Protomylonite evolution potentially revealed by the 3D depiction and fractal analysis of chemical data from a feldspar

Tourmalinization associated with peraluminous granitic intrusions in metapelitic host-rocks has been widely recorded in the Iberian Peninsula, given the importance of tourmaline as a tracer of granite magma evolution and potential indicator of Sn-W mineralizations. In the Penamacor-Monsanto granite pluton (Central Eastern Portugal, Central Iberian Zone), tourmaline occurs: (1) as accessory phase in two-mica granitic rocks, muscovite-granites and aplites, (2) in quartz (±mica)-tourmaline rocks (tourmalinites) in several exocontact locations, and (3) as a rare detrital phase in contact zone hornfels and metapelitic host-rocks. Electron microprobe and stable isotope (δ¹⁸O, δD, δ¹¹B) data provide clear distinctions between tourmaline populations from these different settings: (a) schorl–oxyschorl tourmalines from granitic rocks have variable foititic component (^X□ = 17–57 %) and Mg/(Mg + Fe) ratios (0.19–0.50 in two-mica granitic rocks, and 0.05–0.19 in the more differentiated muscovite-granite and aplites); granitic tourmalines have constant δ¹⁸O values (12.1 ± 0.1 ‰), with wider-ranging δD (?78.2 ± 4.7 ‰) and δ¹¹B (?10.7 to ?9.0 ‰) values; (b) vein/breccia oxyschorl [Mg/(Mg + Fe) = 0.31–0.44] results from late, B- and Fe-enriched magma-derived fluids and is characterized by δ¹⁸O = 12.4 ‰, δD = ?29.5 ‰, and δ¹¹B = ?9.3 ‰, while replacement tourmalines have more dravitic compositions [Mg/(Mg + Fe) = 0.26–0.64], close to that of detrital tourmaline in the surrounding metapelitic rocks, and yield relatively constant δ¹⁸O values (13.1–13.3 ‰), though wider-ranging δD (?58.5 to ?36.5 ‰) and δ¹¹B (?10.2 to ?8.8 ‰) values; and (c) detrital tourmaline in contact rocks and regional host metasediments is mainly dravite [Mg/(Mg + Fe) = 0.35–0.78] and oxydravite [Mg/(Mg + Fe) = 0.51–0.58], respectively. Boron contents of the granitic rocks are low (<650 ppm) compared to the minimum B contents normally required for tourmaline saturation in granitic melts, implying loss of B and other volatiles to the surrounding host-rocks during the late-magmatic stages. This process was responsible for tourmalinization at the exocontact of the Penamacor-Monsanto pluton, either as direct tourmaline precipitation in cavities and fractures crossing the pluton margin (vein/breccia tourmalinites), or as replacement of mafic minerals (chlorite or biotite) in the host-rocks (replacement tourmalinites) along the exocontact of the granite. Thermometry based on ¹⁸O equilibrium fractionation between tourmaline and fluid indicates that a late, B-enriched magmatic aqueous fluid (av. δ¹⁸O ~12.1 ‰, at ~600 °C) precipitated the vein/breccia tourmaline (δ¹⁸O ~12.4 ‰) at ~500–550 °C, and later interacted with the cooler surrounding host-rocks to produce tourmaline at lower temperatures (400–450 °C), and an average δ¹⁸O ~13.2 ‰, closer to the values for the host-rock. Although B-metasomatism associated with some granitic plutons in the Iberian Peninsula seems to be relatively confined in space, extending integrated studies such as this to a larger number of granitic plutons may afford us a better understanding of Variscan magmatism and related mineralizations.     

Ichnodiversity and ichnoabundance: Revealing depositional trends in a confined turbidite system

Ichnological studies are still in their infancy when it comes to the interpretation of deep‐marine deposits. The Eocene–Oligocene turbidite system of the Grès d'Annot Formation in south‐east France is well‐studied sedimentologically, but its trace‐fossil content is poorly known. Here, an integrated ichnological–sedimentological study is presented from the Annot sub‐basin for the first time, which demonstrates its value for interpreting proximal to distal and axial to marginal trends in confined turbidite systems. A comprehensive trace‐fossil data set was collected from seven outcrops situated in the southern part of the basin. These data are presented following a morphology‐based classification scheme to allow easy recognition and characterization of ichnotaxa. Ichnodiversity and the abundance of ichnotaxa are regarded as important parameters in such interpretations. Instead of simply counting ichnotaxa per outcrop or stratigraphic unit, an equation has been developed in which the ‘ichnoabundance’ (new term) of each counted ichnotaxon is calculated. An exponential growth factor is applied to the increase of the frequency of trace fossils, and is assumed in this equation to better reflect the population dynamics of benthic organisms. A comparison of the solution for pre‐turbidite and post‐turbidite trace‐fossil suites seems to be more suitable for revealing regional and stratigraphic trends compared with conventional approaches. Despite varying size and conditions of the studied outcrops, the results achieved from the Grès d'Annot Formation can help in the reconstruction of sedimentary processes acting in this confined turbidite basin.     

