Petrological and geochemical characteristics of Marunthurkota syenites from the Kerala khondalite belt,southern India

This note reports new occurrences of syenite bodies around Marunthurkota area from the Kerala khondalite belt (KKB). Petrological and geochemical studies suggest that the syenites have a pronounced A-type affinity, metaluminous characteristics with high concentrations of alkalies, Rb, Sr, Zr, and high K₂O/Na₂O ratio. Miaskitic nature (agpaitic index<1) of syenite suggest involvement of CO₂ related phase in their genesis. The petrological characteristics signify crystallization of the rock at shallow levels within the crust. Geochemistry favours mantle origin of the magma and enrichment of Ba and Sr are indicative of involvement of carbonatite melt in the source region. The study envisages the presence of a juvenile CO₂ enriched upper mantle below the southern Indian continental crust during the Pan-African time.     

Pleistocene radiolarians from the Leg 119 Site 745, sections (1H to 4H) in the southern ocean region

This paper presents a detailed record of radiolarian species from the Leg 119 Site 745 (sections 1H to 4H) in the southern ocean region. Forty five species were identified and illustrated from forty six samples. The taxonomy, two radiolarian zones namely NR1 and NR2, morphological variations and distribution of taxa have been made from these sections. Twelve new species are identified but they are not formally named. The study provides the detailed Antarctic Pleistocene radiolarian data, proposed the placement of NR1 and NR2 zonal boundary at a shallow depth of 6.63 mbsf and data is used for comparative studies with other parts of the Antarctic region.     

Numerical modeling of flow patterns around subducting slabs in a viscoelastic medium and its implications in the lithospheric stress analysis

This paper presents results obtained from numerical model experiments to show different patterns of mantle flow produced by lithospheric movement in subduction zones. Using finite element models, based on Maxwell rheology (relaxation time ∼ 10¹¹S), we performed three types of experiments: Type 1, Type 2 and Type 3. In Type 1 experiments, the lithospheric slab subducts into the mantle by translational movement, maintaining a constant subduction angle. The experimental results show that the flow perturbations occur in the form of vortices in the mantle wedge, irrespective of subduction rate and angle. The mantle wedge vortex is coupled with another vortex below the subducting plate, which tends to be more conspicuous with decreasing subduction rate. Type 2 experiments take into account a flexural deformation of the plate, and reveal its effect on the flow patterns. The flexural motion induces a flow in the form of spiral pattern at the slab edge. Density-controlled lithospheric flexural motion produces a secondary flow convergence zone beneath the overriding plate. In many convergent zones the subducting lithospheric plate undergoes detachment, and moves down into the mantle freely. Type 3 experiments demonstrate flow perturbations resulting from such slab detachments. Using three-dimensional models we analyze lithospheric stresses in convergent zone, and map the belts of horizontal compression and tension as a function of subduction angle.     

Effect of Geotextile Ties on Uplift Capacity of Anchors Embedded in Sand

This paper presents the results of experimental investigation on the effect of geotextile ties on uplift capacity of anchors embedded in sand. Uplift capacity of anchor increases with increase in embedment depth to base diameter (H/D) ratio irrespective of type of anchor. With the introduction of tie to anchors, uplift capacity of anchors increases and optimum number of layers of ties is found to be 2. A non linear power model has been developed to predict the uplift capacity at any settlement (Q _R) of anchors with tie in terms of uplift capacity at any settlement (Q _URs) of anchor without tie, H/D ratio, number of layers of tie and displacement to base diameter ratio (Δ/D). The model is applicable for predicting Q _R having the values of Q _RS, H/D, N and Δ/D in the range of 0.257 ≤ Q _URs ≤ 1.420, 1.5 ≤ H/D ≤ 3.0, 1 ≤ N ≤ 4, 0.8 ≤ Δ/D ≤ 8.     

