Single frequency processing of Ørsted GPS radio occultation measurements

The Global Positioning System (GPS) radio occultation measurements obtained using the TurboRogue GPS receiver on the Danish satellite Ørsted have been processed using the single frequency method. Atmospheric profiles of refractivity and temperature are derived and validated against numerical weather prediction data from the European Centre for Medium-Range Weather Forecast (ECMWF). Results from the Ørsted GPS measurement campaign in February 2000 indicate that the single frequency method can provide retrievals with accuracy comparable to that of using two frequencies. From comparisons between measured dry temperature profiles and corresponding dry temperature profiles derived from ECMWF analysis fields, we find a mean difference of less than 0.5 K and a standard deviation of 2–4 K between 500 and 30 hPa in height. Above 30 hPa the impact of the ionosphere becomes more dominant and more difficult to eliminate using the single frequency method, and the results show degraded accuracy when compared to previous analysis results of occultation data from other missions using the dual frequency method. At latitudes less than 40° (denoted low latitudes), the standard deviation is generally smaller than at latitudes higher than 40° (denoted high latitudes). A small temperature bias is observed centered at 200 hPa for low latitudes and at 300 hPa for high latitudes. This indicates that the ECMWF analyses do not adequately resolve the tropopause temperature minimum. In the lowest part of the troposphere an observed warm bias is thought to be due to erroneous tracking of the GPS signal in cases of atmospheric multipath propagation.     

Spatial variation of overbank aggradation rate and its influence on avulsion frequency

Abstract River avulsions are commonly considered to be driven by the aggradation and growth of alluvial ridges, and the associated increase in cross‐valley slope relative to either the down‐channel slope or the down‐valley slope (the latter is termed the slope ratio in the present paper). Therefore, spatial patterns of overbank aggradation rate over stratigraphically relevant time scales are critical in avulsion‐dominated models of alluvial architecture. Detailed evidence on centennial‐ to millennial‐scale floodplain deposition has, to date, been largely unavailable. New data on such long‐term overbank aggradation rates from the Rhine–Meuse and Mississippi deltas demonstrate that the rate of decrease of overbank deposition away from the channel belt is much larger than has been supposed hitherto, and can be similar to observations for single overbank floods. This leads to more rapid growth of alluvial ridges and more rapid increase in slope ratios, potentially resulting in increased avulsion frequencies. A revised input parameter for overbank aggradation rate was used in a three‐dimensional model of alluvial architecture to study its effect on avulsion frequency. Realistic patterns of avulsion and interavulsion periods (≈1000 years) were simulated with input data from the Holocene Rhine River, with avulsions occurring when the slope ratio is in the range 3–5. However, caution should be practised with respect to uncritical use of these numbers in different settings. Evidence from the two study areas suggests that the avulsion threshold cannot be represented by one single value, irrespective of whether critical slope ratios are used, as in the present study, or superelevation as has been proposed by other investigators.     

The fall and rise of metropolitan government in Copenhagen

In this paper it is argued that the re-establishment of a metropolitan government in the Greater Copenhagen Area in 2000 (Greater Copenhagen Authority) is not to be seen as a return to the kind of regional, coordinative authority (Greater Copenhagen Council) that was abolished in the Thatcherite climate of the 1980s. Throughout the 1980s and 1990s new forms of urban governance, entrepreneurialism and a higher national priority to the capital region were introduced, which changed the conditions under which the new metropolitan government is operating. This `contextualization' of the analysis of the two generations of metropolitan government points to the fact that typologies of metropolitan government, such as the one put forward by Sharpe (1995), often lacks analytical cogency. This revised version was published online in August 2006 with corrections to the Cover Date.     

Electrons in feldspar II: a consideration of the influence of conduction band-tail states on luminescence processes

 Most natural feldspars contain many charged impurities, and display a range of bond angles, distributed about the ideal. These effects can lead to complications in the structure of the conduction band, giving rise to a tail of energy states (below the high-mobility conduction band) through which electrons can travel, but with reduced mobility: transport through these states is expected to be thermally activated. The purpose of this article is twofold. Firstly, we consider what kind of lattice perturbations could give rise to both localized and extended conduction band-tail states. Secondly, we consider what influence the band tails have on the luminescence properties of feldspar, where electrons travel through the sample prior to recombination. The work highlights the dominant role that 0.04–0.05-eV phonons play in both the luminescence excitation and emission processes of these materials. It also has relevance in the dating of feldspar sediments at elevated temperatures. Received: 11 May 2001 / Accepted: 6 September 2001     

Premelting and calcium mobility in gehlenite (Ca2Al2SiO7) and pseudowollastonite (CaSiO3)

 Premelting effects in gehlenite (Ca₂Al₂SiO₇) have been studied by Raman spectroscopy and calorimetry, and in gehlenite and pseudowollastonite (CaSiO₃) by electrical conductivity. The enthalpy of premelting of gehlenite is 17.3 kJ mol⁻¹ and represents 9% of the reported enthalpy of fusion, which is in the range of the reported fraction of other minerals. The Raman and electrical conductivity experiments at high temperatures, for gehlenite and pseudowollastonite, show that the premelting effects of both compositions are associated with enhanced dynamics of calcium atoms near the melting point. This conclusion agrees with the results obtained for other minerals like diopside, but contrasts with those found for sodium metasilicate in which the weaker bonding of sodium allows the silicate framework to distort near the melting temperature and deform in such a way to prefigure the silicate entities present in the melt. Received: 30 April 2002 / Accepted: 7 August 2002 Acknowledgements We thank Y. Linard for help with DSC measurements and two anonymous reviewers for their constructive comments. This work has been partly supported by the EU Marie-Curie fellowship contract no. HPMF-CT-1999-00329, the CNRS-Carnegie Institution of Washington program PICS no.192, and the NSF grants EAR-9614432 and EAR-9901886 to B.O.M.     

