Discussion: Structural and stratigraphic problems of the Argylla Formation near Mary Kathleen,Queensland

Circumstantial evidence indicates that Gaussberg, an isolated, 370 m high volcanic cone on the Antarctic coast at 57°S, 89°E, is the product of subglacial eruption. The vesicular, highly potassic leucitite, of which Gaussberg is composed, has been dated by K‐Ar and fission‐track methods, the former being applied to leucite concentrates, the latter to glassy leucitite from the ropy‐textured, outer rind of a pillow‐like structure. The K‐Ar geochronology yields an average date of 56 000 ± 5000 years, jwhich is interpreted as defining the time of Gaussberg's formation. The fission‐track work yields a less precise date, which supports the K‐Ar age estimate. These new age determinations indicate that previously published K‐Ar age determinations of 20 Ma and 9 Ma for Gaussberg should be rejected.     

Quantifying and relating land-surface and subsurface variability in permafrost environments using LiDAR and surface geophysical datasets

The value of remote sensing and surface geophysical data for characterizing the spatial variability and relationships between land-surface and subsurface properties was explored in an Alaska (USA) coastal plain ecosystem. At this site, a nested suite of measurements was collected within a region where the land surface was dominated by polygons, including: LiDAR data; ground-penetrating radar, electromagnetic, and electrical-resistance tomography data; active-layer depth, soil temperature, soil-moisture content, soil texture, soil carbon and nitrogen content; and pore-fluid cations. LiDAR data were used to extract geomorphic metrics, which potentially indicate drainage potential. Geophysical data were used to characterize active-layer depth, soil-moisture content, and permafrost variability. Cluster analysis of the LiDAR and geophysical attributes revealed the presence of three spatial zones, which had unique distributions of geomorphic, hydrological, thermal, and geochemical properties. The correspondence between the LiDAR-based geomorphic zonation and the geophysics-based active-layer and permafrost zonation highlights the significant linkage between these ecosystem compartments. This study suggests the potential of combining LiDAR and surface geophysical measurements for providing high-resolution information about land-surface and subsurface properties as well as their spatial variations and linkages, all of which are important for quantifying terrestrial-ecosystem evolution and feedbacks to climate.     

A cluster-optimizing regression-based approach for precipitation spatial downscaling in mountainous terrain

Precipitation temporal and spatial variability often controls terrestrial hydrological processes and states. Common remote-sensing and modeling precipitation products have a spatial resolution that is often too coarse to reveal hydrologically important spatial variability. A statistical algorithm was developed for downscaling low-resolution spatial precipitation fields. This algorithm auto-searches precipitation spatial structures (rain-pixel clusters), and orographic effects on precipitation distribution without prior knowledge of atmospheric setting. It is composed of three components: rain-pixel clustering, multivariate regression, and random cascade. The only required input data for the downscaling algorithm are coarse-pixel precipitation map and a topographic map. The algorithm was demonstrated with 4 km × 4 km Next Generation Radar (NEXRAD) precipitation fields, and tested by downscaling NEXRAD-aggregated 16 km × 16 km precipitation fields to 4 km × 4 km pixel precipitation, which was then compared to the original NEXRAD data. The demonstration and testing were performed at both daily and hourly temporal resolutions for the northern New Mexico mountainous terrain and the central Texas Hill Country. The algorithm downscaled daily precipitation fields are in good agreement with the original 4 km × 4 km NEXRAD precipitation, as measured by precipitation spatial structures and the statistics between the downscaling and the original NEXRAD precipitation maps. For three daily precipitation events, downscaled precipitation map reproduces precipitation variance of the disaggregation field, and with Pearson correlation coefficients between the downscaled map and the NEXRAD map of 0.65, 0.71, and 0.80. The algorithm does not perform as well on downscaling hourly precipitation fields at the examined scale range (from 16 km to 4 km), which underestimates precipitation variance of the disaggregation field. For a scale range from 4 km to 1 km, the algorithm has potential to perform well at both daily and hourly precipitation fields, indicated from good regression performance.     

Pore Water Characteristics Following a Release of Neat Ethanol onto Pre-existing NAPL

Neat ethanol (75.7 L) was released into the upper capillary zone in a continuous-flow, sand-packed aquifer tank (8.2 m³) with an average seepage velocity of 0.75 m/day. This model aquifer system contained a residual nonaqueous phase liquid (NAPL) that extended from the capillary zone to 10 cm below the water table. Maximum aqueous concentrations of ethanol were 20% v/v in the capillary zone and 0.08% in the saturated zone at 25 and 30 cm downgradient from the emplaced NAPL source, respectively. A bench-scale release experiment was also conducted for a similar size spill (scaled to the plan area). The concentrations of ethanol in ground water for both the bench- and pilot-scale experiments were consistent with advective–dispersive limited mass transfer from the capillary to the saturated zone. Concentrations of monoaromatic hydrocarbons and isooctane increased in the pore water of the capillary zone as a result of both redistribution of residual NAPL (confirmed by visualization) and enhanced hydrocarbon dissolution due to the cosolvent effect exerted by ethanol. In the tank experiment, higher hydrocarbon concentrations in ground water were also attributed to decreased hydrocarbon biodegradation activity caused by preferential microbial utilization of ethanol and the resulting depletion of oxygen. These results infer that spills of highly concentrated ethanol will be largely confined to the capillary zone due to its buoyancy, and ethanol concentrations in near-source zone ground water will be controlled by mass transfer limitations and hydrologic conditions. Furthermore, highly concentrated ethanol releases onto pre-existing NAPL will likely exacerbate impacts to ground water, due to NAPL mobilization and dissolution, and decreased bioattenuation of hydrocarbons.     

