Simulating Stable Isotope Ratios in Plumes of Groundwater Pollutants with BIOSCREEN‐AT‐ISO

BIOSCREEN is a well‐known simple tool for evaluating the transport of dissolved contaminants in groundwater, ideal for rapid screening and teaching. This work extends the BIOSCREEN model for the calculation of stable isotope ratios in contaminants. A three‐dimensional exact solution of the reactive transport from a patch source, accounting for fractionation by first‐order decay and/or sorption, is used. The results match those from a previously published isotope model but are much simpler to obtain. Two different isotopes may be computed, and dual isotope plots can be viewed. The dual isotope assessment is a rapidly emerging new approach for identifying process mechanisms in aquifers. Furthermore, deviations of isotope ratios at specific reactive positions with respect to “bulk” ratios in the whole compound can be simulated. This model is named BIOSCREEN‐AT‐ISO and will be downloadable from the journal homepage.     

Spatiotemporal evolution of the completeness magnitude of the Icelandic earthquake catalogue from 1991 to 2013

In 1991, a digital seismic monitoring network was installed in Iceland with a digital seismic system and automatic operation. After 20 years of operation, we explore for the first time its nationwide performance by analysing the spatiotemporal variations of the completeness magnitude. We use the Bayesian magnitude of completeness (BMC) method that combines local completeness magnitude observations with prior information based on the density of seismic stations. Additionally, we test the impact of earthquake location uncertainties on the BMC results, by filtering the catalogue using a multivariate analysis that identifies outliers in the hypocentre error distribution. We find that the entire North-to-South active rift zone shows a relatively low magnitude of completeness M_c in the range 0.5–1.0, highlighting the ability of the Icelandic network to detect small earthquakes. This work also demonstrates the influence of earthquake location uncertainties on the spatiotemporal magnitude of completeness analysis.     

The coast between Cabo de Santa Maria (Portugal) and Rabat (Morocco): a mega-size headland-bay shoreline under control of the North Atlantic swell?

Equilibrium headland-bay beach systems have been mathematically described by logarithmic, parabolic and hyperbolic curve functions. The largest system of this type reported to date has a shoreline length of about 62 km. In the present study, an apparent headland-bay system is presented which has a shoreline length of about 500 km. It was discovered on satellite images, and is located between Cabo de Santa Maria in Portugal and the coastal city of Rabat in Morocco. It appears to be controlled by long-period North Atlantic swells diffracting around Cabo São Vicente at the south-western tip of Portugal, in combination with SW–SE wind wave climates impinging on the northern shoreline of Cádiz Bay. The coast shows two marked departures from the equilibrium shoreline along its central section north and south of the Strait of Gibraltar, which are easily explained. Thus, the promontories to the north of the strait still exist because there has not been sufficient time to erode these back to the equilibrium shoreline since postglacial sea-level recovery. The coastal indentation to the south is explained by an insufficient sediment supply from terrestrial sources to facilitate the required beach accretion. Perfectly adjusted planimetric headland-bay shoreline shapes represent situations where wave orthogonals approach the coast at right angles everywhere, i.e. there is no longer any alongshore sediment transport. Equilibrium shorelines form independently of the grain size of the beach sediment, whereas morphodynamic beach states are indirectly affected by the shoreline shapes because the latter are modulated by wave period and breaker height which also control the morphodynamic response of the beach in combination with the local grain size.     

Mullite in Libyan Desert Glass: Evidence for high-temperature/low-pressure formation

Libyan Desert Glass (LDG) is a SiO₂-rich natural glass whose origin, formation mechanism, and target material are highly debated. We here report on the finding of a lens-shaped whitish inclusion within LDG. The object is dominantly composed of siliceous glass and separated from the surrounding LDG by numerous cristobalite grains. Within cristobalite, several regions rich in mullite often associated with ilmenite were detected. Mineral assemblage, chemical composition, and grain morphologies suggest that mullite was formed by thermal decomposition of kaolinitic clay at atmospheric pressure and T ≥ 1600 °C and also attested to high cooling rates under nonequilibrium conditions. Cristobalite contains concentric and irregular internal cracks and is intensely twinned, indicating that first crystallized β-cristobalite inverted to α-cristobalite during cooling of the SiO₂-rich melt. The accompanied volume reduction of 4% induced the high density of defects. The whitish inclusion also contains several partly molten rutile grains evidencing that at least locally the LDG melt was at T ≥ 1800 °C. Based on these observations, it is concluded that LDG was formed by high-temperature melting of kaolinitic clay-, rutile-, and ilmenite-bearing Cenozoic sandstone or sand very likely during an asteroid or comet impact onto Earth. While melting and ejection occurred at high pressures, the melt solidified quickly at atmospheric pressure.     

Evolution on the AGB and beyond: on the formation of H-deficient post-AGB stars

The evolution on the AGB and beyond is reviewed with respect to the origin of Wolf-Rayet central stars. We focus on thermal pulses due to their particular importance for the evolution of hydrogen deficient stars. It is shown that overshoot applied to all convection regions is a key ingredient to model these objects leading to intershell abundances already close to the surface abundances of Wolf-Rayetcentral stars. In contrast to standard evolutionary calculations, overshoot models do show dredge up for very low envelope masses and efficient dredge up was found even during the post-AGB stage. Three thermal pulse scenarios for Wolf-Rayet central stars can nowbe distinguished: an AGB Final Thermal Pulse (AFTP) occurring at the very end of the AGB evolution, a Late Thermal Pulse (LTP) occurring during the post-AGBevolution when hydrogen burning is still on, and a Very Late Thermal Pulse (VLTP) occurring on the cooling branch when hydrogen burning has already ceased. All scenarios lead to hydrogen-deficient post-AGB stars with carbon and oxygen abundances as observed for Wolf-Rayet stars.Hydrogen is either diluted by dredge up (AFTP, LTP) or completely burnt (VLTP).     

Evidence for chemical evolution in spectra of high redshift galaxies

Using a sample of 57 VLT FORS spectra in the redshift range 1.37< z < 3.40 and a comparison sample with 36 IUE spectra of local ( ) starburst galaxies we derive CIV equivalent width values and estimate metallicities of starburst galaxies as a function of redshift. Assuming that a calibration of the CIV equivalent widths in terms of the metallicity based on the local sample of starburst galaxies is applicable to high-z objects, we find a significant increase of the average metallicities from about 0.16 Z _⊙ at the cosmic epoch corresponding to z ≈ 3.2 to about 0.42 Z _⊙ at z ≈ 2.3. A significant further increase in metallicity during later epochs cannot be detected in our data. Compared to the local starburst galaxies our high-redshift objects tend to be overluminous for a given metallicity. This revised version was published online in August 2006 with corrections to the Cover Date.