Smectite interactions with flavomononucleotide

Adsorption isotherms and UV-visible and Mossbauer spectroscopic data point to specific interactions between flavomononucleotide (FMN) and Fe(3+)-smectite. The maximum amount of FMN adsorption was 0.3 mmole/g of Fe(3+)-smectite giving a 1:1 molar proportion of Fe3+ and FMN. The results suggest a Fe(3+)-FMN complex residing at the smectite surface. Other homoionic smectites (Cu2+, Zn2+, and Ca2+) exhibited lower levels of adsorption and less apparent specific interaction.     

Stratigraphic Analysis of Upper Cretaceous Rocks in the Mahajanga Basin, Northwestern Madagascar: Implications for Ancient and Modern Faunas

Upper Cretaceous strata of the Mahajanga Basin, northwestern Madagascar, yield some of the most significant and exquisitely preserved vertebrate fossils known from Gondwana. The sedimentology of these strata and their stratigraphic relations have been the focus of renewed geological investigations during the course of five expeditions since 1993. We here designate stratotypes and formalize the terrestrial Maevarano Formation, with three new members (Masorobe, Anembalemba, Miadana), and the overlying marine Berivotra Formation. The Maevarano Formation accumulated on a broad, semiarid alluvial plain bounded to the southeast by crystalline highlands and to the northwest by the Mozambique Channel. The Berivotra Formation was deposited in an open marine setting that evolved from a clastic- to a carbonate-dominated shelf, resulting in deposition of the overlying Betsiboka limestone of Danian age. New stratigraphic data clearly indicate that the Maevarano Formation correlates, at least in part, with the Maastrichtian Berivotra Formation, and this in turn indicates that the most fossiliferous portions of the Maevarano Formation are Maastrichtian in age, rather than Campanian as previously reported. This revised age for the Maevarano vertebrate assemblage indicates that it is approximately contemporaneous with the vertebrate fauna recovered from the Deccan basalt volcano-sedimentary sequence of India. The comparable age of these two faunas is significant because the faunas appear to be more similar to one another than either is to those from any other major Gondwanan landmass. The revised age of the Maevarano Formation, when considered in the light of our recent fossil discoveries, further indicates that the ancestral stocks of Madagascar's overwhelmingly endemic modern vertebrate fauna arrived on the island in post-Mesozoic times. The basal stocks of the modern vertebrate fauna are conspicuously absent in the Maevarano Formation. Finally, the revised age of the Maevarano Formation serves to expand our global perspective on the K/T event by clarifying the age of a diverse, and arguably the best preserved, sample of Gondwanan vertebrates from the terminal Cretaceous.     

Seasonal and inter-annual variability in alkalinity in Liverpool Bay (53.5° N, 3.5° W) and in major river inputs to the North Sea

A critical factor controlling changes in the acidity of coastal waters is the alkalinity of the water. Concentrations of alkalinity are determined by supply from rivers and by in situ processes such as biological production and denitrification. A 2-year study based on 15 cruises in Liverpool Bay followed the seasonal cycles of changing concentrations of total alkalinity (TA) and total dissolved inorganic carbon (DIC) in relation to changes caused by the annual cycle of biological production during the mixing of river water into the Bay. Consistent annual cycles in concentrations of nutrients, TA and DIC were observed in both years. At a salinity of 31.5, the locus of primary production during the spring bloom, concentrations of NO _x decreased by 25 ± 4 μmol kg⁻¹ and DIC by 106 ± 16 μmol kg⁻¹. Observed changes in TA were consistent with the uptake of protons during primary biological production. Concentrations of TA increased by 33 ± 8 μmol kg⁻¹ (2009) and 33 ± 15 μmol kg⁻¹ (2010). The impact of changes in organic matter on the measured TA appears likely to be small in this area. Thomas et al. (2009) suggested that denitrification may enhance the CO₂ uptake of the North Sea by 25%, in contrast we find that although denitrification is a significant process in itself, it does not increase concentrations of TA relative to those of DIC and so does not increase buffer capacity and potential uptake of CO₂ into shelf seawaters. For Liverpool Bay historical data suggest that higher concentrations of TA during periods of low flow are likely to contribute in part to the observed change in TA between winter and summer but the appropriate pattern cannot be identified in recent low-frequency river data. On a wider scale, data for the rivers Mersey, Rhine, Elbe and Weser show that patterns of seasonal change in concentrations of TA in river inputs differ between river systems.     