A model of oscillatory zoning in solid solutions grown from aqueous solutions: Applications to the (Ba,Sr)SO4 system

Barite-celestite crystals can be synthesized from aqueous solutions during counter-diffusion in a gel column connecting two reservoirs. It is known that such crystals may exhibit oscillatory zoning, whereby the barium composition in the crystal fluctuates more or less regularly from the core of the crystal to its rim. We present here a simple model of oscillatory zoning in such binary solid solutions A₁A₂ grown from aqueous solutions. The model combines diffusive transport of the relevant ions with an autocatalytic growth process. The latter is formulated as a continuous growth in which the probability of finding a kink site on the growing surface depends on the chemical composition of that surface. Thus, an A₁-rich surface favors the growth of A₁ over A₂, as long as A₁ is present in the vicinity of the surface. Precipitation results in a local depletion of A₁ in the aqueous solution, and the system may switch to a A₂ growth mode, until diffusion replenishes the amount of A₁, and so on. We use a dynamical equation for the molar fraction of component A₁ in the crystal, which results from mass conservation across the rough crystal-solution interface. Linear stability analysis and direct numerical solutions show that the system exhibits oscillatory behavior. Using the barite-celestite system as a framework, the scaling is consistent with the experimental observations. We discuss the variety of zoning patterns and textures numerically obtained as the concentrations of reactants in the reservoirs vary. This model might help in understanding the formation of oscillatory zoning in hydrothermal environments.     

Phytoplankton, nutrients, and transparency in Danish coastal waters

We present a comparative analysis of 1400 data series of water chemistry (particularly nitrogen and phosphorus concentrations), phytoplankton biomass as chlorophylla (chla) concentrations, concentrations of suspended matter and Secchi depth transparency collected from the mid-1980s to the mid-1990s from 162 stations in 27 Danish fjords and coastal waters. The results demonstrate that Danish coastal waters were heavily eutrophied and had high particle concentrations and turbid waters. Median values were 5.1 μg chla 1⁻¹, 10.0 mg DW 1⁻¹ of suspended particles, and Secchi depth of 3.6 m. Chlorophyll concentration was strongly linked to the total-nitrogen concentration. The strength of this relationship increased from spring to summer as the concentration of total nitrogen declined. During summer, total nitrogen concentrations accounted for about 60% of the variability in chlorophyll concentrations among the different coastal systems. The relationship between chlorophyll and total phosphorus was more consistant over the year and correlations were much weaker than encountered for total nitrogen. Secchi depth could be predicted with good precision from measurements of chlorophyll and suspended matter. In a multiple stepwise regression model with In-transformed values the two variables accounted for most of the variability in water transparency for the different seasons and the period March–October as a whole (c. 80%). We were able to demonstrate a significant relationship between total nitrogen and Secchi depth, with important implications for management purposes.     

Wave velocities and attenuation of shaley sandstones as a function of pore pressure and partial saturation

We obtain the wave velocities and quality factors of clay‐bearing sandstones as a function of pore pressure, frequency and partial saturation. The model is based on a Biot‐type three‐phase theory that considers the coexistence of two solids (sand grains and clay particles) and a fluid mixture. Additional attenuation is described with the constant‐Q model and viscodynamic functions to model the high‐frequency behaviour. We apply a uniform gas/fluid mixing law that satisfies the Wood and Voigt averages at low and high frequencies, respectively. Pressure effects are accounted for by using an effective stress law. By fitting a permeability model of the Kozeny– Carman type to core data, the model is able to predict wave velocity and attenuation from seismic to ultrasonic frequencies, including the effects of partial saturation. Testing of the model with laboratory data shows good agreement between predictions and measurements.     

Comparison of Seismic Dispersion and Attenuation Models

The frequency-dependent attenuation of seismic waves causes decreased resolution of seismic images with depth, and the difference in transmission losses induces amplitude variations with offset. Transmission losses may occur due to friction or fluid movement, or may result from scattering in thin-layer. Whatever the physical mechanism, they can often be conveniently described using an empirical formulation wherein the elastic moduli and propagation velocity are complex functions of frequency.We have compiled and compared algebraically and numerically eight different models involving complex velocity: the Kolsky-Futterman model, the power-law model, Kjartansson's model, Müller's model, Azimi's second and third model, the Cole-Cole model, and the standard linear-solid model.For two different parameter sets, the attenuation and phase velocity are computed in the seismic frequency band, and the plane-wave propagation of a Ricker wavelet for the other models is compared with that for the Kolsky-Futterman model. The first parameter set consists of parameters for each of the models calculated from expressions given in the appendix. These expressions make the different models behave similarly to the KF model. The second parameter set consists of model parameters that are numerically adapted to the KF model.By selecting proper parameters, all models, except the standard linear-solid model, show behavior similar to that of the Kolsky-Futterman model. The SLS model behaves differently from the other models as the frequency goes to zero or infinity. Broadband measurement data is needed to select a specific model for a given seismic experiment.