A baseline study of trace metals in a coral reef sedimentary environment,Lakshadweep Archipelago

Surficial and core samples collected from the sedimentary microenvironments of Lakshadweep Archipelago were analysed for their trace metal contents. The synoptical relations in spatial distributions with respect to environmental conditions such as pH, organic carbon and sediment texture were inter-correlated. Some of the metals exhibited good correlations with Fe/Mn, which reflect their similarity in distribution rather than anthropogenic enrichment. Inter-relating the variations in metal—pH relationships with metal—organic carbon, in general, those which exhibited positive correlations with pH, displayed negative interactions with organic carbon content and vice versa. Comparatively, higher values of Fe in the mangrove area of one of the islands highlight the possibility of precipitation of Fe as iron sulphides, which are common in mangrove ecosystem. Based on the contamination factors for Pb, Zn and Cd, as well as the geo-accumulation index of Cd, it can be generalised that some of the islands remain polluted with respect to these elements. An evaluation based on pollution load index shows that none of the islands surveyed for this study posed a serious threat in trace metal pollution. Bray Curtis similarity index was computed to find out the similarity among metals/islands, using non-transformed data of metal concentrations. Group linkage clustering technique was used for drawing dendrograms to show the similarity among them.     

Modeling the behaviour of alluvial and blasted quarried rockfill materials

Two types of modeled rockfill materials were collected from Renuka dam site, Himachal Pradesh, India and Salma dam site, Afghanistan. The rockfill material collected from Renuka dam site is rounded to sub-rounded in shape and the rockfill material collected from Salma dam site is angular to sub-angular in shape. The prototype gradation rockfill material consists maximum particle size larger than 1,000 mm. Therefore, for carrying out laboratory testing and modeling the bahaviour, the prototype rockfill material is scaled down to the maximum particle size (d_max) of 25, 50 and 80 mm for both projects material using parallel gradation technique. Triaxial compression and Index properties tests were conducted on both project rockfill materials and are presented. From the triaxial behaviour, it is observed that the stress–strain behaviour is non-linear, inelastic and stress dependent for both the materials. The material compresses during the initial shearing and shows dilation effect with further shearing. It is observed that the ?-value for alluvial rockfill material increases with increase in d_max and reverse trend is observed for blasted quarried rockfill material which shows the importance of the type of material. The stress–strain-volume change behaviour of both projects modeled rockfill material was predicted by using hierarchical single surface (HISS) model based on elasto plasticity and compared with the laboratory test results. From the comparison, it is observed that both results match closely. It is, therefore, suggested that the behaviour of both types of rockfill materials can be characterized successfully using HISS model.     

Geochemical alterations in surface waters of Govind Ballabh Pant Sagar,Northern Coalfield,India

Major ions showed high concentrations, ionic strength and chemical activity in the surface waters of Govind Ballabh Pant Sagar reservoir. Various geochemical ratios showed the dominance of silicate over carbonate weathering and major ions such as Na⁺ + K⁺ account for about 52 % of the cation budget. The high Na⁺ and K⁺ showed sedimentation of rock/coal particles consisting of highly weathered silicate minerals contributed by the discharge of mine water, fly ash mixing during transportation, etc. Further, Ca²⁺ + Mg²⁺/Na⁺ + K⁺ ratio was <1 (0.92) indicating the occurrence of silicate weathering in the reservoir catchment. The comparative assessment showed that the proportion of Ca²⁺ + Mg²⁺/Na⁺ + K⁺ tends to be lower along the coal mining belts compared to non-coal mining regions in the world. The Ca²⁺/SO₄ ^2? ratio <1 revealed not only H₂CO₃ but H₂SO₄ also acting as a source of protons for rock weathering. The cause underlying these differences can be related directly to geological substrate and anthropogenic activities.     

Evidence for Proterozoic Collision from Airborne Magnetic and Gravity Studies in Southern Granulite Terrain, India and Signatures of Recent Tectonic Activity in the Palghat Gap

