Cytochrome P4501A biomarker indication of the timeline of chronic exposure of Barrow's goldeneyes to residual Exxon Valdez oil

We examined hepatic EROD activity, as an indicator of CYP1A induction, in Barrow’s goldeneyes captured in areas oiled during the 1989 Exxon Valdez spill and those from nearby unoiled areas. We found that average EROD activity differed between areas during 2005, although the magnitude of the difference was reduced relative to a previous study from 1996/1997, and we found that areas did not differ by 2009. Similarly, we found that the proportion of individuals captured from oiled areas with elevated EROD activity (?2 times unoiled average) declined from 41% in winter 1996/1997 to 10% in 2005 and 15% in 2009. This work adds to a body of literature describing the timelines over which vertebrates were exposed to residual Exxon Valdez oil and indicates that, for Barrow’s goldeneyes in Prince William Sound, exposure persisted for many years with evidence of substantially reduced exposure by 2 decades after the spill.     

Shallow degassing events as a trigger for very-long-period seismicity at Kīlauea Volcano,Hawai‘i

The first eruptive activity at Kīlauea Volcano’s summit in 25 years began in March 2008 with the opening of a 35-m-wide vent in Halema‘uma‘u crater. The new activity has produced prominent very-long-period (VLP) signals corresponding with two new behaviors: episodic tremor bursts and small explosive events, both of which represent degassing events from the top of the lava column. Previous work has shown that VLP seismicity has long been present at Kīlauea’s summit, and is sourced approximately 1 km below Halema‘uma‘u. By integrating video observations, infrasound and seismic data, we show that the onset of the large VLP signals occurs within several seconds of the onset of the degassing events. This timing indicates that the VLP is caused by forces—sourced at or very near the lava free surface due to degassing—transmitted down the magma column and coupling to the surrounding rock at 1 km depth.     

A Bayesian approach to monitoring and assessing unexploded ordnance remediation progress from munitions testing ranges

We present a statistical methodology which aims to monitor and assess the progress of unexploded ordnance remediation. We explicitly quantify the probability that each buried sensor-identified anomaly is not a target of interest conditional on the information gleaned from anomalies which have been dug and identified. We provide a measure of confidence that the anomalies which remain onsite after remediation are not unexploded ordnance—this measure of confidence is gleaned through Monte Carlo methods. The methodology is iterative in that, at any point in the remediation process, we can assess remediation progress and compute the probability that no targets of interest remain given the available dig information.     

Hydrogen isotope ratios of leaf wax n-alkanes in grasses are insensitive to transpiration

We analyzed hydrogen isotope ratios of high-molecular weight n-alkanes (δD_l) and oxygen isotope ratios of α-cellulose (δ¹⁸O_C) for C₃ and C₄ grasses grown in the field and in controlled-environment growth chambers. The relatively firm understanding of ¹⁸O-enrichment in leaf water and α-cellulose was used to elucidate fractionation patterns of δD_l signatures. In the different relative humidity environments of the growth chambers, we observed clear and predictable effects of leaf-water enrichment on δ¹⁸O_C values. Using a Craig-Gordon model, we demonstrate that leaf water in the growth chamber grasses should have experienced significant D-enriched due to transpiration. Nonetheless, we found no effect of transpirational D-enrichment on the δD_l values. In field samples, we saw clear evidence of enrichment (correlating with relative humidity of the field sites) in both δ¹⁸O_C and δD_l. These seemingly contrasting results could be explained if leaf waxes are synthesized in an environment that is isotopically similar to water entering plant roots due to either temporal or spatial isolation from evaporatively enriched leaf waters. For grasses in the controlled environment, there was no enrichment of source water, whereas enrichment of grass source water via evaporation from soils and/or stems was likely for grass samples grown in the field.Based on these results, evaporation from soils and/or stems appears to affect δD_l, but transpiration from leaves does not. Further evidence for this conclusion is found in modeling expected net evapotranspirational enrichment. A Craig-Gordon model applied to each of the field sites yields leaf water oxygen isotope ratios that can be used to accurately predict the observed δ¹⁸O_C values. In contrast, the calculated leaf water hydrogen isotope ratios are more enriched than what is required to predict observed δD_l values. These calculations lend support to the conclusion that while δ¹⁸O_C reflects both soil evaporation and transpiration, δD_l appears to only record evaporation from soils and/or stems. Therefore, the δD of n-alkanes can likely be used to reconstruct the δD of water entering a leaf, supporting the soil-enrichment model of Smith and Freeman (2006). In both the field and controlled studies, we found significant photosynthetic pathway effects on n-alkane δD suggesting that biochemical pathways or plant phylogeny have a greater effect on leaf wax δD than leaf-water enrichment in grasses.     

