Initial observations of water quality indicators in the unconfined shallow aquifer in Dili City,Timor-Leste: suggestions for its management

The management of groundwater quality is a critical issue in developing nations where sanitation and drinking water targets are commonly addressed by facilitating access to groundwater, which is then managed as a common-pool resource. We investigate the quality of the shallow unconfined groundwater in Dili’s alluvial fan system, which 50% of Dili’s rapidly growing population use for all their water requirements. Using the basic chemical and microbiological analyses that are locally available (sulfate, total hardness, fluoride, manganese, iron, ammonia, nitrite, nitrate, total coliform and E. coli) we show that the shallow wells commonly contain enhanced concentrations of dissolved solids and microbiological contaminants (total coliform and E. coli), relative to deeper wells. Cool, shallow wells are worse than warm equivalents. Elevated nitrate and nitrite pollution in the embassy district are tentatively attributed to affluence factors, such as lawn cultivation and water filtration equipment. Microbiological contamination, and associated manganese contamination of groundwater, mimic population patterns, but are concentrated in the finer grained sediments of the small fans and low-slope interdistributary areas. We suggest that rapid development and successful implementation of appropriate sanitation policy in Dili (and elsewhere) is required to address the problematic features of the shallow groundwater system. Success will be predicated on (1) the establishment of baseline data, and (2) development of a systems-thinking approach to holistic water resource management.     

Assessing the spatial variability of the ~3 μm OH/H2O absorption feature in CM2 carbonaceous chondrites

H₂O and OH are readily detected in hydrated minerals in CM chondrites via reflectance spectroscopy due to their characteristic vibration absorptions at infrared wavelengths. Previous spectroscopic work on bulk powdered CM chondrites has shown that spectral parameters, like the wavelength position of the “3 μm absorption feature,” vary systematically with the extent to which the samples have been aqueously altered. However, it is yet unclear how these spectral features may vary across an intact meteorite chip when measured at spatial scales smaller than that of the individual components of the meteorite. Here, we explore the spatial variability of this spectral feature and others on intact CM2 chips which, unlike powders, retain their petrologic and textural characteristics. We also model the modal mineralogy of the bulk meteorite powders and correlate this with key spectral features, demonstrating that microscope Fourier transform infrared spectroscopic mapping provides a powerful, rapid, and non-destructive technique for assessing compositional diversity and variations in water–rock interactions in chondritic planetary materials. In all CM2 chondrites studied here, we find that variations in the position, shape, and strength of the 3 μm absorption feature reveal a single chondrite can exhibit as much spectral variation as the entire suite of CM2 chondrites. The observed variations in the position and shape of the 3 μm feature within individual CM2 chondrite chips suggest a range of alteration products (e.g., Mg-rich to Fe-rich phyllosilicates) are present and record sub-mm scale variations in the amount and/or chemistry of the altering fluids. The samples having experienced the most progressive aqueous alteration show the least amount of variability in features like the 3 μm absorption band minimum position, whereas the least altered samples exhibit the most variability. We also find that the bulk spectral signatures in the least altered samples appear to be biased toward the spectral signatures of clasts versus matrix. By extension, asteroid reflectance spectra exhibiting 3 μm absorption features consistent with those measured here may be interpreted in a similar framework in which the spectrum of what may appear to be the least altered asteroids represents an average that belies the true diversity of mineralogy and chemistry of the body.     

