Lower/middle tropospheric ozone variability in Senegal during pre-monsoon and monsoon periods of summer 2008: observations and model results

During the summer (8 June through 3 September) of 2008, 9 ozone profiles are examined from Dakar, Senegal (14.75°N, 17.49°W) to investigate ozone (O₃) variability in the lower/middle troposphere during the pre-monsoon and monsoon periods. Results during June 2008 (pre-monsoon period) show a reduction in O₃ concentrations, especially in the 850–700 hPa layer with Saharan Air Layer (SAL) events. However, O₃ concentrations are increased in the 950–900 hPa layer where the peak of the inversion is found and presumably the highest dust concentrations. We also use the WRF-CHEM model to gain greater insights for observations of reduced O₃ concentrations during the monsoon periods. In the transition period between 26 June and 2 July in the lower troposphere (925–600 hPa), a significant increase in O₃ concentrations (10–20 ppb) occur which we suggest is caused by enhanced biogenic NO_X emissions from Sahelian soils following rain events on 28 June and 1 July. The results suggest that during the pre-monsoon period ozone concentrations in the lower troposphere are controlled by the SAL, reducing ozone concentrations through heterogeneous chemical processes. At the base of the SAL we also find elevated levels of ozone, which we attribute to biogenic sources of NO_X from Saharan dust that are released in the presence of moist conditions. Once the monsoon period commences, lower ozone concentrations are observed and modeled which we attribute to the dry deposition of ozone and episodes of ozone poor air that is horizontally transported into the Sahel from low latitudes by African Easterly Waves (AEWs).     

Human-induced geological hazards along the Dead Sea coast

The Dead Sea is a terminal lake whose level is currently dropping at a rate of about 1 m per year due to the over exploitation of all its tributaries. The lowering started about four decades ago but geological hazards appeared more and more frequently from the end of the 1980s. The water level lowering is matched by a parallel groundwater level drop, which results in an increasing intensity of underground and surface water flow. The diagonal interface between the Dead Sea brine and the fresh groundwater is pushed downwards and seawards. Nowadays, sinkholes, subsidence, landslides and reactivated salt-karsts affect wide coastal segments. Until now, mainly infrastructures were damaged and few people/animals were injured, but the ongoing development of tourism in this very attractive situation will increase the risk if precautionary measures are not included in the development plans. This paper discusses the main observations made all around the Dead Sea and shed a light on the differences between the geological hazards of the western shore (Israel, Palestinian Authority) and the eastern shore (Jordan). It is the first attempt to bring together an overview of the human-induced geological hazards encountered along the Dead Sea coast.     

Source parameters of March 10 and September 13, 2007, United Arab Emirates earthquakes

On March 10 and September 13, 2007 two earthquakes with moment magnitudes 3.66 and 3.94, respectively, occurred in the eastern part of the United Arab Emirates (UAE). The two events were widely felt in the northern Emirates and Oman and were accompanied by a few aftershocks. Ground motions from these events were well recorded by the broadband stations of Dubai (UAE) and Oman seismological networks and provide an excellent opportunity to study the tectonic process and present day stress field acting in this area. In this study, we report the focal mechanisms of the two main shocks by two methods: first motion polarities and regional waveform moment tensor inversion. Our results indicate nearly pure normal faulting mechanisms with a slight strike slip component. We associated the fault plane trending NNE–SSW with a suggested fault along the extension of the faults bounded Bani Hamid area. The seismicity distribution between two earthquake sequences reveals a noticeable gap that may be a site of a future event. The source parameters (seismic moment, moment magnitude, fault radius, stress drop and displacement across the fault) were also estimated from displacement spectra. The moment magnitudes were very consistent with waveform inversion. The recent deployment of seismic networks in Dubai and Oman reveals tectonic activity in the northern Oman Mountains that was previously unknown. Continued observation and analysis will allow for characterization of seismicity and assessment of seismic hazard in the region.     

Hillslope run‐off thresholds with shrink–swell clay soils

Irrigation experiments on 12 instrumented field plots were used to assess the impact of dynamic soil crack networks on infiltration and run‐off. During applications of intensity similar to a heavy rainstorm, water was seen being preferentially delivered within the soil profile. However, run‐off was not observed until soil water content of the profile reached field capacity, and the apertures of surface‐connected cracks had closed >60%. Electrical resistivity measurements suggested that subsurface cracks persisted and enhanced lateral transport, even in wet conditions. Likewise, single‐ring infiltration measurements taken before and after irrigation indicated that infiltration remained an important component of the water budget at high soil water content values, despite apparent surface sealing. Overall, although the wetting and sealing of the soil profile showed considerable complexity, an emergent property at the hillslope scale was observed: all of the plots demonstrated a strikingly similar threshold run‐off response to the cumulative precipitation amount. Copyright © 2014 John Wiley & Sons, Ltd.     

