A pollution history of Chesapeake Bay

Present day anthropogenic fluxes of some heavy metals to central Chesapeake Bay appear to be intermediate to those of the southern California coastal region and those of Narragansett Bay. The natural fluxes, however, are in general higher. On the bases of Pb-210 and Pu-239 + 240 geochronologies and of the time changes in interstitial water compositions, there is a mixing of the upper 30 or so centimeters of the sediments in the mid-Chesapeake Bay area through bioturbation by burrowing mollusks and polychaetes. Coal, coke and charcoal levels reach one percent or more by dry weight in the deposits, primarily as a consequence of coal mining operations.     

Chemical weathering in the drainage basin of a tropical watershed (Nsimi-Zoetele site, Cameroon) : comparison between organic-poor and organic-rich waters

This study deals with the weathering processes operating at the scale of a small catchment (Nsimi-Zoetele, Cameroon) and is focused on the role of organic colloids on mineral weathering and transport of elements in natural waters. Samples of river, spring and groundwaters from Nsimi-Zoetele were filtered through membranes of decreasing pore size (0.22 μm, 0.025 μm, or: 300,000 Da, 5000 Da) to separate colloidal fractions from the truly dissolved one. Major and trace elements and dissolved organic carbon (DOC) were analysed in each fraction. Two kinds of waters can be distinguished in the catchment: clear and coloured waters. Clear waters exhibit low concentrations of major and trace elements and DOC. Elements are carried in these solutions in a true dissolved form except Al and rare earth elements (REEs). By contrast, the higher abundances of Al, Fe and trace elements in coloured waters are controlled by the colloidal fraction. Thermodynamic equilibrium calculations show that clear waters are in equilibrium with kaolinite and iron oxi-hydroxide which are major minerals in the weathered soil. For coloured waters, the aqueous speciation of Ca, Mg, Cu, Fe, Al, La and Th was calculated taking into account the complexes with humic acids. Speciation calculations for Cu, Fe, Al, La, Th show a strong complexation with humic acids, in good agreement with the results of the filtration experiments. By contrast, although filtration experiments show a strong control of major cations by organic matter (for example 75% for Ca), speciation calculations reveal that their complexes with humic ligands do not exceed a few percent of total dissolved elements. This discrepancy is explained as an artefact induced by the organic colloids and occurring during the filtration procedure. Finally, both filtration experiments and speciation calculations show that organic matter plays an important role in natural DOC-rich waters. Organic acids increase significantly the dissolution rates of silicates and oxi-hydroxides and thus the amounts of solutes and of complexed elements leaving the catchment.     

Deep groundwater flow as the main pathway for chemical outputs in a small headwater watershed (Mule Hole,South India)

This study examined the water and chemical cycles of a small forested head catchment. Application of Cl^? mass balance lead to the identification of a groundwater baseflow located into the active zone of the crystalline aquifer, below the weir. These findings indicate that groundwater contributes to a large part of chemical outputs at the catchment scale. This study shows that groundwater should not be ignored in most small watershed studies because this flow path and associated solutes are strongly significant for chemical balance assessment.     

Evolutionary convergence of the highly adapted desert rodent Tympanoctomys barrerae (Octodontidae)

Octodontid rodents have a long evolutionary history in arid landscapes of South America. The red vizcacha rat, Tympanoctomys barrerae , is a monotypic, micro-endemic species that inhabits salt pan-sand dune habitats in west-central Argentina. Its natural history is almost unknown. We present an analysis of the ecology, morphology, behavior, and physiology of the red vizcacha rat and assess the overall degree of convergence of this species with rodents that inhabit similar habitats in different deserts. Our results show that Tympanoctomys barrerae is highly adapted to salt flat basin habitats. Its diet of halophytic vegetation with a high salt content, and physiological and anatomical traits related to salt consumption, are similar to those found in some members of the families Heteromyidae (Dipodomys microps) of North America, and Muridae (Psammomys obesus and Rhombomys opimus) of Africa and Asia. Similarities include feeding behavior, diet composition, kidney morphology, and urine concentration, among other traits. Tympanoctomys barrerae is more similar to these desert rodents than it is to confamilials that do not feed on halophytes.     

Quantification and causes of the terrigeneous sediment budget at the scale of a continental margin: a new method applied to the Namibia–South Africa margin

The terrigeneous sediment budget of passive margin basins records variations in continental relief triggered by either deformation or climate. Consequently, it becomes a major challenge to determine sediment accumulation histories in a large number of basins found in various geodynamic contexts. In this study, we developed a GIS‐based method to determine the sediment budget at the scale of a whole basin (from the upstream continental onlap to the most distal deepest marine deposits) and the associated uncertainties. The volume of sediments preserved in the basin for each time interval was estimated by interpolation between cross‐sections and then corrected from in situ production and porosity to obtain terrigeneous solid volumes. This approach was validated by applying it to Namibia–South African passive margin basins for which independent data are available. We determined by a statistical approach the variances associated with each parameter of the method: the geometrical extrapolation of the section (8–43%), the uncertainties on seismic velocities for the depth conversion (2–10%), on the absolute ages of stratigraphic horizons (0.2–12%), on the carbonate content (0.2–46%) and on remaining porosities estimation (3–5%). Our estimates of the accumulated volumes were validated by comparison with previous estimates at a lower temporal resolution in the same area. We discussed variations in accumulation rates observed in terms of relief variations triggered by climate and/or deformation. The high accumulation rates determined for the Lower Cretaceous, progressively decreasing to a minimum in the Mid‐Cretaceous, are consistent with the progressive relaxation of a rift‐related relief. The following increase to an Upper Cretaceous maximum is consistent with a major relief reorganization driven either by an uplift and/or a change to more humid climate conditions. The lower accumulation rate in the Cenozoic suggests a relief reorganization of lesser amplitude over that period.     

