The photochemical products of benzene in Titan’s upper atmosphere

The Cassini spacecraft detected benzene high in Titan’s atmosphere as well as the presence of large mass positive and negative ions. Previous work has suggested that these large mass ions could be composed of fused-ring polycyclic aromatic hydrocarbon compounds. These fused-ring PAHs, such as naphthalene and anthracene, are usually the result of high temperature processes that may not occur in Titan’s thin, cold, upper thermosphere. Here we suggest that a different class of aromatic compounds, polyphenyls, may be a better explanation of the data. Polyphenyls can grow to be large polymeric structures and could condense to form the aerosols seen in Titan’s cloud and hazes. They have similar properties to fused-ring PAHs (for example, electron affinity, ionization potential) and could be the negative ion species seen in the CAPS instrument data from the Cassini spacecraft.     

Whole-disk spectrophotometric properties of Mercury: Synthesis of MESSENGER and ground-based observations

Disk-integrated and disk-resolved measurements of Mercury’s surface obtained by both the Mercury Dual Imaging System (MDIS) and the Mercury Atmospheric and Surface Composition Spectrometer (MASCS) onboard the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft were analyzed and compared with previous ground-based observations of Mercury at 11 wavelengths. The spectra show no definitive absorption features and display a red spectral slope (increasing reflectance with increasing wavelength) typical of space-weathered rocky surfaces. The MDIS spectra show evidence of phase reddening, which is not observed in the MASCS spectra. The MDIS spectra are commensurate with ground-based observations to within 10%, whereas the MASCS spectra display greater discrepancies with ground-based observations at near-infrared wavelengths. The derived photometric calibrations provide corrections within 10% for observations taken at phase angles less than ∼100°. The derived photometric properties are indicative of a more compact regolith than that of the lunar surface or of average S-type asteroids. The photometric roughness of the surface is also much smoother than the Moon’s. The calculated geometric albedo (reflectance at zero phase) is higher than lunar values. The lower reflectance of immature units on Mercury compared with immature units on the Moon, in conjunction with the higher geometric albedo, is indicative of more complicated grain structures within Mercury’s regolith.     

The formation and stability of carbonic acid on outer Solar System bodies

The radiation chemistry, thermal stability, and vapor pressure of solid-phase carbonic acid (H₂CO₃) have been studied with mid-infrared spectroscopy. A new procedure for measuring this molecule’s radiation stability has been used to obtain intrinsic IR band strengths and half-lives for radiolytic destruction. We report, for the first time, measurements of carbonic acid’s vapor pressure (0.290-2.33 × 10⁻¹¹ bar for 240-255 K) and its enthalpy of sublimation (71 ± 9 kJ mol⁻¹). We also report the first observation of a chemical reaction involving solid-phase carbonic acid. Possible applications of these findings are discussed, with an emphasis on the outer Solar System icy surfaces.     

Evaporation effects on the formation of martian gullies

In order to investigate the formation of martian gullies and the stability of fluids on Mars, we examined about 120 gully images. Twelve HiRISE images contained a sufficient number of Transverse Aeolian Ridges (TARs) associated with the gullies to make the following measurements: overall gully length, length of the alcove, channel and apron, and we also measured the frequency of nearby TARs. Six of the 12 images examined showed a statistically significant negative correlation between overall gully length (alcove, channel and apron length) and TAR frequency. Previous experimental work from our group has shown that at temperatures below ∼200 K, evaporation rate increases by about an order of magnitude as wind speed increases from 0 to ∼15 m/s. Thus the negative correlations we observe between gully length and dune frequency can be explained by formation at temperatures below ∼200 K where wind speed/evaporation is a factor governing gully length. In these cases evaporation of the fluid carving the gully was a constraint on their dimensions. Cases where there is no correlation between gully length and TAR frequency, can be explained by formation at temperatures >200 K. The temperatures are consistent with Global Circulation Model and Thermal Emission Spectrometer (TES) data for these latitudes. The temperatures suggested by these trends are consistent with the fluid responsible for gully formation being a strong brine, such as Fe₂(SO₄)₃ which has a eutectic temperature of ∼200 K. We also find that formation timescales for gullies are 10⁵-10⁶ years.     