Flow separation at the inner (convex) and outer (concave) banks of constant‐width and widening open‐channel bends

There is a paucity of data and insight in the mechanisms of, and controls on flow separation and recirculation at natural sharply‐curved river bends. Herein we report on successful laboratory experiments that elucidate flow structure in one constant‐width bend and a second bend with an outer‐bank widening. The experiments were performed with both a flat immobile gravel bed and mobile sand bed with dominant bedload sediment transport. In the constant‐width bend with immobile bed, a zone of mainly horizontal flow separation (vertical rotational axis) formed at the inner bank that did not contain detectable flow recirculation, and an outer‐bank cell of secondary flow with streamwise oriented rotational axis. Surprisingly, the bend with widening at the outer bank and immobile bed did not lead to a transverse expansion of the flow. Rather, flow in the outer‐bank widening weakly recirculated around a vertical axis and hardly interacted with the inner part of the bend, which behaved as a constant‐width bend. In the mobile bed experiment, downstream of the bend apex a pronounced depositional bar developed at the inside of the bend and pronounced scour occurred at the outside. Moreover the deformed bed promoted flow separation over the bar, including return currents. In the constant‐width bend, the topographic steering impeded the generation of an outer‐bank cell of secondary flow. In the bend with outer‐bank widening, the topographic steering induced an outward expansion of the flow, whereby the major part of the discharge was conveyed in the central part of the widening section. Flow in the outer‐bank widening was highly three dimensional and included return currents near the bottom. In conclusion, the experiments elucidated three distinct processes of flow separation common in sharp bends: flow separation at the inner bank, an outer‐bank cell of secondary flow, and flow separation and recirculation in an outer‐bank widening. Copyright © 2012 John Wiley & Sons, Ltd.     

Land use,associated eel production,and abundance of fish and crayfish in streams in Waikato,New Zealand

Abstract

The density and biomass of fish and crayfish, and the production of eels, was compared among streams in native forest, exotic forest, and pasture. Populations were estimated by multiple‐pass electroshocking at 11 sites in hill‐country streams in the Waikato region, North Island. Three sites were in native forest, four in exotic forest, and four in pasture. Length of stream sampled at each site was 46–94 m (41–246 m² in area), and catchment areas up stream of the sites ranged from 0.44 to 2.01 km².

A total of 487 fish were caught. The species were longfinned and shortfinned eels, banded kokopu, Cran's and redfinned bullies, and common smelt. Eels were the most abundant fish in all three land‐use types, and shortfinned eels were more abundant at pastoral sites (mean density 1.11 fish m^?2) than longfinned eels (mean density 0.129 fish m^?2). Banded kokopu were present only at forested sites. Mean fish densities were greater at pastoral sites (1.55 fish m^?2) than under either native forest (0.130 fish m^?2) or exotic forest (0.229 fish m^?2). Mean fish biomass was also greater at pastoral sites (89.7 g m^?2) than under native forest (12.8 g m^?2) or exotic forest (19.3 g m^?2). Longfinned eels made a greater contribution to the fish biomass at all sites than did shortfinned eels. Densities of crayfish were high (0.46–5.40 crayfish m^?2), but were not significantly different between land‐use types. Crayfish biomass ranged from 1.79 to 11.2 g m^?2. Total eel production was greater at pastoral sites (mean 17.9 g m^?2 year¹) than at forest sites (mean 2.39 gm^?2 year^?1).     

http://www.sciencedirect.com/science/article/pii/S1674987111001113

The Rheic Ocean was one of the most important oceans of the Paleozoic Era.It lay between Laurentia and Gondwana from the Early Ordovician and closed to produce the vast Ouachita-Alleghanian -Variscan orogen during the assembly of Pangea.Rifting began in the Cambrian as a continuation of Neoproterozoic orogenic activity and the ocean opened in the Early Ordovician with the separation of several Neoproterozoic arc terranes from the continental margin of northern Gondwana along the line of a former suture.The rapid rate of ocean opening suggests it was driven by slab pull in the outboard lapetus Ocean.The ocean reached its greatest width with the closure of lapetus and the accretion of the periGondwanan arc terranes to Laurentia in the Silurian.Ocean closure began in the Devonian and continued through the Mississippian as Gondwana sutured to Laurussia to form Pangea.The ocean consequently plays a dominant role in the Appalachian-Ouachita orogeny of North America,in the basement geology of southern Europe,and in the Paleozoic sedimentary,structural and tectonothermal record from Middle America to the Middle East.Its closure brought the Paleozoic Era to an end.