techniques, such as regional foraminiferal tidal‐level transfer functions, may be more appropriate. Copyright © 2011 John Wiley & Sons, Ltd.     

A simple and general methodology to calibrate seismic instruments for debris flow quantification: application to Cotopaxi and Tungurahua volcanoes (Ecuador)

Debris flows are hazardous phenomena occurring at volcanoes, and monitoring them has proved as challenging as imperative in several cases. The use of seismic instruments to measure and study the physical properties of debris flows has witnessed significant progress in the last years, with the use of improved sensors, innovative methodologies and high-resolution analysis. However, the application of such studies to the practical task of providing early warnings remains limited by the significant amount of infrastructural and technological resources commonly required for their deployment. In Ecuador, debris flows at volcanoes are detected by means of seismic instruments which are usually part of broader monitoring networks, thus requiring calibration to provide quantitative information about the flows and feed early-warning systems. In the present work, a theoretical approach based on the Buckingham Π-theorem is used to determine an expression that linearly correlates the seismic signal produced by a transiting debris flow with its discharge rate, for instruments installed in different substrata and at variable distances from the drainage. The expression is experimentally tested with Acoustic Flow Monitors and Broad-band seismometers installed in the vicinity of drainages at Tungurahua and Cotopaxi volcanoes, where actual debris flows occurred in relation to eruptive activity. The experiments consist in comparing the measured peak amplitude values of the seismic signal envelopes with the estimated peak discharge rates of several events. The results confirm the validity of the theoretical expression with linear correlations observed between the seismic amplitudes and the discharge rates, thus defining calibration expressions that can be generally applied to varied environments and instruments. The seismic instruments calibrated through this methodology can provide instantaneous and reliable predictions of debris flow discharge rates within less than an order of magnitude and only requiring limited data processing and storage. Such level of prediction could help to improve early warning systems based on seismic instruments installed in locations where more developed instrumental arrays are unavailable or unpractical.

     

Behaviour of Instrumented Hollow Auger Pile Groups in Sandy Soil

Geotechnical and Geological Engineering - Hollow auger piles are a new solution technique being used more often in recent years as a foundation for buildings of 15 floors or less in the coastal...     

40Ar/39Ar age of material returned from asteroid 25143 Itokawa

The Hayabusa mission to asteroid 25143, Itokawa, brought back 2000 small particles, which most closely resemble material found in LL4‐6 chondrites. We report an ⁴⁰Ar/³⁹Ar age of 1.3 ± 0.3 Ga for a sample of Itokawa consisting of three grains with a total mass of ~2 μg. This age is lower than the >4.0 Ga ages measured for 75% of LL chondrites but close to one for Y‐790964 and its pairs. The flat ⁴⁰Ar/³⁹Ar release spectrum of the sample suggests complete degassing 1.3 Ga ago. Recent solar heating in Itokawa's current orbit does not appear likely to have reset that age. Solar or impact heating 1.3 Ga ago could have done so. If impact heating was responsible, then the 1.3 Ga age sets an upper bound on the time at which the Itokawa rubble pile was assembled and suggests that rubble pile creation was an ongoing process in the inner solar system for at least the first 3 billion years of solar system history.     

The acid catalyzed nitration of methanol: formation of methyl nitrate via aerosol chemistry

The aqueous phase acid-catalyzed reaction of methanol (CH₃OH) with nitric acid (HNO₃) to yield methyl nitrate (CH₃ONO₂) under atmospheric conditions has been investigated using gas-phase infrared spectroscopy. Reactions were conducted in aqueous sulfuric acid solutions (50.5–63.6 wt.%) with [CH₃OH] = 0.00005–0.005 M and [HNO₃] = 0.02–0.21 M, at 278.2–328.6 K. Methyl nitrate production rates increased linearly with CH₃OH and HNO₃ concentrations and exponentially with sulfuric acid weight percent within the regime studied. Rates increased linearly with nitronium ion concentration, indicating that the reaction involves as the nitrating agent under these conditions. At 298 K, the rate of methyl nitrate production can be calculated from k _obs [CH₃OH][HNO₃], where k _obs  = 2.337 × 10⁻¹³(exp(0.3198*wt.% H₂SO₄)) when the solubility of CH₃ONO₂ in acidic solution is approximated by H* for pure water. The temperature dependence of the rate coefficient is related to solution composition, with activation energies of 59 and 49 kJ/mol at 51.1 and 63.6 wt.% H₂SO₄, respectively, when k is calculated from rate. The temperature dependence has also been parameterized for application to the atmosphere, but the small quantities of present in aerosol particles will result in methyl nitrate production rates too small to be of significance under most atmospheric conditions. An erratum to this article can be found at     

Monument-antenna effects on GPS coordinate time series with application to vertical rates in Antarctica

We examine the electromagnetic coupling of a GPS antenna–monument pair in terms of its simulated affect on long GPS coordinate time series. We focus on the Earth and Polar Observing System (POLENET) monument design widely deployed in Antarctica and Greenland in projects interested particularly in vertical velocities. We base our tests on an absolute robot calibration that included the top ~0.15 m of the monument and use simulations to assess its effect on site coordinate time series at eight representative POLENET sites in Antarctica over the period 2000.0–2011.0. We show that the neglect of this calibration would introduce mean coordinate bias, and most importantly for velocity estimation, coordinate noise which is highly sensitive to observation geometry and hence site location and observation period. Considering only sub-periods longer than 2.5 years, we show vertical site velocities may be biased by up to ±0.4 mm/year, and biases up to 0.2 mm/year may persist for observation spans of 8 years. Changing between uniform and elevation-dependent observation weighting alters the time series but does not remove the velocity biases, nor does ambiguity fixing. The effect on the horizontal coordinates is negligible. The ambiguities fixed series spectra show noise between flicker and random walk with near-white noise at the highest frequencies, with mean spectral indices (frequencies <20 cycles per year) of approximately −1.3 (uniform weighting) and −1.4 (elevation-dependent weighting). While the results are likely highly monument specific, they highlight the importance of accounting for monument effects when analysing vertical coordinate time series and velocities for the highest precision and accuracy geophysical studies.