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81.
R. O. Colson G. A. McKay L. A. Taylor 《Contributions to Mineralogy and Petrology》1989,102(2):242-246
We have used trace element partitioning data available in the literature to investigate nonideality of the cations of Yb, Sm, Gd, Ca, Mn, Sc, Ni, and Al in silicate melt, olivine, and low-Ca pyroxene. Results are consistent with ordering of Mg and Fe around trace cations in olivine and pyroxene. On the basis of these data, we suggest there is an increasing tendency for Fe to congregate in the vincinity of the trace cation as the size of the trace cation increases. These results are important both in achieving a better understanding of trace element behavior in crystals and in constraining the temperature and compositional dependence of trace element partitioning. 相似文献
82.
Kendrick C. Taylor John W. Hess Aldo Mazzela 《Ground Water Monitoring & Remediation》1989,9(1):100-104
The Geonics EM-39 borehole induction tool was field tested to evaluate its performance under controlled conditions. The effects of temperature changes and borehole fluids were found to be negligible under most conditions. The instrument can be calibrated in large bodies of water of known electrical conductivity. When properly calibrated, the ± 5 percent accuracy claimed by the manufacturer is obtainable. A geologic unit must be at least 4m thick for the electrical conductivity of the unit to be accurately measured. Geologic units thinner than 4m thick can be detected if the conductivity contrast to adjacent units is sufficiently large. 相似文献
83.
James C. Lynch John R. Meriwether Brent A. McKee Francisco Vera-Herrera Robert R. Twilley 《Estuaries and Coasts》1989,12(4):284-299
Accretion rates were measured in fringe and basin mangrove forests in river and tidally dominated sites in Terminos Lagoon, Mexico, and a basin mangrove forest in Rookery Bay, Florida, USA. Accretion rates were determined using the radionuclides210Pb and137Cs. Consolidation-corrected accretion rates for the Rookery Bay cores, ranged from 1.4 to 1.7 mm yr?1, with an average rate of 1.6 mm yr?1. Rates at the Mexico sites ranged from 1.0 to 4.4 mm yr?1, with an average of 2.4 mm yr?1. Determination of rates in these mangrove forests was greatly affected by the consolidation corrections which decreased the apparent accretion rate by over 50% in one case. Accretion rates at basin sites compare favorably with a reported 1.4 to 1.6 mm yr?1 rate of sea-level rise, indicating little or no subsidence at inland locations. Accretion rates in fringe sites are generally greater than basin sites, indicating greater subsidence rates in these sediments over longer time intervals. 相似文献
84.
85.
Paul F. McMillan Brent T. Poe Thomas R. Stanton Richard L. Remmele 《Physics and Chemistry of Minerals》1993,19(7):454-459
We have obtained high quality Raman spectra for two H/D isotopically substituted hydrous aluminosilicate glasses with compositions along the NaAlSi3O8-SiO2 join. Consistent with the results of previous studies, the isotope shift for the band near 900 cm–1, whose intensity grows with increasing water content, is extremely small: v
h
/v
d
= 1.004 ± 0.004. The lack of a definite H/D isotope shift for this band does not, however, preclude its association with a vibration of a hydrous species in the glass, because of likely strong coupling between different vibrational modes of hydrated framework species. The 900 cm–1 band could well be due to a T — OH (T = Si, Al) stretching or bending vibration in the hydrous glass, as required by the presence of a combination band near 4500 cm–1 in near-infrared spectra. 相似文献
86.
J. R. Taylor T. K. Yeoman M. Lester M. J. Buonsanto J. L. Scali J. M. Ruohoniemi J. D. Kelly 《Annales Geophysicae》1994,12(12):1174-1191
We report on the response of high-latitude ionospheric convection during the magnetic storm of March 20–21 1990. IMP-8 measurements of solar wind plasma and interplanetary magnetic field (IMF), ionospheric convection flow measurements from the Wick and Goose Bay coherent radars, EISCAT, Millstone Hill and Sondrestrom incoherent radars and three digisondes at Millstone Hill, Goose Bay and Qaanaaq are presented. Two intervals of particular interest have been identified. The first starts with a storm sudden commencement at 2243 UT on March 20 and includes the ionospheric activity in the following 7 h. The response time of the ionospheric convection to the southward turning of the IMF in the dusk to midnight local times is found to be approximately half that measured in a similar study at comparable local times during more normal solar wind conditions. Furthermore, this response time is the same as those previously measured on the dayside. An investigation of the expansion of the polar cap during a substorm growth phase based on Faraday’s law suggests that the expansion of the polar cap was nonuniform. A subsequent reconfiguration of the nightside convection pattern was also observed, although it was not possible to distinguish between effects due to possible changes in By and effects due to substorm activity. The second interval, 1200–2100 UT 21 March 1990, included a southward turning of the IMF which resulted in the Bz component becoming -10 nT. The response time on the dayside to this change in the IMF at the magnetopause was approximately 15 min to 30 min which is a factor of \sim2 greater than those previously measured at higher latitudes. A movement of the nightside flow reversal, possibly driven by current systems associated with the substorm expansion phases, was observed, implying that the nightside convection pattern can be dominated by substorm activity. 相似文献
87.