Sierra Leone’s illicit diamonds: the challenges and the way forward

Although the Kimberley Process Certificate Scheme has considerably reduced the flow of conflict diamonds from 4% to less than 1%, other forms of illicit diamonds are estimated at 20% of global production. While scholars and policy makers have given considerable attention to illicit mining and smuggling (with some success), illicit exploitation still hinders revenue generation that is needed for economic growth and development in Sub-Saharan African (SSA) countries heavily reliant on alluvial minerals. Based on surveys of 240 households in four diamondiferous chiefdoms in Kono District in Sierra Leone, key informant interviews, focus groups and secondary data, and drawing from the actor-oriented approach and Le Billon (Fuelling war: natural resources and armed conflict. London, International Institute for Strategic Studies, 2005) conceptualization of the political geography of the resource, this paper examines the problem of illicit diamond exploitation in post-conflict Sierra Leone. It investigates: (1) the causes of illicit diamond mining and smuggling; (2) the spatial and temporal aspects of illicit mining and smuggling, and (3) possible solutions to illicit diamond exploitation. The paper argues that the ineffectiveness of national mining laws/policies has created conditions that are exploited by local and international actors in the diamond industry. This is further exacerbated by the political geography of the resource. Study findings reveal that while better mining regulation could reduce illicit exploitation, bringing buyers closers to miners and offering them better prices for rough diamonds will minimize smuggling and thus increase government’s mineral revenue base.     

Burial and degradation of organic carbon in Louisiana shelf/slope sediments

The primary focus of this paper is to better understand carbon burial on the Louisiana continental margin using spatial scales that covered various shelf depositional areas far-field and near-field (sediment and organic carbon inputs relative to river mouth proximity) and covering a variety of sedimentation rates. Box-cores samples were collected in July 2003; cores were collected along two depositional transects extending westward and southward from the Southwest Pass (SW Pass). A key difference between the two transects sampled in this study was the greater occurrence of mobile muds derived from spillover from shallower regions along the westward 50 m isobaths. The dominant mechanism for mixing in the surface active zone (SAZ) on the inner Louisiana shelf was due to physical, not biological, forces. Burial efficiencies for organic carbon (57.2–91.5%) and total nitrogen (44.2–86.9%) ranged widely across all shelf stations. Lower burial efficiencies for bulk organic carbon, total nitrogen, and pigment biomarkers were associated with mobile muds west of Southwest Pass. Chlorophyll a concentrations were significantly higher than pheopigments at depth at the Mississippi River and Southwest Pass stations, making up 40.4 and 77.4% of total pigment concentrations in the (SAZ) and 46.2 and 63.2% in the accumulation zone (AZ), respectively. These results are in agreement with earlier plant pigment studies which showed that a large fraction of the phytodetritus delivered to the inner shelf was derived from coastal and river diatoms. The amount of lignin preserved with depth decreased with increasing residence time in the SAZ and diagenetic zone (DZ) along the canyon transect but not along the western transect. Trends for lignin concentration followed previously identified surface sediment trends indicating overall lower burial of refractory terrestrial material at depth with greater distance offshore.     

Timing and mechanisms controlling evaporite diapirism on Ellef Ringnes Island,Canadian Arctic Archipelago

The Permo‐Carboniferous to Eocene Sverdrup Basin in Canada's Arctic Archipelago is strongly influenced by evaporite diapirism. However, salt structures within the basin have not been extensively investigated recently due to their remote location. This study includes the interpretation of legacy seismic reflection and borehole data to characterize the geometry of selected evaporite domes, and 1D backstripping of wells to investigate tectonic and sedimentary influences on diapirism. Extensional rift‐structures appear to have played a significant role in the formation of evaporite domes by triggering and directing salt movement. Diapirism was initiated by at least the Middle Triassic and continued to develop during the Mesozoic. Differential loading of salt on opposing east–west dome margins led to their present day asymmetric geometries. Diapir growth rates in the Mesozoic were closely linked to the rate of sedimentation and influenced by regional tectonism.     

