Petrological evolution of a suite of spinel granulites from Vizianagram, Eastern Ghats Belt, India, and genesis of sapphirine-bearing assemblages

A suite of spinel–cordierite granulites from Viziangram, Eastern Ghats Belt, India preserve mineral assemblages and reaction textures indicative of peak metamorphic conditions of >1000 °C, >8<10 kbar, followed successively by near isobaric cooling (down to 750–800 °C), near isothermal decompression (to 4–5 kbar), and late hydration. P–T conditions of each stage are evaluated through a combination of petrogenetic grid approach and thermobarometry. Sapphirine is developed in sillimanite‐bearing acid pegmatite veins that intruded the spinel–cordierite granulite close to peak metamorphic conditions, and also in the host rock in immediate contact with the pegmatite. Both sillimanite and sapphirine in the pegmatite are considered to be magmatic phases. Field observations and textural characteristics suggest that Al‐metasomatism of the spinel–cordierite granulite due to the intrusion of pegmatite was responsible for sapphirine formation in the spinel granulite.     

Application of meteorological and vegetation indices for evaluation of drought impact: a case study for Rajasthan, India

Drought is a serious climatic condition that affects nearly all climatic zones worldwide, with semi-arid regions being especially susceptible to drought conditions because of their low annual precipitation and sensitivity to climate changes. Drought indices such as the standardized precipitation index (SPI) using meteorological data and vegetation indices from satellite data were developed for quantifying drought conditions. Remote sensing of semi-arid vegetation can provide vegetation indices which can be used to link drought conditions when correlated with various meteorological data based drought indices. The present study was carried out for drought monitoring for three districts namely Bhilwara, Kota and Udaipur of Rajasthan state in India using SPI, normalized difference vegetation index (NDVI), water supply vegetation index (WSVI) and vegetation condition index (VCI) derived from the Advanced Very High resolution Radiometer (AVHRR). The SPI was computed at different time scales of 1, 2, 3, 6, 9 and 12 months using monthly rainfall data. The NDVI and WSVI were correlated to the SPI and it was observed that for the three stations, the correlation coefficient was high for different time scales. Bhilwara district having the best correlation for the 9-month time scale shows late response while Kota district having the best correlation for 1-month shows fast response. On the basis of the SPI analysis, it was found that the area was worst affected by drought in the year 2002. This was validated on the basis of NDVI, WSVI and VCI. The study clearly shows that integrated analysis of ground measured data and satellite data has a great potential in drought monitoring.     

Qualitative stability assessment of cut slopes along the National Highway-05 around Jhakri area,Himachal Pradesh,India

Several deformation phases in tectonically active Himalayas have rendered the rock masses very complex in terms of structure, lithology and degree of metamorphism. Again, anthropogenic activities such as roads, tunnels and other civil engineering constructions have led to a state of disequilibrium which in many cases, results in failure of rock masses. National Highway-05 around Jhakri area in India is a major connecting route to the China border in the hilly terrains of the state Himachal Pradesh. It cuts through the Himalayan rocks and has a hazardous history of landslides destroying human lives and interrupting communication very frequently. As a contribution towards the mitigation process, a study has been carried out along the highway to analyse kinematic stability and qualitative estimation of rock mass condition through rock mass classification systems. The kinematic analysis shows that the rock slopes are prone to planar and wedge failure. Rock mass rating for most of the locations lies between 7 and 34, representing a poor rock mass quality (Class IV), whereas slope mass rating is more disperse and ranges from 11 to 52 for most of the slopes (Class III, IV and V).     

A Three Dimensional Comparative Study of Seismic Behaviour of Vertical and Batter Pile Groups

To a practicing foundation engineer, the performance of batter pile under seismic conditions still remains a questionable prospect. The contradictory findings reported by various investigators with regard to the performance of batter piles add to this dilemma. This calls for a rigorous three-dimensional investigation to evaluate seismic behavior of batter pile groups. In this study, a comparative assessment of three-dimensional seismic behavior of a 2 × 2 vertical and batter pile groups having batter angle of 15° was carried out using a full three-dimensional finite element code developed in MATLAB (Sarkar 2009). The effects of centre to centre spacing of piles and soil modulus values were investigated. Idealized soil profiles having constant and triangular variation of soil modulus were adopted for the study. Results of analyses for both the vertical and batter pile groups are presented in terms of dynamic stiffness and kinematic interaction factors. Results indicate better seismic performance of batter pile groups in comparison to that of vertical pile groups. To demonstrate the importance of the findings, a five-storied portal frame structure supported separately on vertical and batter pile groups were considered and analyzed for El-Centro Earthquake (1940) time history. The difference in structural response considering vertical and batter pile groups is highlighted.     

Kinetics of oxytetracycline sorption on magnetite nanoparticles

Iron oxide nanoparticles (nano-Fe) have been widely used in environmental remediation, including that of emerging contaminants, such as antibiotics. Magnetite nanoparticles (nano-Fe₃O₄) have been reported to form on the outer surface of nano-Fe and have the potential to be a good sorbent for certain antibiotics. This study reports, for the first time, the kinetics and thermodynamics of adsorption of a common tetracycline group antibiotic, oxytetracycline (OTC), on nano-Fe₃O₄. Batch sorption kinetics were evaluated by varying initial OTC concentration (0.25–2 mM), nano-Fe₃O₄ concentration (2.5–20 g L^?1), pH (3.8–7.6), temperature (5, 15, 35 °C), and ionic strength (0.01–0.5 M KCl) to derive thermodynamic and kinetic constants. Results show that OTC sorption kinetics is rapid and increases with increasing temperature. The derived thermodynamic constants suggest a surface chemical-controlled reaction that proceeds via an associative mechanism. Results indicate the potential of developing a nano-magnetite-based remediation system for tetracycline group of antibiotics.     