Chemical and isotopic methods for management of artificial recharge in Mazraha Station (Damascus Basin,Syria)

Artificially enhancing recharge rate into groundwater aquifer at specially designed facilities is an attractive option for increasing the storage capacity of potable water in arid and semi‐arid region such as Damascus basin (Syria). Two dug wells (I and II) for water injection and 24 wells for water extraction are available in Mazraha station for artificial recharge experiment. Chemical and stable isotopes (δ²H and δ¹⁸O) were used to evaluate artificial recharge efficiency. 400 to 500*10³ m³ of spring water were injected annually into the ambient shallow groundwater in Mazraha station, which is used later for drinking purpose. Ambient groundwater and injected spring water are calcium bicarbonate type with EC about 880 ± 60 μS/cm and 300 ± 50 μS/cm, respectively. The injected water is under saturated versus calcite and the ambient groundwater is over saturated, while the recovered water is near equilibrium. It was observed that the injection process formed a chemical dilution plume that improves the groundwater quality. Results demonstrate that the hydraulic conductivity of the aquifer is estimated around 6.8*10^?4 m/s. The effective diameter of artificial recharge is limited to about 250 m from the injection wells. Mixing rate of 30% is required in order to reduce nitrate concentration below 50 mg/l which is considered the maximum concentration limit for potable water. Deuterium and oxygen‐18 relationship demonstrates that mixing line between injected water and ambient groundwater has a slope of 6.1. Oxygen‐18 and Cl^? plot indicates that groundwater salinity origin is from mixing process, and no dissolution and evaporation were observed. These results demonstrate the efficiency of the artificial recharge experiments to restore groundwater storage capacity and to improve the water quality. Copyright © 2011 John Wiley & Sons, Ltd.     

Climatic factors controlling chemical and isotopic characteristics of precipitation in Syria

The chemical and isotopic composition of monthly composite rain samples collected at 13 meteoric stations in Syria during two hydrological cycles from 1991 to 1993 have been measured. The chemical analysis of the samples revealed at a number of stations pollution due to industry and sand storms. The temporal and spatial variation of the isotopic composition has been found to be comparable with one of the neighbouring countries such as Jordan and others. The average weighted oxygen‐18 and deuterium values are − 7·5 and − 39·11‰, respectively, and the deuterium excess is 21‰ . The individual isotope values can be divided into two groups. One group is represented by winter precipitation and fits closely the Mediterranean Meteorological Water Line (MMWL). Thus, for winter precipitation, condensation of Mediterranean water vapour appears to be the dominating isotope fractionation process. The other group represents spring precipitation and is spread along an evaporation line below the MMWL, thus indicating the influence of sub‐cloud evaporation. The d‐excess has been found to be lower in the north of Syria (19·9‰ at Tartous, 18·1‰ at Jarablous) than in the south of the country (23·4‰ at Sweida, 24·1‰ at Izra) where Mediterranean air mass dominates. The d‐excess of precipitation in neighbouring countries is also close to the average value of the eastern Mediterranean basin of 22‰ , e.g. for Jordan the value is 23‰ , which signifies that Mediterranean water vapour is, for all these countries, the dominant source of precipitation. The tritium content of precipitation was found to increase with distance from the coast (5·3 TU at coastal station Tartous, 8·8 TU at continental station Palmyra). Low tritium content and high d‐excess at coastal stations clearly indicate a Mediterranean air moisture source. Copyright © 2010 John Wiley & Sons, Ltd.     

Rate and budget of blown sand movement along the western bank of Lake Nasser,southern Egypt

Three sets of Landsat? satellite images for the years 1993, 1998, and 2003 show that the sand dunes at the southwestern Desert of Egypt are generally moving towards southeast direction with a mean annual creeping speed over ground attaining 15 m/year. The manual-stickled field measurements show that the net annual extension of the longitudinal dunes in the coastal area is between 4 and 5 m/year, while the inland longitudinal dunes showed a net movement ranging between 5 and 6 m/year. Seasonal variations of drift potential and sand movement refer to a strongly high energy wind desert environment in the spring season, high energy wind desert environment in the summer season, and relatively high to intermediate in the autumn and winter seasons, respectively. The total annual estimated volume of transported sand which falls down into Lake Nasser basin attains 16,225,808 m³ as calculated by Bagnold's equation and quantities of sand collected from the sand traps. Comparing this value with the total volume of Lake Nasser Basin, which attains 120?×?10⁹ m³, we can conclude that the sand sheets or sand accumulations may represent serious natural hazards to Lake Nasser in some locations. However, the sand drifting towards the lake may be obstructed by high contour topography hindrance, and the mean grain size of the sand sheets is bigger than 0.25 mm, which needs high wind velocity more than 4 m/s. In addition, the direction of the prevailing wind is N-NNW to S-SSE, and this direction sometimes is parallel to Lake Nasser in some places according to the meandering of the lake. The total lengths of hazardous areas along the western bank of Lake Nasser, which receive the most amounts of the drifted sands, attain 43.6 km only.     

Modelling the effect of temperature on unsaturated soil behaviour

A simple thermohydromechanical (THM) constitutive model for unsaturated soils is described. The effective stress concept is extended to unsaturated soils with the introduction of a capillary stress. This capillary stress is based on a microstructural model and calculated from attraction forces due to water menisci. The effect of desaturation and the thermal softening phenomenon are modelled with a minimal number of material parameters and based on existing models. THM process is qualitatively and quantitatively modelled by using experimental data and previous work to show the application of the model, including a drying path under mechanical stress with transition between saturated and unsaturated states, a heating path under constant suction and a deviatoric path with imposed suction and temperature. The results show that the present model can simulate the THM behaviour in unsaturated soils in a satisfactory way.