From mush to eruption in centuries: assembly of the super-sized Oruanui magma body

The magmatic systems that give rise to voluminous crystal-poor rhyolite magma bodies can be considered to operate on two contrasting timescales: Those governed by longer-term processes by which a magma acquires its chemical and isotopic characteristics (e.g., fractional crystallisation and assimilation), and those operating at shorter timescales during the physical accumulation of the melt-dominant magma body that finally erupts. We explore the compositional and textural relationships between amphibole and orthopyroxene crystals from the 25.4 ka, 530 km³ (magma) Oruanui eruption products (Taupo volcano, New Zealand) to investigate how processes related to the physical assembly of the pre-eruptive magma body are represented in the crystal record. Over 90 % of orthopyroxenes from the volumetrically dominant high-SiO₂ (>74 wt%) rhyolite pumices record textural evidence for a significant disequilibrium event (partial dissolution ± resorption of cores and interiors) prior to the growth of 40–500 μm thick rim zones. This dissolution/regrowth history of orthopyroxene is recorded in the chemistry of co-crystallising amphiboles as a prominent inflection in the concentrations of Mn and Zn, two elements notably enriched in orthopyroxene relative to amphibole. Textural and chemical features, linked with in situ thermobarometric estimates, indicate that a major decompression event preceded the formation of the melt-dominant body. The decompression event is inferred to represent the extraction of large volumes of melt plus crystals from the Oruanui crystal mush/source zone at pressures of 140–300 MPa (~6–12 km depth). Orthopyroxene underwent partial dissolution during ascent before reestablishing in the melt-dominant magma body at pressures of 90–140 MPa (~3.5–6 km). We model Fe–Mg diffusion across the core-rim boundaries along the crystallographic a or b-axes to constrain the timing of this decompression event, which marked establishment of the melt-dominant magma body. Maximum modelled ages indicate that this event did not begin until ~1,600 years before eruption, consistent with constraints from zircon model-age spectra. Once extraction began, it underwent runaway acceleration with a peak extraction age of ~230 years, followed by an apparent period of stasis of ~60 years prior to eruption. The rapidity of the extraction and accumulation processes implies the involvement of a dynamic driving force which, in the rifted continental arc setting of the Taupo Volcanic Zone, seems likely to be represented by magma-assisted extensional tectonic processes.     

Geological and thermochronological studies of the Dashui gold deposit, West Qinling Orogen, Central China

The Dashui gold deposit is a structurally controlled, Carlin-type gold deposit hosted by recrystallised limestone in the West Qinling Orogen of Central China. The major, structurally late east-trending Dashui Fault forms the hanging wall to the gold mineralisation at the Dashui mine and defines the contact between Middle Triassic limestone and a steeply dipping overlying succession of Middle Triassic argillaceous limestone, dolomite, and sandstone. Multiple carbonate veins and large-scale supergene enrichment, represented by hematite, goethite, limonite and jarosite, characterise the deposit. Detailed geochronological investigation using zircon SHRIMP U-Pb dating reveals that volcanic rocks closely associated with the Dashui gold deposit were synchronous with the Ge’erkuohe Granite and pre-date mineralisation. The igneous dyke sample from the hanging wall has the same U-Pb zircon age as the footwall, ca. 213 Ma. (U-Th)/He thermochronology on dykes in the hanging wall and footwall of the Dashui Fault yields identical (U-Th)/He zircon ages of ca. 210 Ma but distinct (U-Th)/He apatite ages of ca. 136 and 211 Ma, respectively. Therefore, the hanging wall and footwall are interpreted as having distinct post-mineralisation exhumation histories. Reverse fault movement exhumed the hanging wall ~2 to 4 km since the Late Triassic with the main component of faulting taking place between the Late Triassic and Early Cretaceous. These relationships suggest a Late Triassic to Early Cretaceous age for the primary gold mineralisation at the Dashui gold deposit, with the corollary that any ‘missing portion’ of the deposit, previously hypothesised to exist in the hanging wall of the Dashui Fault, has been eroded away. The mineralisation in the footwall may have been supergene enriched soon after the primary mineralisation was emplaced, because it has been located at shallow depth since the Late Triassic. Semi-quantitative results obtained in this study also constrain the maximum depth of formation of the Dashui gold at no more than 2 km.