Periglacial structures within fluvio‐aeolian successions of the end of the Last Glaciation – examples from SE Poland and NW Ukraine

The nature of permafrost and related environmental conditions in the Weichselian Late Pleniglacial and Lateglacial are reconstructed based on the assessment of frost structures that are best documented in the Loess Belt and in plateau areas composed of glacial till. Investigations were conducted in the central‐eastern part of the European Sand Belt (SE Poland and NW Ukraine) on a fluvio‐aeolian sedimentary succession and took into account its chronological context given by luminescence dating. Various generations of periglacial structures found in these deposits indicate not only the development of permafrost (ice‐wedge pseudomorphs) and decreased humidity (composite wedge casts) but also the degradation of permafrost (large‐scale involutions) and, finally, the establishment of deep seasonal frost (frost cracks). The diversity of structures in the study region appears to result from local conditions rather than increasing continentality of climate towards the east.     

An Iterative Method for Calculation of Wind Profiles at the Mesoscale and Microscale

Boundary-Layer Meteorology - Space–time correlations are fundamental to statistical theories and turbulence modelling. However, experimental studies of space–time correlations are often...     

The Use of Stable Sulfur, Oxygen and Hydrogen Isotope Ratios as Geochemical Tracers of Sulfates in the Podwiśniówka Acid Drainage Area (South-Central Poland)

The paper presents the results of determinations of stable S and O isotopes of dissolved sulfates and O and H stable isotopes of waters from three ponds, that is, Marczakowe Do?y acid pond, Marczakowe Do?y fish pond and Podwi?niówka acid pit pond, located in the Holy Cross Mountains (south-central Poland). The δ³⁴S_V-CDT and δ¹⁸O_V-SMOW of SO₄ ^2? in waters of three ponds (n = 14) varied from ?16.2 to ?9.5 ‰ (mean of ?13.6 ‰) and from ?8.1 to ?3.2 ‰ (mean of ?4.8 ‰), respectively. The mean δ³⁴S–SO₄ ^2? values were closer to those of pyrite (mean of ?25.4 ‰) and efflorescent sulfate salts (mean of ?25.6 ‰), recorded previously in the Podwi?niówka quarry, than to sulfates derived from other anthropogenic or soil and bedrock sources. The SO₄ ^2? ions formed by bacterially induced pyrite oxidation combined with bacterial (dissimilatory) dissolved sulfate reduction, and presumably with subordinate mineralization of carbon-bonded sulfur compounds, especially in both Marczakowe Do?y ponds. In addition, the comparison of δ¹⁸O–SO₄ ^2? and δ¹⁸O–H₂O values indicated that 75–100 % of sulfate oxygen was derived from water. Due to the largest size, the Podwi?niówka acid pit pond revealed distinct seasonal variations in both δ¹⁸O–H₂O (?9.2 to ?1.6) and δD–H₂O (?29.7 to ?71.3) values. The strong correlation coefficient (r ² = 0.99) was noted between δ¹⁸O–H₂O and δD–H₂O values, which points to atmospheric precipitation as the only source of water. The sediments of both acid ponds display different mineral inventory: the Marczakowe Do?y acid pond sediment consists of schwertmannite and goethite, whereas Podwi?niówka acid pit pond sediment is composed of quartz, illite, chlorite and kaolinite with some admixture of jarosite reflecting a more acidic environment. Geochemical modeling of two acid ponds indicated that the saturation indices of schwertmannite and nanosized ε-Fe₂O₃ (Fe³⁺ oxide polymorph) were closest to thermodynamic equilibrium state with water, varying from ?1.44 to 3.05 and from ?3.42 to 6.04, respectively. This evidence matches well with the obtained mineralogical results.     

Sunspot Time Series – Relations Inferred from the Location of the Longest Spotless Segments

Spotless days (i.e., days when no sunspots are observed on the Sun) occur during the interval between the declining phase of the old sunspot cycle and the rising phase of the new sunspot cycle, being greatest in number and of longest continuous length near a new cycle minimum. In this paper, we introduce the concept of the longest spotless segment (LSS) and examine its statistical relation to selected characteristic points in the sunspot time series (STS), such as the occurrences of first spotless day and sunspot maximum. The analysis has revealed statistically significant relations that appear to be of predictive value. For example, for Cycle 24 the last spotless day during its rising phase should be about August 2012 (± 9.1 months), the daily maximum sunspot number should be about 227 (± 50; occurring about January 2014±9.5 months), and the maximum Gaussian smoothed sunspot number should be about 87 (± 25; occurring about July 2014). Using the Gaussian-filtered values, slightly earlier dates of August 2011 and March 2013 are indicated for the last spotless day and sunspot maximum for Cycle 24, respectively.     