Characterization of halophiles in natural MgSO4 salts and laboratory enrichment samples: Astrobiological implications for Mars

The presence of sulfate salts and limited subsurface water (ice) on Mars suggests that any liquid water on Mars today will occur as (magnesium) sulfate-rich brines in regions containing sources of magnesium and sulfur. The Basque Lakes of British Columbia, Canada, represent a hypersaline terrestrial analogue site, which possesses chemical and physical properties similar to those observed on Mars. The Basque Lakes also contain diverse halophilic organisms representing all three Kingdoms of life, growing in surface and near-subsurface environments. Of interest from an astrobiological perspective, crushed magnesium sulfate samples that were analyzed using a modified Lowry protein assay contained biomass in every crystal inspected, with biomass values from 0.078 to 4.21 mg_biomass/g_salt; average=0.74±0.7 mg_biomass/g_salt. Bacteria and Archaea cells were easily observed even in low-biomass samples using light microscopy, and bacteria trapped within magnesium sulfate crystals were observed using confocal microscopy. Regions within the salt also contained bacterial pigments, e.g., carotenoids, which were separate from the cells, indicating that cell lysis might have occurred during entrapment within the salt matrix. These biosignatures, cells, and any ‘soluble’ organic constituents were primarily found trapped within fluid inclusions or fluid-filled void spaces between intergrown crystals. Diffuse reflectance infrared Fourier transform spectroscopy (reflectance IR) analysis of enrichment cultures, containing cyanobacteria, Archaea, or dissimilatory sulfate-reducing bacteria, highlighted molecular biosignature features between 550-1650 and 2400-3000 cm⁻¹. Spectra from natural salts demonstrated that we can detect biomass within salt crystals using the most sensitive biosignatures, which are the 1530-1570 cm⁻¹, C-N, N-H, -COOH absorptions and the 1030-1050 cm⁻¹ C-OH, C-N, PO₄³⁻ bond features. The lowest detection limit for a biosignature absorption feature using reflectance IR was with a natural sample that possessed 0.78 mg_biomass/g_salt. In a model cell, i.e., a 0.5 by 1 μm bacillus, this biomass value corresponds to approximately 7.8×10⁸ cells/g_salt. Based on its ability to detect biomass entrapped within natural sulfate salts, reflectance IR may make an effective remote-sensing tool for finding enrichments of organic carbon within outcrops and surficial sedimentary deposits on Mars.     

Rain infiltration and crust formation in the extreme arid zone of the Atacama Desert, Chile

A key question in understanding life on Mars under dry(ing) conditions is how arid soils respond to small levels of liquid water. We have conducted a series of simulated rain experiments in the hyperarid core region of the Atacama Desert. Rain amounts from 0.24 to 3.55 mm were applied in the early evening to the soil. We conclude that rain events of less than 1 mm do not saturate the surface, and the soil humidity at the surface remains below 100%. Rain events of 2 mm or more generate free water in the pore space of the soil surface, which may be necessary to support biological activity in the soil. The crust on the surface of the soil is a strong barrier to the diffusion of subsurface moisture and subsequent evaporation. Our results show that once the relative humidity in hyperarid soils begins to fall below 100% the rate of decrease is quite rapid. Thus, the precise value assumed for the limits of life or water activity, do not appreciably change the time of water availability resulting from small desert rains. The Atacama Desert results may be applied to models of (H₂O) wetting in the upper soils of Mars due to light rains, melting snow and heavy precipitating fog.     

Yardangs in terrestrial ignimbrites: Synergistic remote and field observations on Earth with applications to Mars

The conditions of formation and the form of yardangs in ignimbrites in the Central Andes of Chile, Bolivia, and Argentina may be the most convincing terrestrial analog to the processes and lithology that produce the extensive yardangs of the Medusae Fossae Formation (MFF) of Mars. Through remote and field study of yardang morphologies in the Central Andes we highlight the role that variable material properties of the host lithology plays in their final form. Here, ignimbrites typically show two main facies: an indurated and jointed facies, and a weakly to poorly indurated, ash- and pumice-rich facies. Both facies are vertically arranged in large (erupted volume >100's of km³) ignimbrites resulting in a resistant capping layer, while smaller (10's of km³) ignimbrites are made predominantly of the weakly indurated facies. The two facies have quite different mechanical properties; the indurated facies behaves as strong rock, fails by block collapse and supports steep/vertical cliffs, while the non-indurated facies is more easily eroded and forms gentle slopes and manifests as more subdued erosional forms. In response to aeolian action, the presence of an upper indurated facies results in large, elongate, high aspect ratio (1:20-1:40) megayardangs that form tall (100 m), thin ridges with steep to vertical walls. These are built on a broad apron of the weakly indurated facies with abundant fallen blocks from the upper indurated facies. These terrestrial megayardangs appear to be analogous to megayardangs with associated block fields seen on Mars. Smaller-volume, weakly indurated ignimbrites are sculpted into smaller, stubbier forms with aspect ratios of 1:5-1:10 and heights rarely exceeding 10 m. Excavation of a windward basal moat suggests an erosional progression like that seen in incipient yardangs on Mars. Excavation rates of 0.007-0.003 cm/year are calculated for the weakly indurated ignimbrites. While a persistent strong unidirectional wind is the dominant parameter controlling yardang formation and orientation, a role for flow separation and vorticity is also suggested by our observations at both yardang types. While the indurated facies is commonly pervasively jointed, jointing is of secondary importance in controlling yardang orientation. Serrated margins, a common feature on Mars, result from oblique intersections of jointing with yardang flanks or scarps of ignimbrite. The processes of yardang formation we describe from ignimbrites from the Central Andes are not necessarily specific to ignimbrites, but do connote that degree and distribution of induration is a major control in yardang formation and this has implications for the lithology of the MFF on Mars.     