The influence of<Emphasis Type="Italic">Phragmites</Emphasis> (common reed) on the distribution,abundance, and potential prey of a resident marsh fish in the Hackensack Meadowlands,New Jersey

This study investigates the influence ofPhragmites australis (common reed) invasion on the habitat of the resident marsh fish,Fundulus heteroclitus (mummichog) in the Hackensack Meadowlands, New Jersey. These abundant fish play an important role in the transfer of energy from the marsh surface to adjacent subtidal waters and thus estuarine food webs. The objectives of this 2-yr study (1999 and 2000) were to compare the distribution and abundance of the eggs, larvae, juveniles, and adults of mummichog and their invertebrate prey inhabitingSpartina alterniflora-dominated marshes withPhragmites-dominated marshes, and to experimentally investigate the influence of marsh surface microtoprography on larval fish abundance withinPhragmites-dominated marshes. In 2000, we verified that egg deposition does occur inPhragmites-dominated marshes. In both years, the abundance of larvae and small juveniles (4–20 mm TL) inS. alterniflora was significantly greater than inPhragmites-dominated marshes, while larger juveniles and adults (>20 mm TL) were similarly abundant in both habitat types. The overall abundance of larvae and small juveniles was significantly greater in experimentalPhragmites plots in which microtopography was manipulated to resemble that ofSpartina marshes than inPhragmites control plots. Major groups of invertebrate taxa differed between marsh types with potential prey for larval fish being significantly more abundant inS. alterniflora marshes.Phragmites-dominated marshes may not provide the most suitable habitat for the early life-history stages of the mummichog. The low abundance of larvae and small juveniles inPhragmites marshes is likely due to inadequate larval habitat and perhaps decreased prey availability for these early life history stages.     

Early oxidation of organic matter in pelagic sediments of the eastern equatorial Atlantic: suboxic diagenesis

Pore water profiles of total-CO₂, pH, PO^3?₄, NO^?₃ plus NO^?₂, SO^2?₄, S^2?, Fe²⁺ and Mn²⁺ have been obtained in cores from pelagic sediments of the eastern equatorial Atlantic under waters of moderate to high productivity. These profiles reveal that oxidants are consumed in order of decreasing energy production per mole of organic carbon oxidized (O₂ > manganese oxides ~ nitrate > iron oxides > sulfate). Total CO₂ concentrations reflect organic regeneration and calcite dissolution. Phosphate profiles are consistent with organic regeneration and with the effects of release and uptake during inorganic reactions. Nitrate profiles reflect organic regeneration and nitrate reduction, while dissolved iron and manganese profiles suggest reduction of the solid oxide phases, upward fluxes of dissolved metals and subsequent entrapment in the sediment column. Sulfate values are constant and sulfide is absent, reflecting the absence of strongly anoxic conditions.     

Non-linear dependence and teleconnections in climate data: sources,relevance, nonstationarity

Quantification of relations between measured variables of interest by statistical measures of dependence is a common step in analysis of climate data. The choice of dependence measure is key for the results of the subsequent analysis and interpretation. The use of linear Pearson’s correlation coefficient is widespread and convenient. On the other side, as the climate is widely acknowledged to be a nonlinear system, nonlinear dependence quantification methods, such as those based on information-theoretical concepts, are increasingly used for this purpose. In this paper we outline an approach that enables well informed choice of dependence measure for a given type of data, improving the subsequent interpretation of the results. The presented multi-step approach includes statistical testing, quantification of the specific non-linear contribution to the interaction information, localization of areas with strongest nonlinear contribution and assessment of the role of specific temporal patterns, including signal nonstationarities. In detail we study the consequences of the choice of a general nonlinear dependence measure, namely mutual information, focusing on its relevance and potential alterations in the discovered dependence structure. We document the method by applying it to monthly mean temperature data from the NCEP/NCAR reanalysis dataset as well as the ERA dataset. We have been able to identify main sources of observed non-linearity in inter-node couplings. Detailed analysis suggested an important role of several sources of nonstationarity within the climate data. The quantitative role of genuine nonlinear coupling at monthly scale has proven to be almost negligible, providing quantitative support for the use of linear methods for monthly temperature data.     

Web 2.0 collaborations address uncertainty in climate reconstructions of the past millennium

Reducing uncertainty in global temperature reconstructions of the past millennium remains the key issue in applying this record to society’s pressing climate change problem. Reconstructions are collaborative, built on the research of hundreds of scientists who apply their diverse scientific expertise and field and laboratory skill to create the individual proxy reconstructions that underlie the multi-proxy, global average temperature time series. Web 2.0 features have enabled collaborative efforts that improve the characterization of uncertainty. Raw data shared via a repository (the World Data Center for Paleoclimatology) enable new reconstructions from the collection of user-generated data. Standards propagated by expert communities facilitate quality control and interoperability. Open access to data and computer code promote transparency and make the science accessible to a broader audience. Blogs, wikis, and listservs share background information and highlight contentious as well as unique aspects of paleo science. A novel approach now underway, titled the Paleoclimate Reconstruction Challenge, and based on the sharing of simulated data (pseudo-proxies) and reconstruction results, seeks to facilitate method development, further reducing uncertainty. Broadly-useful aspects of the Challenge may find application in other fields.