Evaluation of spatially clustered ordnance when using compliance sampling surveys after clean-up at military training sites

After site clean-up teams have removed all of what they believe to be UXO within a specific impact area, statistical compliance sampling is a possible method for verifying with a specified probability that this area has been cleaned to specifications. Schilling [J Qual Technol 10(2):47–51, 1978, Acceptance sampling in quality control. Marcel Dekker, Inc., New York, 1982] developed a compliance sampling methodology based on the hypergeometric distribution. Bowen and Bennett (1987) also use compliance sampling where they provide an approximation for estimating the number of samples (n) required to state with desired probability that the entire population of sample units (N, where n < N) are in compliance with cleanup goals. This article describes two methods (anomaly and transect) for applying the Schilling [J Qual Technol 10(2):47–51, 1978, Acceptance sampling in quality control. Marcel Dekker, Inc., New York, 1982] compliance sampling method to military training sites. After describing these methods, a simulation study is presented which demonstrates the performance of transect compliance sampling calculations based on varied degrees of clustered UXO within a specific impact area and different types of sampling routines.     

Data reporting norms for 40Ar/39Ar geochronology

Data reported in ⁴⁰Ar/³⁹Ar geochronology studies are commonly insufficient to allow computation of ages. This deficiency renders it difficult to compare ages based on different standards or constants, and often hinders critical evaluation of the results. Herein are presented an enumeration of the data that should be reported in all ⁴⁰Ar/³⁹Ar studies, including a discussion in support of these requirements. The minimum required data are identified and distinguished from parameters that are useful but may be derived from them by calculation. Finally, recommendations are made for metadata needed to document age calculations (e.g., from age spectrum or isochron analyses).     

Octahedral cation ordering in olivine at high temperature. I: in situ neutron single-crystal diffraction studies on natural mantle olivines (Fa12 and Fa10)

Crystallographic determinations on natural olivine single crystals of mantle composition and origin, carried out by in situ neutron diffraction at high temperature, show that the octahedrally co-ordinated Fe²⁺ and Mg cations undergo two successive trends of cation ordering with increasing temperature. An initial slight preference of Fe²⁺ for site M1, up to a temperature of about 850?°C, is followed by a reverse-ordering reaction with a site preference exchange between the two cations. The cross-over between the two regimes of ordering, corresponding to a situation of complete disorder, occurs at about 900?°C. Above this temperature Fe²⁺ progressively and strongly segregates into site M2 up to 1300?°C, the practical limit of the experimental setup utilized in the experiments. Care was taken to ensure that no chemical changes occurred in the crystals (i.e. oxidation), as testified by Mössbauer spectroscopy determinations carried out before and after the heat treatment. The cation-ordering behaviour is reflected in temperature-dependent changes of geometrical and atomic displacement parameters occurring in the octahedral sites M1 and M2. A thermodynamical explanation of this behaviour is proposed in terms of a prevailing vibrational contribution to entropy.     

William Gilbert: the first palaeomagnetist

William Gilbert first described the Earth as a giant dipole magnet 400 years ago. But, as Rod Wilson recounts, he did far more than this.     

New views of Betelgeuse: multi-wavelength surface imaging and implications for models of hotspot generation

We report contemporaneous multi-wavelength interferometric imaging of the red supergiant star Betelgeuse ( α Orionis), using the Cambridge Optical Aperture Synthesis Telescope (COAST) and the William Herschel Telescope (WHT), at wavelengths of 700, 905 and 1290 nm. We find a strong variation in the apparent symmetry of the stellar brightness distribution as a function of wavelength. At 700 nm the star is highly asymmetric, and can be modelled as the superposition of three bright spots on a strongly limb-darkened disc. However, at 905 nm only a single low-contrast feature is visible and at 1290 nm the star presents a featureless symmetric disc. The change in spot contrast with wavelength is consistent with a model in which the bright spots represent unobscured areas of elevated temperature, owing perhaps to convection, on a stellar disc that itself has a different appearance, i.e. geometrical extent and limb-darkening profile, at different wavelengths. The featureless centre-to-limb brightness profile seen at 1290 nm is consistent with this model and suggests that future interferometric monitoring of the star to quantify the size changes associated with radial velocity variations should be performed at similar wavelengths in the near-infrared.