Determination of asteroid masses from their close encounters with Mars

An obstacle to the asteroid mass determination lies in the difficulty in isolating the gravitational perturbation exerted by a single asteroid on the planets, being strongly correlated and mixed up with those of many other asteroids. This hindrance may be avoided by the method of analysis presented here: an asteroid mass is estimated in correspondence with its close encounters with Mars where the acceleration it induces on the planet can be sufficiently disentangled from those generated by the remaining asteroid masses to calculate. We test this technique in the analysis of range observations to Mars Global Surveyor and Mars Express performed from 1999 to 2007. For this purpose, we adopt the dynamical model of the planetary ephemeris INPOP06 (Fienga et al., 2008), which includes the gravitational influences of the 300 most perturbing asteroids of the Martian orbit. We obtain the solutions of 10 asteroid masses that have the largest effects on this orbit over the period examined: they are generally in good agreement with determinations recently published.     

Scientific field training for human planetary exploration

Forthcoming human planetary exploration will require increased scientific return (both in real time and post-mission), longer surface stays, greater geographical coverage, longer and more frequent EVAs, and more operational complexities than during the Apollo missions. As such, there is a need to shift the nature of astronauts’ scientific capabilities to something akin to an experienced terrestrial field scientist. To achieve this aim, the authors present a case that astronaut training should include an Apollo-style curriculum based on traditional field school experiences, as well as full immersion in field science programs. Herein we propose four Learning Design Principles (LDPs) focused on optimizing astronaut learning in field science settings. The LDPs are as follows:

(1)

LDP#1: Provide multiple experiences: varied field science activities will hone astronauts’ abilities to adapt to novel scientific opportunities

(2)

LDP#2: Focus on the learner: fostering intrinsic motivation will orient astronauts towards continuous informal learning and a quest for mastery

(3)

LDP#3: Provide a relevant experience—the field site: field sites that share features with future planetary missions will increase the likelihood that astronauts will successfully transfer learning

(4)

LDP#4: Provide a social learning experience—the field science team and their activities: ensuring the field team includes members of varying levels of experience engaged in opportunities for discourse and joint problem solving will facilitate astronauts’ abilities to think and perform like a field scientist.

The proposed training program focuses on the intellectual and technical aspects of field science, as well as the cognitive manner in which field scientists experience, observe and synthesize their environment. The goal of the latter is to help astronauts develop the thought patterns and mechanics of an effective field scientist, thereby providing a broader base of experience and expertise than could be achieved from field school alone. This will enhance their ability to execute, explore and adapt as in-field situations require.     

Lead angles and emitting electron energies of Io-controlled decameter radio arcs

The Io-controlled radio arcs are emissions in the decametric radio range which appear arc shaped in the time-frequency plane. Their occurrence is controlled by Io's position, so it has been for long inferred that they are powered by the Io-Jupiter electrodynamic interaction. Their frequency ranges correspond to the electron cyclotron frequencies along the Io Flux tube, so they are expected to be generated by cyclotron maser instability (CMI). The arc shape was proposed to be a consequence of the strong anisotropy of the decametric radio emissions beaming, combined with the topology of the magnetic field in the source and the observation geometry. Recent papers succeeded at reproducing the morphologies of a few typical radio arcs by modeling in three dimensions the observation geometry, using the best available magnetic field model and a beaming angle variation consistent with a loss-cone driven CMI. In the continuation of these studies, we present here the systematic modeling of a larger number of observations of the radio arcs emitted in Jupiter's southern hemisphere (including multiple arcs or arcs exhibiting abrupt changes of shape), which permits to obtain a statistical determination of the emitting field line localization (lead angle) relative to the instantaneous Io field line, and of the emitting particle velocities or energies. Variations of these parameters relative to Io's longitude are also measured and compared to the location of the UV footprints of the Io-Jupiter interaction. It is shown that the data are better organized in a reference frame attached to the UV spot resulting from the main Alfvén wing resulting from the Io-Jupiter interaction. It is proposed that the radio arcs are related to the first reflected Alfvén wing rather than to the main one.