Environmental and land use factors affecting phosphate hysteresis patterns of stream water during flood events (Carpathian Foothills,Poland)

Flood events play a substantial role in the circulation of catchment phosphate (PO₄^3?). The purpose of the research was to analyze the factors determining PO₄^3? hysteresis patterns (direction and width) during four types of floods: short and long rainfall floods and snowmelt floods on frozen and thawed soil. The research took place in small catchments (forested, agricultural, mixed‐use) in the Carpathian Foothills in Poland. Anticlockwise hysteresis was identified in the forested catchment during short and long rainfall floods. Under the same conditions, the clockwise direction was observed in the agricultural catchment. In the mixed‐use catchment, the direction of PO₄^3? hysteresis loops was various, driven by the share of water flowing from each part of the catchment. For snowmelt floods, the PO₄^3? hysteresis pattern was similar in all the streams studied (usually clockwise). The direction of PO₄^3? hysteresis loops depends on water circulation patterns, which are determined by the different influx times of particular runoff components. The stream recharge mechanism during a flood event is affected both by the factor initiating the event (precipitation, snowmelt) as well as by land use in the given catchment. Hysteresis loop width was determined by the pool of PO₄^3? in a given catchment during the time period immediately preceding a flood event as well as by the quantity of PO₄^3? flushed out of the soil. The greater a catchment's pool of PO₄^3? and the greater its ability to flush PO₄^3? out of the soil and into surface flow, the wider the hysteresis loops. Copyright © 2012 John Wiley & Sons, Ltd.     

Application of hydrological and hydraulic models for hydrological data transfer

This paper presents an application of hydrological and hydraulic models for transferring instantaneous discharges from a water gauge station to budgeting sites on rivers. Calculations were done using the following models: MIKE NAM rainfall-runoff model and a hydrodynamic MIKE 11 HD model. The simulations were carried out for the catchment of Warta River and its tributaries for the multiyear period 1999–2009.     

Site specific prediction equations for peak acceleration of ground motion due to earthquakes induced by underground mining in Legnica-Głogów Copper District in Poland

Ground motion database from the region of ?elazny Most tailings pond, the largest in Europe ore-flotation waste repository, is used to identify ground motion prediction equations (GMPE-s) for peak horizontal and peak vertical acceleration. A GMPE model including both geometrical spreading and anelastic damping terms cannot be correctly identified and the model with only spreading term is accepted. The analysis of variance of this model’s residuals with station location as grouping variable indicates that station locations contribute significantly to the observed ground motion variability. Therefore, a site specific GMPE model with relative site amplifications is assessed. Despite short distances among stations, the amplification considerably vary from point to point, up to 1.8 times for the horizontal and 3.5 times for the vertical peak amplitude. The model including site effects enhances GMPE-s fit to observations, explains more than 60% dependent variables variability and correctly accounts for site effects.     

Groundwater quality as a geoindicator of organochlorine pesticide contamination after pesticide tomb reclamation: a case study of Franciszkowo, northwestern Poland

The need of surface soil removal during reclamation of the former underground landfills makes environmental monitoring difficult to perform. Environmental quality assessment after reclamation is very important because it provides information about: (1) the efficiency of remediation, (2) the rate of biodegradation of contaminants which were not removed during reclamation works and (3) the possible migration of contaminants from soil and permeable host rocks to surface waters and groundwaters. The concept of geoindicators, which was introduced to facilitate the assessment of environmental changes, can help assess environmental quality at sites previously subjected to reclamation. The groundwater quality is usually used as a geoindicator of inorganic contaminants. This concept was applied to find changes in organochlorine pesticide concentrations in groundwaters after toxic pesticide burial ground reclamation. The aim of this study was to monitor the concentrations of organochlorine pesticides and their metabolites in groundwaters at the former pesticide landfill site after its remediation. The study showed that very high concentrations of organochlorine pesticides and their metabolites in a contaminated soil had a small influence on pesticide concentrations in groundwaters and that this influence decreased in time. It has been 2 years since reclamation of the landfill took place, and the concentrations of organochlorine pesticides in groundwaters dropped to acceptable levels within the current environmental quality standards.