Slope stability assessment and design of remedial measures for Tungnath Temple at Uttarakhand,India: a case study

Natural Hazards - The present paper assesses the slope&nbsp;stability of the Tungnath Temple at Rudraprayag District, in the Indian state of Uttarakhand, and suggests the remedial measures. The...     

Tectonic Significance of Fissure Veins Associated with Pseudotachylites of the Kui-Chitraseni Shear Zone, Aravalli Mountain, NW India

Kui-Chitraseni Shear Zone of the Precambrian Aravalli Mountain, NW India is marked by a nearly 400 m-wide NE-SW trending belt of cataclasites developed on the granites and metasediments of the Delhi Supergroup. The cataclasites are criss crossed by pseudotachylite and fissure-veins. While the pseudotachylites are aphanitic to microlitic, the fissure veins are characterized by syntaxial-bitaxial as well as unitaxial growth of elongate quartz grains. Textural study of the fissure veins suggests crystallization of quartz grains in a dilational environment in hydrous condition. Contrarily the pseudotachylites bear the evidence of frictional melting of rocks under anhydrous conditions. Since in many instances it is observed that the fissure veins have replaced the pseudotachylites following the crack seal mechanism, the formation of fissure veins is considered to be latekinematic to pseudotachylites. Hence it is interpreted that the pseudotachylites and fissure veins were formed in two distinct tectonic events. While pseudotachylites were formed in a compressional setting resulted from thrusting along the shear zone, the fissure veins have been formed in an extensional setting during a late stage normal faulting. In light of this tectonic rejuvenation along the Kui-Chitraseni Shear Zone, various lineaments present within the Aravalli Mountains need further study for understanding the evolution of the region.     

Distribution of polycyclic aromatic hydrocarbons in recent sediments of Sundarban mangrove wetland of India and Bangladesh: a comparative approach

The present work is the first attempt to compare the data of a comprehensive study of the origin and distribution of 16 priority pollutant polycyclic aromatic hydrocarbons (PAHs) in surface sediments (<63 μm) from 18 sampling stations, 9 from Sundarban of Bangladesh and 9 from Indian counterpart. Σ19PAHs concentration in sediments showed wide variations from 208.3 to 12,993.1 ng g^?1 dry weight in Indian Sundarban, whereas 208.4 to 4,687.9 ng g^?1 in the case of Bangladesh. Fluoranthene, pyrene, benzo(b)fluoranthene, benzo(a)pyrene and dibenzo(a,h)anthracene were predominant species for both the countries. The PAH diagnostic ratios indicated that the PAHs in sediments from both the countries were of mixed source of hydrocarbons of both petrogenic and pyrolytic origin. According to the numerical effect-based sediment quality guidelines, the levels of PAHs in the Sundarban wetland of Bangladesh and India should not exert adverse biological effects. The TEQ values calculated for samples from the Bangladesh and Indian Sundarban varied from 13.68 to 1,014.75 and 1.31 to 2,451 ng g^?1 d.w. with an average of 221.02 and 358.63 ng g^?1, respectively. The overall contamination status of PAH was higher in India than Bangladesh.     

Heavy metal pollution assessment through comparison of different indices in sewage-fed fishery pond sediments at East Kolkata Wetland,India

The sediments of the raw sewage-fed fishpond system at East Kolkata Wetland (EKW) were analyzed for heavy metal content in a comprehensive way. Various indices of contamination like enrichment factor (EF), geo-chemical index (I _geo), modified degree of contamination (mD_C), and pollution load index (PLI) were assessed. In all cases, instead of literature values, the metal concentrations of less contaminated sites, separated by the statistical approach of the hierarchical cluster analysis, were used as baseline values. In the present study, about 70% of the pond sediments are found uncontaminated, 5% display low degree of contamination and 25% are designated as moderate degree of contamination. Both the EF and I _geo indices highlighted that the metals lead (Pb), cadmium (Cd), and chromium (Cr) are responsible for the contamination while there is little anthropogenic input in cases of Cu, Zn, and Ni. Most of the ponds situated near the main sewage flowing canals as well as the main traffic highway and close to the solid waste dumping areas recorded higher degree of metal contamination as evident from spatial variation of mD_C and PLI indices in the study area. Indices comparison study clearly indicates that although these are calculated using different methods, these may or may not produce the same indices values and hence the values should neither be compared nor be averaged. But all the above indices are directly related to a common term contamination factor (CF). Classification of contamination levels based on these CF values is found to be similar and this classification is only valid up to the level of high degree of contamination. Thus, the use of any one of these indices is sufficient to classify the degree of contamination of an area. However, to evaluate the contamination per metal, both I _geo and EF are effective while, to assess the composite effect of all the metals, PLI is preferable to mD_C.