The composite airborne total intensity map of the Southern Granulite Terrain (SGT) at an average elevation of 7000' (≈ 2100 m) shows bands of bipolar regional magnetic anomalies parallel to the structural trends suggesting the distribution of mafic/ultramafic rocks that are controlled by regional structures/shear zones and thrusts in this region. The spectrum and the apparent susceptibility map computed from the observed airborne magnetic anomalies provide bands of high susceptibility zones in the upper crust associated with known shear zones/thrusts such as Transition Zone, Moyar-Bhavani and Palghat-Cauvery Shear Zones (MBSZ and PCSZ). The quantitative modelling of magnetic anomalies across Transition Zone, MBSZ and PCSZ suggest the presence of mafic rocks of susceptibility (1.5-4.0 × 10⁻³ CGS units) in upper crust from 8-10 km extending up to about 21-22 km, which may represent the level of Curie point geotherm as indicated by high upper mantle heat flow in this section.Two sets of paired gravity anomalies in SGT and their modelling with seismic constraints suggest gravity highs and lows to be caused by high density mafic rocks along Transition Zone and Cauvery Shear Zone (CSZ) in the upper crust at depth of 6-8 km and crustal thickening of 45-46 km south of them, respectively. High susceptibility and high density rocks (2.8 g/cm³) along these shear zones supported by high velocity, high conductivity and tectonic settings suggest lower crustal mafic/ultramafic granulite rocks thrusted along them. These signatures with lower crustal rocks of metamorphic ages of 2.6-2.5 Ga north of PCSZ and Neoproterozoic period (0.6-0.5 Ga) south of it suggest that the SGT represents mosaic of accreted crust due to compression and thrusting. These observations along with N-verging thrusts and dipping reflectors from Dharwar Craton to SGT suggest two stages of N-S directed compression: (i) between Dharwar Craton and northern block of SGT during 2.6-2.5 Ga with Transition Zone and Moyar Shear towards the west as thrust, and (ii) between northern and southern blocks of SGT with CSZ as collision zone and PCSZ as thrust during Neoproterozoic period (0.6-0.5 Ga). The latter event may even represent just a compressive phase without any collision related to Pan-African event. The proposed sutures in both these cases separate gravity highs and lows of paired gravity anomalies towards north and south, respectively. The magnetic anomalies and causative sources related to Moyar Shear, MBSZ and PCSZ join with those due to Transition Zone, Mettur and Gangavalli Shears in their eastern parts, respectively to form an arcuate-shaped diffused collision zone during 2.6-2.5 Ga.Most of the Proterozoic collision zones are highlands/plateaus but the CSZ also known as the Palghat Gap represents a low lying strip of 80-100 km width, which however, appears to be related to recent tectonic activities as indicated by high upper mantle heat flow and thin crust in this section. It is supported by low density, low velocity and high conductive layer under CSZ and seismic activity in this region as observed in case of passive rift valleys. They may be caused by asthenospheric upwarping along pre-existing faults/thrusts (MBSZ and PCSZ) due to plate tectonic forces after the collision of Indian and Eurasian plates since Miocene time.     

Experimental technique of calibration of symmetrical air pollution models

Based on the inherent property of symmetry of air pollution models, a Symmetrical Air Pollution Model Index (SAPMI) has been developed to calibrate the accuracy of predictions made by such models, where the initial quantity of release at the source is not known. For exact prediction the value of SAPMI should be equal to 1. If the predicted values are overestimating then SAPMI is <1 and if it is underestimating then SAPMI is >1. Specific design for the layout of receptors has been suggested as a requirement for the calibration experiments. SAPMI is applicable for all variations of symmetrical air pollution dispersion models.     

Hydrochemistry of reservoirs of Damodar River basin, India: weathering processes and water quality assessment

Water samples collected from the six reservoirs of Damodar River basin in pre- and post-monsoon, have been analysed, to study the major ion chemistry and the weathering and geochemical processes controlling the water composition. Ca, Na and HCO₃ dominate the chemical composition of the reservoir water. The seasonal data shows a minimum concentration of most of the ions in post-monsoon and a maximum concentration in pre-monsoon seasons, reflecting the concentrating effects due to elevated temperature and increased evaporation during the low water level period of the pre-monsoon season. Water chemistry of the reservoirs strongly reflects the dominance of continental weathering aided by atmospheric and anthropogenic activities in the catchment area. Higher concentration of SO₄ and TDS in Panchet, Durgapur and Tenughat reservoirs indicate mining and anthropogenic impact on water quality. The high contribution of (Ca+Mg) to the total cations, high concentration of dissolved silica, relatively high (Na+K)/TZ⁺ ratio (0.3) and low equivalent ratio of (Ca+Mg)/(Na+K) suggests combined influence of carbonate and silicate weathering. Kaolinite is the possible mineral that is in equilibrium with the water, implying that the chemistry of reservoir water favours kaolinite formation. The calculated values of SAR, RSC and sodium percentage indicate the ‘excellent to good quality’ of water for irrigation uses.