Small-scale instabilities below the cooling oceanic lithosphere

Interpretation of satellite altimetry data as well as ship bathymetry data revealed strongly elongated anomalies roughly perpendicular to the mid-ocean ridges in the Indian and east Pacific oceans. A spectral analysis of gravity altimetry data along profiles parallel to the East Pacific Rise indicated wavelengths of about 150–180  km close to the ridge and about 250  km further away. A simple model of Rayleigh–Taylor instabilities developing at the base of the cooling lithosphere is discussed and applied to the data. By considering thermal diffusion and comparing Rayleigh–Taylor growth rates to the velocity of the thermal front in the cooling lithosphere, we are able to explain the observed anomalies by instabilities developing below the lithosphere in a layer with a viscosity of about 10¹⁹  Pa  s above an asthenospheric layer with a viscosity reduction of 2–3 orders of magnitude.     

Modeling the Subsurface Structure of Sunspots

While sunspots are easily observed at the solar surface, determining their subsurface structure is not trivial. There are two main hypotheses for the subsurface structure of sunspots: the monolithic model and the cluster model. Local helioseismology is the only means by which we can investigate subphotospheric structure. However, as current linear inversion techniques do not yet allow helioseismology to probe the internal structure with sufficient confidence to distinguish between the monolith and cluster models, the development of physically realistic sunspot models are a priority for helioseismologists. This is because they are not only important indicators of the variety of physical effects that may influence helioseismic inferences in active regions, but they also enable detailed assessments of the validity of helioseismic interpretations through numerical forward modeling. In this article, we provide a critical review of the existing sunspot models and an overview of numerical methods employed to model wave propagation through model sunspots. We then carry out a helioseismic analysis of the sunspot in Active Region 9787 and address the serious inconsistencies uncovered by Gizon et al. (2009a, 2009b). We find that this sunspot is most probably associated with a shallow, positive wave-speed perturbation (unlike the traditional two-layer model) and that travel-time measurements are consistent with a horizontal outflow in the surrounding moat.     

The Multiscale TROPIcal CatchmentS critical zone observatory M-TROPICS dataset I: The Nyong River Basin,Cameroon

Simultaneously acquiring time series of climate, hydrology and hydrochemical data over decades on river systems is pivotal to understand the complex interactions involving rock, soil water, air and biota in the Critical Zone, to build integrated modelling and to propose predictive scenarios. Among the Critical Zone Observatories (CZOs) implemented in the past 25 years, only a few are located in the humid Tropics despite the importance of these regions in terms of population density, fast-changing land use, biodiversity hotspots, biomass stock on continents, size of river systems, etc. Since 1994, weathering and erosion processes and fluxes have been investigated at both local (experimental watershed) and regional scales in the Nyong River Basin (Cameroon) which belongs to the Critical Zone Observatories network named Multiscale TROPIcal CatchmentS (M-TROPICS). The data shared by M-TROPICS in Cameroon are: (1) rainfall; (2) air temperature, air relative humidity, wind speed and direction, and global radiation; (3) stream and river water level; (4) pH, electrical conductivity, water temperature and suspended particulate matter (SPM) concentration; (5) major ion, alkalinity and dissolved organic carbon (DOC) concentrations. The dataset already contributed to describe the water partitioning in these tropical humid watersheds, to better understand the factors controlling chemical weathering and physical erosion in tropical ecosystems, particularly the role of organic matter. The dataset also contributed to calculate elemental weathering fluxes and saprolite production rate and to propose denudation rates on tropical cratonic landscapes. Hydrological modelling allowed quantification of the geographical water sources contributing to streamflow. DOC data were used to determine greenhouse-gas emissions and carbon budgets from African inland waters. However, long-term solute concentrations at the outlet of a small tributary of the Nyong River exhibit non-stationary behaviour over the last 26 years. The processes governing those fluctuations are not yet fully understood and might be related to changes in the hydrological regime, land-cover and land-use. The latter highlights the need for longer time-series and continued support for CZOs particularly in the humid tropics.     

Characterization of seasonal local recharge using electrical resistivity tomography and magnetic resonance sounding

A groundwater recharge process of heterogeneous hard rock aquifer in the Moole Hole experimental watershed, south India, is being studied to understand the groundwater flow behaviour. Significant seasonal variations in groundwater level are observed in boreholes located at the outlet area indicating that the recharge process is probably taking place below intermittent streams. In order to localize groundwater recharge zones and to optimize implementation of boreholes, a geophysical survey was carried out during and after the 2004 monsoon across the outlet zone. Magnetic resonance soundings (MRS) have been performed to characterize the aquifer and measure groundwater level depletion. The results of MRS are consistent with the observation in boreholes, but it suffers from degraded lateral resolution. A better resolution of the regolith/bedrock interface is achieved using electrical resistivity tomography (ERT). ERT results are confirmed by resistivity logging in the boreholes. ERT surveys have been carried out twice—before and during the monsoon—across the stream area. The major feature of recharge is revealed below the stream with a decrease by 80% of the calculated resistivity. The time‐lapse ERT also shows unexpected variations at a depth of 20 m below the slopes that could have been interpreted as a consequence of a deep seasonal water flow. However, in this area time‐lapse ERT does not match with borehole data. Numerical modelling shows that in the presence of a shallow water infiltration, an inversion artefact may take place thus limiting the reliability of time‐lapse ERT. A combination of ERT with MRS provides valuable information on structure and aquifer properties respectively, giving a clue for a conceptual model of the recharge process: infiltration takes place in the conductive fractured‐fissured part of the bedrock underlying the stream and clayey material present on both sides slows down its lateral dissipation. Copyright © 2007 John Wiley & Sons, Ltd.