88.
N. R. Khisina D. A. Khramov M. V. Kolosov A. A. Kleschev Lawrence A. Taylor 《Physics and Chemistry of Minerals》1995,22(4):241-250
Olivine samples (Fa 11) have been oxidized in air (f O2 = 0.2 atm) at temperatures ranging from 350–700 °C and examined by Mössbauer spectroscopy, transmission electron microscopy, X-ray powder diffraction and thermomagnetic analysis. Oxidation of olivine was found to result in ferriolivine, magnesioferrite (major oxide phase) and magnetite (minor oxide phase) formation. Ferriolivine forms planar (001) precipitates, 0.6 nm in thickness, in the olivine host; the composition is likely to be Mg0.5 v 0.5(Fe3+)1.0SiO4. Magnesioferrite MgFe2O4 exsolves as fine-grained precipitates (5–6 nm in size) filling interstices between the ferriolivine planar precipitates. Oxidation kinetic data at 700 °C show two stages of oxidation corresponding to formation of ferriolivine in the first stage and magnesioferrite in the second stage. The linear rate law with a rate constant k Fol = 1.23 · 10-3 s-1 was found for the first stage whereas a parabolic rate-law with a constant of k oxi = 3.28 · 10-3 s-1 was determined for the second stage of oxidation. It was found that ferriolivine is not an intermediate metastable phase in the oxidation process, terminated by magnesioferrite formation. The ferriolivine and magnesioferrite are considered to have formed by independent reactions which do not necessarily proceed simultaneously. 相似文献
89.
The Stanley River in western Tasmania, Australia, contains sub-fossil rainforest logs within the channel and floodplain. Of the more than 85 radiocarbon dates obtained, all but 3 date from 17 ka to the present and permit an interpretation of fluvial and related environmental changes over this period. Particular attention is focused on the interactive relationship between the river and its riparian rainforest. Following the Last Glacial Maximum, the Stanley River was a laterally active gravel-load system reworking most of its valley floor in the upstream reaches. With ameliorating conditions at the end of the Pleistocene, climate became less seasonal and flow regimes less energetic. Huon pines already present in the catchment, re-asserted themselves in the form of dense tree cover along the river banks and floodplains with basal floodplain deposition shifting from gravels to coarse sands and granules. By about 3.5 ka, a further change in climate reduced stream discharges substantially. As a result the channel reduced in size, transported finer sediment, became laterally stable, and the floodplain accreted with overbank deposits of sand and silt. Huon pines falling into the channel formed obstructions of woody debris, some surviving for 2 ka. These have reduced stream power and boundary shear stress, further contributing to channel stability. Generational sequences of Huon pines on the river banks, some extending back 1–2 ka, are additional evidence of this stability. Since the Pleistocene, changing climate and the re-establishment of dense riparian rainforest appear to have stabilised the river channels and floodplains of western Tasmania. 相似文献
90.
Annual mean ocean surface heat fluxes have been studied as a function of horizontal resolution in the ECMWF model (cycle 33) and compared with Oberhuber's COADS (1959–1979) based empirical estimates. The model has been run at resolutions of T21, T42, T63 and T106 for 15 months with prescribed monthly varying climatological SST and sea ice. The T42 simulation was extended to 2 years, which enabled us to determine that many differences between the resolution runs were significant and could not be explained by the fact that individual realizations of an ensemble of years can be expected to give different estimates of the annual mean climate state. In addition to systematic differences between the modeled and the observed fluxes, the simulated fields of surface shortwave and longwave radiation showed much more spatial variability than the observed estimates. In the case of the longwave radiation this may be attributable more to deficiencies in the observations than to errors in the model. The modeled latent and sensible heat fields were in better agreement with observations. The primary conclusion concerning the dependence of ocean surface fluxes on resolution is that the T21 simulation differed significantly from the higher resolution runs, especially in the tropics. Although the differences among the three higher resolution simulations were generally small over most of the world ocean, there were local areas with large differences. It appears, therefore, that in relation to ocean surface heat fluxes, a resolution greater than T42 may not be justified for climate model simulations, although the locally large differences found between the higher resolution runs suggest that convergence has not been achieved everywhere even at T106. 相似文献